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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-Oxo-2-(propylamino)ethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C15H24N4O3S2
    [2-Oxo-2-(propylamino)ethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H25N5O3S2
    [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C19H30N4O3S2
    [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-(Cyclopropylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C15H22N4O3S2
    [2-(Cyclopropylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-(2-Methylpropylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H26N4O3S2
    [2-(2-Methylpropylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H28N4O3S2
    [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-(Cyclopentylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C17H26N4O3S2
    [2-(Cyclopentylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— Cyanomethyl 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C12H16N4O2S2
    Cyanomethyl 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(2R)-1-amino-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C13H20N4O3S2
    [(2R)-1-amino-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-Oxo-2-(propan-2-ylamino)ethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C15H24N4O3S2
    [2-Oxo-2-(propan-2-ylamino)ethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H24N4O3S2
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(2R)-butan-2-yl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H26N4O3S2
    [2-[[(2R)-butan-2-yl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-(Tert-butylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H26N4O3S2
    [2-(Tert-butylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-oxo-2-[[(2R)-pentan-2-yl]amino]ethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C17H28N4O3S2
    [2-oxo-2-[[(2R)-pentan-2-yl]amino]ethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(1R)-2-oxocyclohexyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H23N3O3S2
    [(1R)-2-oxocyclohexyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— Cyclohexylmethyl 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C17H27N3O2S2
    Cyclohexylmethyl 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C17H28N4O3S2
    [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C19H30N4O3S2
    [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— (2-Amino-2-oxoethyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C12H18N4O3S2
    (2-Amino-2-oxoethyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— tert-butyl N-[2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]carbamate —— C14H24N4O4S
    tert-butyl N-[2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]carbamate
    —— 5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-N-(2-methoxyethyl)-1,3,4-thiadiazol-2-amine —— C12H13ClFN3OS2
    5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-N-(2-methoxyethyl)-1,3,4-thiadiazol-2-amine
    —— methyl 5-[(2S)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C16H22N4O4S2
    methyl 5-[(2S)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C14H24N4O2S2
    2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— tert-butyl N-[2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]carbamate —— C14H24N4O4S
    tert-butyl N-[2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]carbamate
    —— 2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C14H24N4O2S2
    2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C20H24N4O2S2
    1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-[2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide —— C13H17N5O3S2
    N-[2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide
    —— 1-[2,5-Dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C15H19F3N4O2S2
    1-[2,5-Dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-(2-methoxyethyl)-1,3,4-thiadiazol-2-amine —— C12H13BrFN3OS2
    5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-(2-methoxyethyl)-1,3,4-thiadiazol-2-amine
    —— methyl 5-[(2R)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C16H22N4O4S2
    methyl 5-[(2R)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C14H24N4O2S2
    2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— (2R)-N-[[(2S)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide —— C16H19N3O2S2
    (2R)-N-[[(2S)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide
    —— Methyl 3-[3-[2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate —— C17H24N4O4S2
    Methyl 3-[3-[2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate
    —— (2S)-N-[[(2S)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide —— C16H19N3O2S2
    (2S)-N-[[(2S)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide
    —— (2R)-N-[[(2R)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide —— C16H19N3O2S2
    (2R)-N-[[(2R)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide
    —— (2S)-N-[[(2R)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide —— C16H19N3O2S2
    (2S)-N-[[(2R)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide
    —— (3S)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-1-(2-methylpropanoyl)piperidine-3-carboxamide —— C22H28N4O2S
    (3S)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-1-(2-methylpropanoyl)piperidine-3-carboxamide
    —— ethyl 5-[(2S)-2-(2-fluorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C18H20FNO3S
    ethyl 5-[(2S)-2-(2-fluorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-(2-fluorophenyl)sulfanyl-N-(2-phenylsulfanylphenyl)acetamide —— C20H16FNOS2
    2-(2-fluorophenyl)sulfanyl-N-(2-phenylsulfanylphenyl)acetamide
    —— 2-(2-Piperidin-1-ium-1-ylethylsulfanyl)-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile —— C18H19F3N3S2+
    2-(2-Piperidin-1-ium-1-ylethylsulfanyl)-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(2-fluorophenyl)sulfanylacetamide —— C20H15ClFNOS2
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(2-fluorophenyl)sulfanylacetamide
    —— 1-[1-[2-(4-Chlorophenyl)ethyl]-2,5-dimethylpyrrol-3-yl]-2-(2-fluorophenyl)sulfanylethanone —— C22H21ClFNOS
    1-[1-[2-(4-Chlorophenyl)ethyl]-2,5-dimethylpyrrol-3-yl]-2-(2-fluorophenyl)sulfanylethanone
    —— 1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(2-fluorophenyl)sulfanylethanone —— C21H19F2NOS
    1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(2-fluorophenyl)sulfanylethanone
    —— 2-(2-chlorophenyl)sulfanyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]acetamide —— C13H18ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]acetamide
    —— 2-ethylsulfanyl-5-[(1R)-1-pyridin-4-ylethyl]sulfanyl-1,3,4-thiadiazole —— C11H13N3S3
    2-ethylsulfanyl-5-[(1R)-1-pyridin-4-ylethyl]sulfanyl-1,3,4-thiadiazole
    —— 2-ethylsulfanyl-5-[(1S)-1-pyridin-4-ylethyl]sulfanyl-1,3,4-thiadiazole —— C11H13N3S3
    2-ethylsulfanyl-5-[(1S)-1-pyridin-4-ylethyl]sulfanyl-1,3,4-thiadiazole
    —— (4R)-1-methyl-2-oxo-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)piperidine-4-carboxamide —— C17H18N4O2S
    (4R)-1-methyl-2-oxo-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)piperidine-4-carboxamide
    —— (4S)-1-methyl-2-oxo-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)piperidine-4-carboxamide —— C17H18N4O2S
    (4S)-1-methyl-2-oxo-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)piperidine-4-carboxamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]acetamide —— C13H18ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]acetamide
    —— 2-[(2,5-Difluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(3-methylphenyl)methyl]pyrimidin-4-one —— C21H20F2N2OS
    2-[(2,5-Difluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(3-methylphenyl)methyl]pyrimidin-4-one