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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(2-chloro-4-fluorophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H16ClFN2OS
    2-[(2-chloro-4-fluorophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— N-(4-ethylphenyl)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H15N5OS2
    N-(4-ethylphenyl)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2S)-N-benzyl-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide —— C19H23NOS
    (2S)-N-benzyl-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide
    —— 2-[(1S)-1-phenylethyl]sulfanyl-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C19H20N2OS
    2-[(1S)-1-phenylethyl]sulfanyl-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(3-chlorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H17ClN2OS
    2-[(3-chlorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]propanamide —— C18H24N4OS2
    (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]propanamide
    —— 5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C15H19N3O2S2
    5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C23H27N3O4S2
    1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— (2R)-N-(1-adamantyl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C21H26N4OS2
    (2R)-N-(1-adamantyl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-4-ium-1-yl)propan-1-one —— C19H28N5OS2+
    (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-4-ium-1-yl)propan-1-one
    —— 2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylethanone —— C17H21N3O2S
    2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylethanone
    —— (2R)-N-benzyl-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide —— C19H23NOS
    (2R)-N-benzyl-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide
    —— (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C15H18N4OS2
    (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— 2-[(4-chlorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H17ClN2OS
    2-[(4-chlorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H19FN4OS2
    (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— 2-[(2-methylphenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C19H20N2OS
    2-[(2-methylphenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(1R)-1-phenylethyl]sulfanyl-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C19H20N2OS
    2-[(1R)-1-phenylethyl]sulfanyl-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— N-phenyl-5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C16H15N3S2
    N-phenyl-5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(4-ethylphenyl)-5-methylsulfanyl-1,3,4-thiadiazol-2-amine —— C11H13N3S2
    N-(4-ethylphenyl)-5-methylsulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(2-cyanoethyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C16H19N5OS2
    N-(2-cyanoethyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 2-[(2S)-2-phenylpropyl]-5-(3-phenylpropylsulfanyl)-1,3,4-oxadiazole —— C20H22N2OS
    2-[(2S)-2-phenylpropyl]-5-(3-phenylpropylsulfanyl)-1,3,4-oxadiazole
    —— 2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylethanone —— C17H21N3O2S
    2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylethanone
    —— (2S)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one —— C17H23N5OS2
    (2S)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— 2-methyl-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole —— C11H12N2S2
    2-methyl-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole
    —— (2R)-N-benzyl-2-(3,4-dimethylphenyl)sulfanyl-N-methylpropanamide —— C19H23NOS
    (2R)-N-benzyl-2-(3,4-dimethylphenyl)sulfanyl-N-methylpropanamide
    —— 2-[(4-chlorophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H17ClN2OS
    2-[(4-chlorophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— (2S)-N-(1-cyanocyclohexyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H25N5OS2
    (2S)-N-(1-cyanocyclohexyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 1-(4-Acetylpiperazin-1-yl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C16H19N5O2S2
    1-(4-Acetylpiperazin-1-yl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— (2R)-N-benzyl-2-(2,5-dimethylphenyl)sulfanyl-N-methylpropanamide —— C19H23NOS
    (2R)-N-benzyl-2-(2,5-dimethylphenyl)sulfanyl-N-methylpropanamide
    —— 1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C23H27N3O4S2
    1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— N-butyl-2-(2,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C18H27NO3S2
    N-butyl-2-(2,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(2-methylphenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C19H20N2OS
    2-[(2-methylphenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 4-methyl-2-[(1S)-1-phenylethyl]sulfanyl-1,3-thiazole —— C12H13NS2
    4-methyl-2-[(1S)-1-phenylethyl]sulfanyl-1,3-thiazole
    —— 2-[(3-fluorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H17FN2OS
    2-[(3-fluorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C15H18N4O3S3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-diethylacetamide —— C14H18N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-diethylacetamide
    —— 5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-phenyl-1,3,4-thiadiazol-2-amine —— C12H11N5OS2
    5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-phenyl-1,3,4-thiadiazol-2-amine
    —— 2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(1-ethyl-2,5-dimethylpyrrol-3-yl)ethanone —— C18H20N4OS2
    2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(1-ethyl-2,5-dimethylpyrrol-3-yl)ethanone
    —— 2-[(2-bromophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H17BrN2OS
    2-[(2-bromophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(2-bromophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H17BrN2OS
    2-[(2-bromophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide —— C20H22N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide
    —— 5-(2-methylprop-2-enylsulfanyl)-N-phenyl-1,3,4-thiadiazol-2-amine —— C12H13N3S2
    5-(2-methylprop-2-enylsulfanyl)-N-phenyl-1,3,4-thiadiazol-2-amine
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide —— C17H15ClN4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide
    —— 2-[(2R)-2-phenylpropyl]-5-(3-phenylpropylsulfanyl)-1,3,4-oxadiazole —— C20H22N2OS
    2-[(2R)-2-phenylpropyl]-5-(3-phenylpropylsulfanyl)-1,3,4-oxadiazole
    —— 2-methyl-5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole —— C11H12N2S2
    2-methyl-5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole
    —— 2-[(2-chloro-4-fluorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H16ClFN2OS
    2-[(2-chloro-4-fluorophenyl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide —— C20H22N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide
    —— N,N-diethyl-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C18H26N4OS2
    N,N-diethyl-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— 2-[(4-bromo-2-fluorophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H16BrFN2OS
    2-[(4-bromo-2-fluorophenyl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H19N5OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide