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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-methyl-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C11H13N3S2
    N-methyl-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-methylbutyl)acetamide —— C10H18N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-methylbutyl)acetamide
    —— N-methyl-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C13H12N4S3
    N-methyl-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine —— C10H9N5O2S2
    5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H26N4OS2
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H20N4OS2
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C12H13FN4OS2
    N-[(4-fluorophenyl)methyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-Ethanimidoyl-4-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C9H11N5OS2
    2-Ethanimidoyl-4-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— N-benzyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C20H22N4OS2
    N-benzyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide
    —— ethyl 2,5-dimethyl-4-[2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C14H18N4O3S2
    ethyl 2,5-dimethyl-4-[2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— N-cyclohexyl-N-ethyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H22N4OS2
    N-cyclohexyl-N-ethyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-benzyl-N-ethyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H18N4OS2
    N-benzyl-N-ethyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(1-Adamantyl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C15H21N3OS2
    1-(1-Adamantyl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide —— C17H16N4OS3
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide
    —— 1-(5-Chlorothiophen-2-yl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C9H8ClN3OS3
    1-(5-Chlorothiophen-2-yl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N,N-dibenzyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H20N4OS2
    N,N-dibenzyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H15FN4OS2
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-phenylpropyl)acetamide —— C14H18N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-phenylpropyl)acetamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C13H16N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C13H16N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C13H16N4O2S2
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— [2-[(2-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H20FNO3S
    [2-[(2-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[4-(Dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C22H28N2O3S
    [2-[[4-(Dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H26N2O3S
    [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C23H25NO3S
    [2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C18H17NO4S
    [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[2-(2-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C20H22FNO3S
    [2-[2-(2-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] 2-methylpropanoate —— C14H18BrNO3S
    [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] 2-methylpropanoate
    —— 4-methyl-3-[2-[(3S)-3-methylpiperidin-1-yl]pyrimidin-4-yl]-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine —— C16H20N8S
    4-methyl-3-[2-[(3S)-3-methylpiperidin-1-yl]pyrimidin-4-yl]-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[[4-(dimethylamino)phenyl]methyl]acetamide —— C18H19N6OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[[4-(dimethylamino)phenyl]methyl]acetamide
    —— 2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]acetamide —— C17H24N4OS3
    2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C21H23N3OS2
    N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide —— C19H20N6OS
    2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide
    —— 3-[2-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]-4-methyl-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine —— C17H22N8S
    3-[2-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]-4-methyl-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide —— C19H21N6OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide
    —— 3-[2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]-4-methyl-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine —— C17H22N8S
    3-[2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]-4-methyl-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine
    —— 4-methyl-3-[2-[(3R)-3-methylpiperidin-1-yl]pyrimidin-4-yl]-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine —— C16H20N8S
    4-methyl-3-[2-[(3R)-3-methylpiperidin-1-yl]pyrimidin-4-yl]-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine
    —— 3-[2-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]-4-methyl-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine —— C17H22N8S
    3-[2-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]-4-methyl-7-methylsulfanyl-[1,2,4]triazolo[5,1-c][1,2,4]triazine
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C16H19N3O2S
    N-[[4-(dimethylamino)phenyl]methyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-(4-methylphenyl)-4-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-thiazol-2-amine —— C16H18N4S4
    N-(4-methylphenyl)-4-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-thiazol-2-amine
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C16H22N4OS3
    N-[[4-(dimethylamino)phenyl]methyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C17H21N3O2S
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H27N5O3S
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[2-[[4-(Dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H21N5O2S3
    2-[[5-[2-[[4-(Dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C18H27N5O3S
    N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]acetamide —— C21H25N5OS
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H27N5O2S
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H19N5O2S3
    2-[[5-[2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (5R)-9-(2-amino-6-thiophen-2-ylsulfanylpyrimidin-4-yl)-3-methyl-1-oxa-3,9-diazaspiro[4.5]decan-2-one —— C16H19N5O2S2
    (5R)-9-(2-amino-6-thiophen-2-ylsulfanylpyrimidin-4-yl)-3-methyl-1-oxa-3,9-diazaspiro[4.5]decan-2-one
    —— (5S)-3-methyl-7-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1-oxa-3,7-diazaspiro[4.4]nonan-2-one —— C15H19N5O3S
    (5S)-3-methyl-7-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1-oxa-3,7-diazaspiro[4.4]nonan-2-one