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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C12H17N5O2S2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C12H17N5O2S2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide
    —— (2S)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide —— C17H23N5OS2
    (2S)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide
    —— (2R)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C13H17N5OS2
    (2R)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— (2S)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylpropanamide —— C16H23N5OS2
    (2S)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylpropanamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-tert-butylacetamide —— C12H17N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-tert-butylacetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N,N-bis(2-methoxyethyl)acetamide —— C14H21N5O3S2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N,N-bis(2-methoxyethyl)acetamide
    —— 2-[(4-Amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-(azepan-1-yl)ethanone —— C14H19N5OS2
    2-[(4-Amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-(azepan-1-yl)ethanone
    —— ethyl N-[2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetyl]carbamate —— C11H13N5O3S2
    ethyl N-[2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetyl]carbamate
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C13H19N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C13H19N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— (2R)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-benzyl-N-methylpropanamide —— C17H19N5OS2
    (2R)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-benzyl-N-methylpropanamide
    —— (1S,8R)-8,11,11-trimethyl-5-(2-piperidin-1-ium-1-ylethylsulfanyl)-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C18H29N4S+
    (1S,8R)-8,11,11-trimethyl-5-(2-piperidin-1-ium-1-ylethylsulfanyl)-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
    —— (3S)-N-butyl-N-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]-1,1-dioxothiolan-3-amine —— C12H21N3O2S3
    (3S)-N-butyl-N-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]-1,1-dioxothiolan-3-amine
    —— (3R)-N-butyl-N-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]-1,1-dioxothiolan-3-amine —— C12H21N3O2S3
    (3R)-N-butyl-N-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]-1,1-dioxothiolan-3-amine
    —— (NE)-N-[[4-[(Z)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine —— C8H10N2O2S3
    (NE)-N-[[4-[(Z)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine
    —— (2R)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N-(2-methoxyethyl)propanamide —— C19H24FN3O3S
    (2R)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N-(2-methoxyethyl)propanamide
    —— (2S)-N-[1-(3-methylphenyl)cyclopentyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H24N4OS
    (2S)-N-[1-(3-methylphenyl)cyclopentyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-[1-(3-methylphenyl)cyclopentyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H24N4OS
    (2R)-N-[1-(3-methylphenyl)cyclopentyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 5-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]pentanamide —— C23H33N3O2S
    5-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]pentanamide
    —— 5-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]pentanamide —— C23H33N3O2S
    5-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]pentanamide
    —— (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol —— C15H21N3O3S2
    (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2S)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C15H28N4O2S
    (2S)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2S)-1-(4-methylpiperidin-1-yl)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol —— C15H21N3O2S2
    (2S)-1-(4-methylpiperidin-1-yl)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2R)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol —— C18H26N4O2S2
    (2R)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol
    —— (2S)-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-3-(1-methylimidazol-2-yl)sulfanylpropan-2-ol —— C13H23N3O2S
    (2S)-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-3-(1-methylimidazol-2-yl)sulfanylpropan-2-ol
    —— (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol —— C15H21N3O3S2
    (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol
    —— 5-[(3-Fluorophenyl)methyl]-3,6-dimethyl-2-{[(4-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one —— C21H21FN2OS
    5-[(3-Fluorophenyl)methyl]-3,6-dimethyl-2-{[(4-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one
    —— (2R)-1-(4-methylpiperidin-1-yl)-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol —— C11H21N5OS
    (2R)-1-(4-methylpiperidin-1-yl)-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol
    —— (2R)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol —— C12H21N3O2S2
    (2R)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2R)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol —— C12H21N3O2S2
    (2R)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-(1-methylimidazol-2-yl)sulfanylpropan-2-ol —— C13H23N3O2S
    (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-(1-methylimidazol-2-yl)sulfanylpropan-2-ol
    —— (2R)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol —— C18H26N4O2S2
    (2R)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol
    —— (2S)-1-(4-methylpiperidin-1-yl)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol —— C12H21N3OS2
    (2S)-1-(4-methylpiperidin-1-yl)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2S)-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol —— C15H21N3O3S2
    (2S)-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C17H30N4O2S2
    (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C17H30N4OS2
    (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C17H30N4O2S2
    (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol —— C18H26N4O2S2
    (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol
    —— (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol —— C11H21N5O2S
    (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol
    —— (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C17H30N4O2S2
    (2S)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2R)-1-(1-methylimidazol-2-yl)sulfanyl-3-(4-methylpiperidin-1-yl)propan-2-ol —— C13H23N3OS
    (2R)-1-(1-methylimidazol-2-yl)sulfanyl-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol —— C12H21N3O2S2
    (2S)-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2S)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol —— C11H21N5O2S
    (2S)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol
    —— N-cyclopropyl-2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C19H26N4OS2
    N-cyclopropyl-2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— N-cyclopropyl-2-[[5-[(5R)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C19H26N4OS2
    N-cyclopropyl-2-[[5-[(5R)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— N'-{(E)-[5-(phenylsulfanyl)furan-2-yl]methylidene}-3-(trifluoromethyl)benzohydrazide —— C19H13F3N2O2S
    N'-{(E)-[5-(phenylsulfanyl)furan-2-yl]methylidene}-3-(trifluoromethyl)benzohydrazide
    —— 1-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3-[[(2R)-oxolan-2-yl]methyl]urea —— C16H19N3O2S2
    1-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3-[[(2R)-oxolan-2-yl]methyl]urea
    —— (2S)-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H15BrN4O2S
    (2S)-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 1-[(2R)-1-methoxypropan-2-yl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C15H19N3O2S2
    1-[(2R)-1-methoxypropan-2-yl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea