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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H17FN4O2S
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C17H20FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— 2-(4-Chlorophenyl)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C17H10ClFN4O2S
    2-(4-Chlorophenyl)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— N-[(2S)-butan-2-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H16FN3O2S
    N-[(2S)-butan-2-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide —— C13H14FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 1-(4-Acetylpiperazin-1-yl)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C16H17FN4O3S
    1-(4-Acetylpiperazin-1-yl)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H17FN4O2S
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C21H18FN3O3S
    2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methylbutyl)acetamide —— C15H18FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methylbutyl)acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)acetamide —— C14H16FN3O3S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C16H14FN3O2S2
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— ethyl 5-[2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C19H18FN3O4S
    ethyl 5-[2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C19H20FN3O2S
    1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— N'-acetyl-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetohydrazide —— C12H11FN4O3S
    N'-acetyl-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetohydrazide
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20FN3O2S
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 1-[2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]imidazolidin-2-one —— C13H11FN4O3S
    1-[2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]imidazolidin-2-one
    —— 2-(2-Fluorophenyl)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C12H9FN4O2S
    2-(2-Fluorophenyl)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C13H14N4S2
    (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide —— C12H12FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-(2-Fluorophenyl)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C15H9FN4O3S
    2-(2-Fluorophenyl)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20FN3O2S
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C13H14N4S2
    (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— (2R)-N-cyclohexyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H26N4O2S
    (2R)-N-cyclohexyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-cyclohexyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H26N4O2S
    (2S)-N-cyclohexyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20FN3O2S
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-cyclopropyl-5-[[5-(5-methyl-3-phenyl-1,2-oxazol-4-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H16N6O2S2
    N-cyclopropyl-5-[[5-(5-methyl-3-phenyl-1,2-oxazol-4-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[(4-fluorophenyl)methyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H13F2N3O2S
    N-[(4-fluorophenyl)methyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 1-(1-Ethyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C18H18FN3O2S
    1-(1-Ethyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-(2-fluorophenyl)-1,3,4-oxadiazole —— C15H9BrF2N2OS
    2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-(2-fluorophenyl)-1,3,4-oxadiazole
    —— Ethyl 2-[5-[2-[[4-(dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]acetate —— C19H27N5O3S
    Ethyl 2-[5-[2-[[4-(dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]acetate
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-2,2,2-trifluoro-1-phenylethyl]acetamide —— C13H13F3N4OS
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-2,2,2-trifluoro-1-phenylethyl]acetamide
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-2,2,2-trifluoro-1-phenylethyl]acetamide —— C13H13F3N4OS
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-2,2,2-trifluoro-1-phenylethyl]acetamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-3-methyl-1-pyrrolidin-1-ylbutan-1-one —— C14H22N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-3-methyl-1-pyrrolidin-1-ylbutan-1-one
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-3-methyl-1-pyrrolidin-1-ylbutan-1-one —— C14H22N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-3-methyl-1-pyrrolidin-1-ylbutan-1-one
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptyl-3-methylbutanamide —— C17H28N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptyl-3-methylbutanamide
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptyl-3-methylbutanamide —— C17H28N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptyl-3-methylbutanamide
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] (2S)-2-phenylsulfanylpropanoate —— C14H19NO3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] (2S)-2-phenylsulfanylpropanoate
    —— [2-(6-amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C16H17N3O5S
    [2-(6-amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H19FN2O3S
    [(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] (2S)-2-phenylsulfanylpropanoate —— C14H19NO3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] (2S)-2-phenylsulfanylpropanoate
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] (2R)-2-phenylsulfanylpropanoate —— C14H19NO3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] (2R)-2-phenylsulfanylpropanoate
    —— [(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H19FN2O3S
    [(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C19H17FN2O3S
    [(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[cyclopropyl-[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C19H25NO5S2
    [2-[cyclopropyl-[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H14F2N2O3S
    [(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C19H17FN2O3S
    [(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— (2R)-2-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C20H29N5OS
    (2R)-2-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C15H21NO3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[cyclopropyl-[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C19H25NO5S2
    [2-[cyclopropyl-[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C15H21NO3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2,4-dimethylphenyl)sulfanylacetate