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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(4-Fluorophenyl)-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C16H9FN4O2S3
    3-(4-Fluorophenyl)-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 7-(3,3-Dimethyl-2-oxobutyl)sulfanyl-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C16H16N4O2S2
    7-(3,3-Dimethyl-2-oxobutyl)sulfanyl-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-cycloheptyl-2-[(7-oxo-6-phenyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide —— C19H22N6O2S
    N-cycloheptyl-2-[(7-oxo-6-phenyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide
    —— 3-(4-Chlorophenyl)-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C13H9ClN4O2S2
    3-(4-Chlorophenyl)-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 3-Benzyl-7-(3,3-dimethyl-2-oxobutyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C17H18N4O2S2
    3-Benzyl-7-(3,3-dimethyl-2-oxobutyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 6-(4-fluorophenyl)-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C16H10FN5O2S2
    6-(4-fluorophenyl)-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— N-cyclohexyl-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide —— C12H15N5O2S2
    N-cyclohexyl-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide
    —— 7-(2-Oxo-2-thiophen-2-ylethyl)sulfanyl-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C16H10N4O2S3
    7-(2-Oxo-2-thiophen-2-ylethyl)sulfanyl-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-cyclopentyl-2-[[6-(4-fluorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]acetamide —— C17H17FN6O2S
    N-cyclopentyl-2-[[6-(4-fluorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]acetamide
    —— 6-(4-methylphenyl)-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C14H13N5O2S
    6-(4-methylphenyl)-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 6-(4-fluorophenyl)-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C13H10FN5O2S
    6-(4-fluorophenyl)-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 7-(3,3-Dimethyl-2-oxobutyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C10H12N4O2S2
    7-(3,3-Dimethyl-2-oxobutyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-cycloheptyl-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide —— C13H17N5O2S2
    N-cycloheptyl-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide
    —— 3-(3,3-dimethyl-2-oxobutyl)sulfanyl-6-methyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C11H15N5O2S
    3-(3,3-dimethyl-2-oxobutyl)sulfanyl-6-methyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 2-[[6-(4-chlorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]-N-cyclopentylacetamide —— C17H17ClN6O2S
    2-[[6-(4-chlorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— N-cyclopentyl-2-[[3-(4-fluorophenyl)-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl]sulfanyl]acetamide —— C17H16FN5O2S2
    N-cyclopentyl-2-[[3-(4-fluorophenyl)-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl]sulfanyl]acetamide
    —— 3-Benzyl-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C17H12N4O2S3
    3-Benzyl-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 6-methyl-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C8H9N5O2S
    6-methyl-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 2-[(3-tert-butyl-4-oxo-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]-N-(4-methylbenzyl)acetamide —— C18H21N5O2S2
    2-[(3-tert-butyl-4-oxo-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]-N-(4-methylbenzyl)acetamide
    —— 6-[(4-methylphenyl)methyl]-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C15H15N5O2S
    6-[(4-methylphenyl)methyl]-3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 3-(4-Methylphenyl)-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H12N4O2S2
    3-(4-Methylphenyl)-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 3-(4-Fluorophenyl)-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C13H9FN4O2S2
    3-(4-Fluorophenyl)-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 3-[(4-Methylphenyl)methyl]-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C15H14N4O2S2
    3-[(4-Methylphenyl)methyl]-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-[(4-methylphenyl)methyl]-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide —— C14H13N5O2S2
    N-[(4-methylphenyl)methyl]-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide
    —— 7-(3,3-Dimethyl-2-oxobutyl)sulfanyl-3-methyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C11H14N4O2S2
    7-(3,3-Dimethyl-2-oxobutyl)sulfanyl-3-methyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-cyclohexyl-2-[(4-oxo-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide —— C18H19N5O2S2
    N-cyclohexyl-2-[(4-oxo-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide
    —— N-cyclopentyl-2-[[3-(4-methylphenyl)-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl]sulfanyl]acetamide —— C18H19N5O2S2
    N-cyclopentyl-2-[[3-(4-methylphenyl)-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl]sulfanyl]acetamide
    —— 3-Benzyl-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H12N4O2S2
    3-Benzyl-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-[(5-cyclohexyl-4-pyrrol-1-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopentylacetamide —— C19H27N5OS
    2-[(5-cyclohexyl-4-pyrrol-1-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopentylacetamide
    —— 2-[(3-benzyl-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]-N-cyclopentylacetamide —— C18H19N5O2S2
    2-[(3-benzyl-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]-N-cyclopentylacetamide
    —— 3-Methyl-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C11H8N4O2S3
    3-Methyl-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-[(1S)-1-phenylbutyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C20H21N3OS3
    N-[(1S)-1-phenylbutyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 2-[(3R)-1-methyl-2-oxopyrrolidin-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C12H17N3O2S
    2-[(3R)-1-methyl-2-oxopyrrolidin-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-[(3S)-1-methyl-2-oxopyrrolidin-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C12H17N3O2S
    2-[(3S)-1-methyl-2-oxopyrrolidin-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— N-[(1R)-1-phenylbutyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C20H21N3OS3
    N-[(1R)-1-phenylbutyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-cyclohexyl-2-[(5-cyclohexyl-4-pyrrol-1-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C20H29N5OS
    N-cyclohexyl-2-[(5-cyclohexyl-4-pyrrol-1-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-phenylbutyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H20N4OS2
    N-[(1S)-1-phenylbutyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C15H18F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C20H20FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C20H20ClN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C20H20FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C16H21N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— N-benzyl-2-{[5-cyclohexyl-4-(1H-pyrrol-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C21H25N5OS
    N-benzyl-2-{[5-cyclohexyl-4-(1H-pyrrol-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-(cyclohexen-1-yl)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C23H25N3O3S
    N-(cyclohexen-1-yl)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C15H18F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— N-[(1R)-1-phenylbutyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H20N4OS2
    N-[(1R)-1-phenylbutyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C21H24N4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C16H21N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(1R)-1-phenylbutyl]acetamide —— C18H20BrNOS
    2-(4-bromophenyl)sulfanyl-N-[(1R)-1-phenylbutyl]acetamide
    —— N-[(1S)-1-phenylbutyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-[(1S)-1-phenylbutyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide