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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— 1-[(4-methylsulfanylphenyl)methyl]-3-[(1S)-1-(1,3,5-trimethylpyrazol-4-yl)ethyl]urea —— C17H24N4OS
    1-[(4-methylsulfanylphenyl)methyl]-3-[(1S)-1-(1,3,5-trimethylpyrazol-4-yl)ethyl]urea
    —— 2-[3-(4-Chlorophenyl)sulfanylpropylazaniumyl]ethyl-dimethylazanium —— C13H23ClN2S+2
    2-[3-(4-Chlorophenyl)sulfanylpropylazaniumyl]ethyl-dimethylazanium
    —— Dimethyl-[2-[3-(4-methylphenyl)sulfanylpropylazaniumyl]ethyl]azanium —— C14H26N2S+2
    Dimethyl-[2-[3-(4-methylphenyl)sulfanylpropylazaniumyl]ethyl]azanium
    —— [(1S)-3-methyl-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium —— C15H22N3OS+
    [(1S)-3-methyl-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium
    —— 5-(5-Benzylsulfanyl-1,3,4-oxadiazol-2-yl)pentylazanium —— C14H20N3OS+
    5-(5-Benzylsulfanyl-1,3,4-oxadiazol-2-yl)pentylazanium
    —— 2-(4-methylphenyl)sulfanyl-N-(2,2,6,6-tetramethylpiperidin-1-ium-4-yl)acetamide —— C18H29N2OS+
    2-(4-methylphenyl)sulfanyl-N-(2,2,6,6-tetramethylpiperidin-1-ium-4-yl)acetamide
    —— [(1S,2R)-1-[5-[(3-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium —— C14H19ClN3OS+
    [(1S,2R)-1-[5-[(3-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium
    —— tert-butyl N-[(1S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropyl]carbamate —— C18H24FN3O3S
    tert-butyl N-[(1S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropyl]carbamate
    —— 5-[5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]pentylazanium —— C14H19ClN3OS+
    5-[5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]pentylazanium
    —— [(1S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propyl]azanium —— C14H20N3OS+
    [(1S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propyl]azanium
    —— [(1S,2R)-1-[5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium —— C14H19FN3OS+
    [(1S,2R)-1-[5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium
    —— [(1S,2S)-2-methoxycyclopentyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C16H24N2O3S
    [(1S,2S)-2-methoxycyclopentyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— [(1S)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)-2-methylpropyl]azanium —— C13H18N3OS+
    [(1S)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)-2-methylpropyl]azanium
    —— [(1S)-3-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium —— C15H22N3OS+
    [(1S)-3-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium
    —— 1-[(4-methylsulfanylphenyl)methyl]-3-[(1R)-1-(1,3,5-trimethylpyrazol-4-yl)ethyl]urea —— C17H24N4OS
    1-[(4-methylsulfanylphenyl)methyl]-3-[(1R)-1-(1,3,5-trimethylpyrazol-4-yl)ethyl]urea
    —— 5-[(6-methoxypyridin-2-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C14H18N4O2S2
    5-[(6-methoxypyridin-2-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 5-[(6-methoxypyridin-2-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C14H18N4O2S2
    5-[(6-methoxypyridin-2-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— [(1S,2S)-2-methoxycyclopentyl] 3-cyclopentylsulfonylpropanoate —— C14H24O5S
    [(1S,2S)-2-methoxycyclopentyl] 3-cyclopentylsulfonylpropanoate
    —— 4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2R)-1-methoxypropan-2-yl]butanamide —— C17H20F3N3O3S
    4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2R)-1-methoxypropan-2-yl]butanamide
    —— (2S)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoate —— C11H9N2O3S-
    (2S)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoate
    —— 4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]butanamide —— C18H20F3N3O3S
    4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]butanamide
    —— N-[(2R)-butan-2-yl]-4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanamide —— C17H20F3N3O2S
    N-[(2R)-butan-2-yl]-4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanamide
    —— 4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]butanamide —— C18H20F3N3O3S
    4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]butanamide
    —— N-[(2S)-butan-2-yl]-4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanamide —— C17H20F3N3O2S
    N-[(2S)-butan-2-yl]-4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanamide
    —— N-[(1R,2S)-2-methylcyclohexyl]-2-phenylsulfanylacetamide —— C15H21NOS
    N-[(1R,2S)-2-methylcyclohexyl]-2-phenylsulfanylacetamide
    —— 4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2S)-1-methoxypropan-2-yl]butanamide —— C17H20F3N3O3S
    4-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2S)-1-methoxypropan-2-yl]butanamide
    —— N-[(1S,2R)-2-methylcyclohexyl]-2-phenylsulfanylacetamide —— C15H21NOS
    N-[(1S,2R)-2-methylcyclohexyl]-2-phenylsulfanylacetamide
    —— (3S)-3-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]piperidine-1-sulfonamide —— C12H21N3O2S3
    (3S)-3-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]piperidine-1-sulfonamide
    —— (3R)-3-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]piperidine-1-sulfonamide —— C12H21N3O2S3
    (3R)-3-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]piperidine-1-sulfonamide
    —— (2S)-N'-propanoyl-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanehydrazide —— C11H19N5O2S2
    (2S)-N'-propanoyl-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanehydrazide
    —— (2S)-2-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]piperidine-1-sulfonamide —— C12H21N3O2S3
    (2S)-2-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]piperidine-1-sulfonamide
    —— (2R)-N'-propanoyl-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanehydrazide —— C11H19N5O2S2
    (2R)-N'-propanoyl-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanehydrazide
    —— 2-(1-cyclopropyl-4-oxopyrimidin-2-yl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C14H19N3O3S
    2-(1-cyclopropyl-4-oxopyrimidin-2-yl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-(1-cyclopropyl-4-oxopyrimidin-2-yl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C14H19N3O3S
    2-(1-cyclopropyl-4-oxopyrimidin-2-yl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 3-aminopyrazine-2-carboxylate —— C21H20N4O3S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 3-aminopyrazine-2-carboxylate
    —— N-[(2S)-4-phenylbutan-2-yl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C22H29NOS
    N-[(2S)-4-phenylbutan-2-yl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— N-cycloheptyl-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C19H29NOS
    N-cycloheptyl-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— 3-Methyl-7-[(2,3,5,6-tetramethylphenyl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C18H20N2OS2
    3-Methyl-7-[(2,3,5,6-tetramethylphenyl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-cyclopentyl-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C17H25NOS
    N-cyclopentyl-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C17H22N2O2S3
    N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-(2,3,5,6-tetramethylphenyl)sulfanylethanone —— C22H26N2O2S
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-(2,3,5,6-tetramethylphenyl)sulfanylethanone
    —— N-[(2R)-4-phenylbutan-2-yl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C22H29NOS
    N-[(2R)-4-phenylbutan-2-yl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— N-[(1S)-1-phenylethyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C20H25NOS
    N-[(1S)-1-phenylethyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— N-[(2S)-2-phenylpropyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C21H27NOS
    N-[(2S)-2-phenylpropyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C24H35NOS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— ethyl 2,4-dimethyl-5-[2-(2,3,5,6-tetramethylphenyl)sulfanylacetyl]-1H-pyrrole-3-carboxylate —— C21H27NO3S
    ethyl 2,4-dimethyl-5-[2-(2,3,5,6-tetramethylphenyl)sulfanylacetyl]-1H-pyrrole-3-carboxylate
    —— ethyl N-[2-(2,3,5,6-tetramethylphenyl)sulfanylacetyl]carbamate —— C15H21NO3S
    ethyl N-[2-(2,3,5,6-tetramethylphenyl)sulfanylacetyl]carbamate