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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C22H30N4O2S
    2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C22H30N4O2S
    2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C22H31N4O2S+
    2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 3-(2-Morpholin-4-ium-4-ylethylsulfanyl)-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C20H30N4O2S+2
    3-(2-Morpholin-4-ium-4-ylethylsulfanyl)-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 1-(Pyrrolidin-1-yl)-3-{[2-(pyrrolidin-1-yl)ethyl]sulfanyl}-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C20H28N4S
    1-(Pyrrolidin-1-yl)-3-{[2-(pyrrolidin-1-yl)ethyl]sulfanyl}-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C22H31N4O2S+
    2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 3-(2-Hydroxyethylsulfanyl)-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C16H22N3OS+
    3-(2-Hydroxyethylsulfanyl)-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 3-(2-Pyrrolidin-1-ium-1-ylethylsulfanyl)-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C20H30N4S+2
    3-(2-Pyrrolidin-1-ium-1-ylethylsulfanyl)-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 3-[(2-Methoxyethyl)sulfanyl]-1-(pyrrolidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C17H23N3OS
    3-[(2-Methoxyethyl)sulfanyl]-1-(pyrrolidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— (1S,2S)-2-methyl-1-(5-propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)butan-1-amine —— C10H19N3OS
    (1S,2S)-2-methyl-1-(5-propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)butan-1-amine
    —— (1S,2S)-1-[5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18FN3OS
    (1S,2S)-1-[5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— (1R)-1-[5-(2-methylprop-2-enylsulfanyl)-1,3,4-oxadiazol-2-yl]ethanamine —— C8H13N3OS
    (1R)-1-[5-(2-methylprop-2-enylsulfanyl)-1,3,4-oxadiazol-2-yl]ethanamine
    —— [(1R)-1-[5-(2-methylprop-2-enylsulfanyl)-1,3,4-oxadiazol-2-yl]ethyl]azanium —— C8H14N3OS+
    [(1R)-1-[5-(2-methylprop-2-enylsulfanyl)-1,3,4-oxadiazol-2-yl]ethyl]azanium
    —— 2-[(4-cyano-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridin-3-yl)sulfanyl]acetate —— C13H13N2O2S-
    2-[(4-cyano-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridin-3-yl)sulfanyl]acetate
    —— (2S)-N-(2-morpholin-4-ylethyl)-2-phenylsulfanylpropanamide —— C15H22N2O2S
    (2S)-N-(2-morpholin-4-ylethyl)-2-phenylsulfanylpropanamide
    —— [(1R)-1-[5-[(3-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropyl]azanium —— C13H17FN3OS+
    [(1R)-1-[5-[(3-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropyl]azanium
    —— (2R)-N-(2-morpholin-4-ium-4-ylethyl)-2-phenylsulfanylpropanamide —— C15H23N2O2S+
    (2R)-N-(2-morpholin-4-ium-4-ylethyl)-2-phenylsulfanylpropanamide
    —— (1R)-1-[5-[(3-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropan-1-amine —— C13H16FN3OS
    (1R)-1-[5-[(3-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropan-1-amine
    —— N-butyl-N-(1H-imidazol-2-ylmethyl)-2-pyridin-4-ylsulfanylacetamide —— C15H20N4OS
    N-butyl-N-(1H-imidazol-2-ylmethyl)-2-pyridin-4-ylsulfanylacetamide
    —— N-(1H-imidazol-2-ylmethyl)-N-(2-phenylethyl)-2-pyridin-4-ylsulfanylacetamide —— C19H20N4OS
    N-(1H-imidazol-2-ylmethyl)-N-(2-phenylethyl)-2-pyridin-4-ylsulfanylacetamide
    —— N-(1H-imidazol-2-ylmethyl)-N-(2-methylpropyl)-2-pyridin-4-ylsulfanylacetamide —— C15H20N4OS
    N-(1H-imidazol-2-ylmethyl)-N-(2-methylpropyl)-2-pyridin-4-ylsulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-(3-methylcyclopent-2-en-1-ylidene)amino]acetamide —— C14H15FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(E)-(3-methylcyclopent-2-en-1-ylidene)amino]acetamide
    —— N-(1H-imidazol-2-ylmethyl)-N-[(1S)-1-phenylethyl]-2-pyridin-4-ylsulfanylacetamide —— C19H20N4OS
    N-(1H-imidazol-2-ylmethyl)-N-[(1S)-1-phenylethyl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N'-[[5-(hydroxymethyl)-2-methyl-3-oxopyridin-4-ylidene]methyl]acetohydrazide —— C16H16FN3O3S
    2-(2-fluorophenyl)sulfanyl-N'-[[5-(hydroxymethyl)-2-methyl-3-oxopyridin-4-ylidene]methyl]acetohydrazide
    —— N-(1-adamantyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H22N4OS
    N-(1-adamantyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide —— C14H13FN2O2S
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide
    —— N-[(Z)-(2-fluorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H12F2N2OS
    N-[(Z)-(2-fluorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-[(3S)-3-methylcyclohexylidene]amino]acetamide —— C15H19FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-[(3S)-3-methylcyclohexylidene]amino]acetamide
    —— N-[(Z)-[3,5-dimethyl-1-[(4-methylphenyl)methyl]pyrazol-4-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C22H23FN4OS
    N-[(Z)-[3,5-dimethyl-1-[(4-methylphenyl)methyl]pyrazol-4-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(Z)-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C19H24FN3OS
    N-[(Z)-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-(2,3,4,5,6-pentafluorophenyl)methylideneamino]acetamide —— C15H8F6N2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-(2,3,4,5,6-pentafluorophenyl)methylideneamino]acetamide
    —— N-[(Z)-1-(2-chlorophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C16H14ClFN2OS
    N-[(Z)-1-(2-chlorophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide —— C14H12FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide
    —— N-[(Z)-2-ethylbutylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C14H19FN2OS
    N-[(Z)-2-ethylbutylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(Z)-1-(2,6-difluorophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C16H13F3N2OS
    N-[(Z)-1-(2,6-difluorophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(Z)-1-(3-bromophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C16H14BrFN2OS
    N-[(Z)-1-(3-bromophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C13H11FN2OS2
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— N-[(Z)-1-(5-bromothiophen-2-yl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C14H12BrFN2OS2
    N-[(Z)-1-(5-bromothiophen-2-yl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-furan-2-ylmethylideneamino]acetamide —— C13H11FN2O2S
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-furan-2-ylmethylideneamino]acetamide
    —— N-[(Z)-[(2E)-2-benzylideneheptylidene]amino]-2-(2-fluorophenyl)sulfanylacetamide —— C22H25FN2OS
    N-[(Z)-[(2E)-2-benzylideneheptylidene]amino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(3,5-dimethylpyrazol-1-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C15H18N4OS
    2-(3,5-dimethylpyrazol-1-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-thiophen-3-ylmethylideneamino]acetamide —— C13H11FN2OS2
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-thiophen-3-ylmethylideneamino]acetamide
    —— N-[(Z)-1-(4-cyclohexylphenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C22H25FN2OS
    N-[(Z)-1-(4-cyclohexylphenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-(cyclopentylideneamino)-2-(2-fluorophenyl)sulfanylacetamide —— C13H15FN2OS
    N-(cyclopentylideneamino)-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-(3,5,5-trimethylcyclohex-2-en-1-ylidene)amino]acetamide —— C17H21FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(E)-(3,5,5-trimethylcyclohex-2-en-1-ylidene)amino]acetamide
    —— N-[(Z)-(2-bromophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H12BrFN2OS
    N-[(Z)-(2-bromophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-phenylbutylideneamino]acetamide —— C18H19FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-phenylbutylideneamino]acetamide
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H11ClF2N2OS
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-(cyclohexylideneamino)-2-(2-fluorophenyl)sulfanylacetamide —— C14H17FN2OS
    N-(cyclohexylideneamino)-2-(2-fluorophenyl)sulfanylacetamide
    —— 1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C14H19N3OS2
    1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[[(2S)-oxolan-2-yl]methyl]thiourea