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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-benzyl-6-(3,4-dimethylphenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C19H18N4S
    3-benzyl-6-(3,4-dimethylphenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-benzyl-6-(4-methylphenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C18H16N4S
    3-benzyl-6-(4-methylphenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 6-(4-methylphenyl)-3-(thiophen-2-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H12N4S2
    6-(4-methylphenyl)-3-(thiophen-2-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[[5-(3-methyl-1,2-oxazol-5-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H16N4O3S
    2-[[5-(3-methyl-1,2-oxazol-5-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(3-methyl-1,2-oxazol-5-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H16N4O3S
    2-[[5-(3-methyl-1,2-oxazol-5-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (4R)-6-methyl-4-(5-methyl-1H-imidazol-4-yl)-2-oxo-N-(2-pyridin-2-ylsulfanylethyl)-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C17H20N6O2S
    (4R)-6-methyl-4-(5-methyl-1H-imidazol-4-yl)-2-oxo-N-(2-pyridin-2-ylsulfanylethyl)-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— (4S)-6-methyl-4-(5-methyl-1H-imidazol-4-yl)-2-oxo-N-(2-pyridin-2-ylsulfanylethyl)-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C17H20N6O2S
    (4S)-6-methyl-4-(5-methyl-1H-imidazol-4-yl)-2-oxo-N-(2-pyridin-2-ylsulfanylethyl)-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— (4R)-1-ethyl-4-[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]-4,5-dihydro-2H-pyrazolo[3,4-b]pyridin-6-one —— C14H14N6O2S
    (4R)-1-ethyl-4-[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]-4,5-dihydro-2H-pyrazolo[3,4-b]pyridin-6-one
    —— 2-[[4-[(1R)-1-phenylethyl]-5-(pyridin-3-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C18H18N4O2S
    2-[[4-[(1R)-1-phenylethyl]-5-(pyridin-3-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (3S)-2,2-dimethyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]pyrrolidin-3-amine —— C10H20N6S
    (3S)-2,2-dimethyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]pyrrolidin-3-amine
    —— (3R)-2,2-dimethyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]pyrrolidin-3-amine —— C10H20N6S
    (3R)-2,2-dimethyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]pyrrolidin-3-amine
    —— 2-[[4-[(1S)-1-phenylethyl]-5-(pyridin-3-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C18H18N4O2S
    2-[[4-[(1S)-1-phenylethyl]-5-(pyridin-3-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2R)-2-[(4-chloro-2-phenylsulfanyl-1,3-thiazol-5-yl)methylamino]butan-1-ol —— C14H17ClN2OS2
    (2R)-2-[(4-chloro-2-phenylsulfanyl-1,3-thiazol-5-yl)methylamino]butan-1-ol
    —— 2-[[5-(1-ethylpyrazol-4-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H19N5O2S
    2-[[5-(1-ethylpyrazol-4-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(1-ethylpyrazol-4-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H19N5O2S
    2-[[5-(1-ethylpyrazol-4-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (6S)-6-[[5-(ethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C15H17N3OS2
    (6S)-6-[[5-(ethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6R)-6-[[5-(ethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C15H17N3OS2
    (6R)-6-[[5-(ethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6R)-6-(1-methyltetrazol-5-yl)sulfanyl-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C13H14N4OS
    (6R)-6-(1-methyltetrazol-5-yl)sulfanyl-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6S)-6-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C16H19N3O2S
    (6S)-6-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6S)-6-(1-methyltetrazol-5-yl)sulfanyl-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C13H14N4OS
    (6S)-6-(1-methyltetrazol-5-yl)sulfanyl-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6S)-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C14H15N3OS
    (6S)-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6R)-6-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C16H19N3O2S
    (6R)-6-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— (6R)-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one —— C14H15N3OS
    (6R)-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-6,7,8,9-tetrahydrobenzo[7]annulen-5-one
    —— N-[[(3S)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]piperidin-3-yl]methyl]acetamide —— C18H28N2OS
    N-[[(3S)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]piperidin-3-yl]methyl]acetamide
    —— N-[[(3R)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]piperidin-3-yl]methyl]acetamide —— C18H28N2OS
    N-[[(3R)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]piperidin-3-yl]methyl]acetamide
    —— N-[[(3R)-1-[(5-methylsulfanyl-2-sulfanylidene-1,3,4-thiadiazol-3-yl)methyl]piperidin-3-yl]methyl]acetamide —— C12H20N4OS3
    N-[[(3R)-1-[(5-methylsulfanyl-2-sulfanylidene-1,3,4-thiadiazol-3-yl)methyl]piperidin-3-yl]methyl]acetamide
    —— N-[[(3S)-1-[(5-methylsulfanyl-2-sulfanylidene-1,3,4-thiadiazol-3-yl)methyl]piperidin-3-yl]methyl]acetamide —— C12H20N4OS3
    N-[[(3S)-1-[(5-methylsulfanyl-2-sulfanylidene-1,3,4-thiadiazol-3-yl)methyl]piperidin-3-yl]methyl]acetamide
    —— (1R)-2-(5-bromopyrimidin-2-yl)sulfanyl-1-phenylethanol —— C12H11BrN2OS
    (1R)-2-(5-bromopyrimidin-2-yl)sulfanyl-1-phenylethanol
    —— (1S)-2-(5-bromopyrimidin-2-yl)sulfanyl-1-phenylethanol —— C12H11BrN2OS
    (1S)-2-(5-bromopyrimidin-2-yl)sulfanyl-1-phenylethanol
    —— 5-bromo-2-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpyrimidine —— C10H11BrN6OS
    5-bromo-2-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpyrimidine
    —— 5-bromo-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpyrimidine —— C10H11BrN6OS
    5-bromo-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpyrimidine
    —— 3-[(5-Methyl-2-piperidin-1-ium-1-ylidene-1,3-dithiol-4-yl)sulfanyl]propanoate —— C12H17NO2S3
    3-[(5-Methyl-2-piperidin-1-ium-1-ylidene-1,3-dithiol-4-yl)sulfanyl]propanoate
    —— 2-[(3-Fluorophenyl)methylsulfanyl]-3,6-dimethylpyrimidin-4-one —— C13H13FN2OS
    2-[(3-Fluorophenyl)methylsulfanyl]-3,6-dimethylpyrimidin-4-one
    —— 3,6-Dimethyl-5-[(3-methylphenyl)methyl]-2-{[(2-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one —— C22H24N2OS
    3,6-Dimethyl-5-[(3-methylphenyl)methyl]-2-{[(2-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one
    —— Tert-butyl 2-[1,4-dimethyl-5-[(2-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylacetate —— C20H26N2O3S
    Tert-butyl 2-[1,4-dimethyl-5-[(2-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylacetate
    —— 2-[(2,4-Difluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one —— C20H17F3N2OS
    2-[(2,4-Difluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one
    —— 2-{[(3-Fluorophenyl)methyl]sulfanyl}-3,6-dimethyl-5-[(3-methylphenyl)methyl]-3,4-dihydropyrimidin-4-one —— C21H21FN2OS
    2-{[(3-Fluorophenyl)methyl]sulfanyl}-3,6-dimethyl-5-[(3-methylphenyl)methyl]-3,4-dihydropyrimidin-4-one
    —— 2-[(4-Fluorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one —— C15H17FN2OS
    2-[(4-Fluorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one
    —— (3R,4R,6S)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol —— C17H18N2O5S
    (3R,4R,6S)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol
    —— (2R)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N-pentylpropanamide —— C21H28FN3O2S
    (2R)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N-pentylpropanamide
    —— (2S)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N-pentylpropanamide —— C21H28FN3O2S
    (2S)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N-pentylpropanamide
    —— (3R,4R,6R)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol —— C17H18N2O5S
    (3R,4R,6R)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol
    —— (3R,4S,6S)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol —— C17H18N2O5S
    (3R,4S,6S)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol
    —— (3R,4S,6R)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol —— C17H18N2O5S
    (3R,4S,6R)-6-(3-nitro-5-phenylsulfanylanilino)oxane-3,4-diol
    —— (2R,6R)-2,6-dimethyl-4-(3-phenylsulfanylpropyl)morpholine —— C15H23NOS
    (2R,6R)-2,6-dimethyl-4-(3-phenylsulfanylpropyl)morpholine
    —— 2-[2-(4-fluorophenyl)-6-methylpyrimidin-4-yl]sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C23H24FN3OS
    2-[2-(4-fluorophenyl)-6-methylpyrimidin-4-yl]sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— 2-[2-(3-fluorophenyl)-6-methylpyrimidin-4-yl]sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C23H24FN3OS
    2-[2-(3-fluorophenyl)-6-methylpyrimidin-4-yl]sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— (2S,6S)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholine —— C17H27NO2S
    (2S,6S)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholine
    —— (3S,5R)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidin-1-ium —— C17H28NOS+
    (3S,5R)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidin-1-ium
    —— (2R,6R)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholin-4-ium —— C16H26NOS+
    (2R,6R)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholin-4-ium