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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5-Phenyl-1,3,4-oxadiazol-2-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H18N2O3S
    (5-Phenyl-1,3,4-oxadiazol-2-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— (2-Amino-2-oxoethyl) 2-(2,5-dimethylphenyl)sulfanylacetate —— C12H15NO3S
    (2-Amino-2-oxoethyl) 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(Cyclopentylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C17H23NO3S
    [2-(Cyclopentylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C16H21NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C20H23NO3S
    [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C16H21NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C20H22FNO3S
    [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(1-Adamantylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C22H29NO3S
    [2-(1-Adamantylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-amino-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C13H17NO3S
    [(2R)-1-amino-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-Oxo-2-(propan-2-ylamino)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C15H21NO3S
    [2-Oxo-2-(propan-2-ylamino)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C18H24N2O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— ethyl 4-[2-[2-(2,5-dimethylphenyl)sulfanylacetyl]oxyacetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate —— C21H25NO5S
    ethyl 4-[2-[2-(2,5-dimethylphenyl)sulfanylacetyl]oxyacetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C13H17NO3S
    [(2S)-1-amino-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(4-Amino-1-methyl-2,6-dioxo-3-propylpyrimidin-5-yl)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C20H25N3O5S
    [2-(4-Amino-1-methyl-2,6-dioxo-3-propylpyrimidin-5-yl)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[(4-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H20FNO3S
    [2-[(4-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C16H21NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C16H21NO3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C17H16N2O4S
    [5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[(1-Cyanocyclohexyl)amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H24N2O3S
    [2-[(1-Cyanocyclohexyl)amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] pyridine-4-carboxylate —— C20H16N2O3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] pyridine-4-carboxylate
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(2-methylphenyl)methylideneamino]acetamide —— C16H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(2-methylphenyl)methylideneamino]acetamide
    —— 1-[(3R)-4-(cyclopropylmethyl)-3-propan-2-yl-1,4-diazepan-1-yl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C17H29N5OS
    1-[(3R)-4-(cyclopropylmethyl)-3-propan-2-yl-1,4-diazepan-1-yl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (3R)-4-(cyclopropylmethyl)-1-(2-methylsulfanylpyrimidin-4-yl)-3-propan-2-yl-1,4-diazepan-5-one —— C17H26N4OS
    (3R)-4-(cyclopropylmethyl)-1-(2-methylsulfanylpyrimidin-4-yl)-3-propan-2-yl-1,4-diazepan-5-one
    —— 1-[(3S)-4-(cyclopropylmethyl)-3-propan-2-yl-1,4-diazepan-1-yl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C17H29N5OS
    1-[(3S)-4-(cyclopropylmethyl)-3-propan-2-yl-1,4-diazepan-1-yl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (3S)-4-(cyclopropylmethyl)-1-(2-methylsulfanylpyrimidin-4-yl)-3-propan-2-yl-1,4-diazepan-5-one —— C17H26N4OS
    (3S)-4-(cyclopropylmethyl)-1-(2-methylsulfanylpyrimidin-4-yl)-3-propan-2-yl-1,4-diazepan-5-one
    —— N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H21N5O3S2
    N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H14ClN5OS
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C18H19N5OS2
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H14ClN5OS
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 3-Methyl-7-[(1-methyltetrazol-5-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C10H10N6OS2
    3-Methyl-7-[(1-methyltetrazol-5-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-(1-cyanocyclopentyl)-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C10H14N6OS
    N-(1-cyanocyclopentyl)-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— (2R)-2-(1-methyltetrazol-5-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C15H21N5OS
    (2R)-2-(1-methyltetrazol-5-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]propanamide —— C15H21N5OS
    (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]propanamide
    —— methyl 2,4-dimethyl-5-[(2S)-2-(1-methyltetrazol-5-yl)sulfanylpropanoyl]-1H-pyrrole-3-carboxylate —— C13H17N5O3S
    methyl 2,4-dimethyl-5-[(2S)-2-(1-methyltetrazol-5-yl)sulfanylpropanoyl]-1H-pyrrole-3-carboxylate
    —— N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H21N5O3S2
    N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C18H20BrNOS
    2-(4-bromophenyl)sulfanyl-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(2R)-2-phenylpropyl]acetamide —— C17H18BrNOS
    2-(4-bromophenyl)sulfanyl-N-[(2R)-2-phenylpropyl]acetamide
    —— [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] 3-methylbenzoate —— C22H18ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] 3-methylbenzoate
    —— 2-(4-bromophenyl)sulfanyl-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C14H15BrN2OS
    2-(4-bromophenyl)sulfanyl-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(1R)-1-(4-chlorophenyl)ethyl]acetamide —— C16H15BrClNOS
    2-(4-bromophenyl)sulfanyl-N-[(1R)-1-(4-chlorophenyl)ethyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(2S)-2-phenylpropyl]acetamide —— C17H18BrNOS
    2-(4-bromophenyl)sulfanyl-N-[(2S)-2-phenylpropyl]acetamide
    —— 2-(4-Bromophenyl)sulfanyl-1-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]ethanone —— C18H17BrN2O2S
    2-(4-Bromophenyl)sulfanyl-1-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]ethanone
    —— N-cyclohexyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H22N4O3S2
    N-cyclohexyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H20N4O3S2
    N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— ethyl 2,4-dimethyl-5-[(2S)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate —— C14H18N4O3S
    ethyl 2,4-dimethyl-5-[(2S)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H18N4OS
    N-[(1S,2S)-2-methylcyclohexyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(4-bromophenyl)sulfanyl-1-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]ethanone —— C19H22BrNO2S
    2-(4-bromophenyl)sulfanyl-1-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]ethanone
    —— N-(furan-2-ylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C9H10N4O2S
    N-(furan-2-ylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(1H-1,2,4-triazol-5-ylsulfanyl)-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C14H22N4OS
    2-(1H-1,2,4-triazol-5-ylsulfanyl)-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— [2-[[(2S)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C16H22BrNO3S
    [2-[[(2S)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate