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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(2,4-dimethylphenyl)sulfanylacetate —— C18H17NO4S
    [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[[(1S)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C16H16FNO4S
    [2-[[(1S)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-(2-Methylbutan-2-ylamino)-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C17H25NO3S
    [2-(2-Methylbutan-2-ylamino)-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C17H23NO3S
    [2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[[(1R)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C17H23NO3S
    [2-[[(1R)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide —— C15H19FN2OS
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide
    —— [2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C23H25NO3S
    [2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[Methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C21H25NO3S2
    [2-[Methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-2-cyano-3-methylbutan-2-yl]propanamide —— C15H19ClN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-2-cyano-3-methylbutan-2-yl]propanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-2-cyano-3-methylbutan-2-yl]propanamide —— C15H19ClN2OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-2-cyano-3-methylbutan-2-yl]propanamide
    —— N-benzyl-N-propan-2-yl-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H20N4O2S
    N-benzyl-N-propan-2-yl-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-2-cyano-3-methylbutan-2-yl]propanamide —— C15H19ClN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-2-cyano-3-methylbutan-2-yl]propanamide
    —— 4-[(Z)-(3-benzylsulfanyl-5-sulfanylidene-1H-1,2,4-triazol-4-yl)iminomethyl]-1,5-dimethylpyrrole-2-carbonitrile —— C17H16N6S2
    4-[(Z)-(3-benzylsulfanyl-5-sulfanylidene-1H-1,2,4-triazol-4-yl)iminomethyl]-1,5-dimethylpyrrole-2-carbonitrile
    —— 3-benzylsulfanyl-4-[(Z)-(5-methylthiophen-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C15H14N4S3
    3-benzylsulfanyl-4-[(Z)-(5-methylthiophen-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(5-morpholin-4-ylthiophen-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C18H19N5OS3
    3-benzylsulfanyl-4-[(Z)-(5-morpholin-4-ylthiophen-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(2-bromophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H13BrN4S2
    3-benzylsulfanyl-4-[(Z)-(2-bromophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(3-hydroxyphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H14N4OS2
    3-benzylsulfanyl-4-[(Z)-(3-hydroxyphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(2-fluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H13FN4S2
    3-benzylsulfanyl-4-[(Z)-(2-fluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(3,4-difluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H12F2N4S2
    3-benzylsulfanyl-4-[(Z)-(3,4-difluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(2,4,5-trimethylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C19H20N4S2
    3-benzylsulfanyl-4-[(Z)-(2,4,5-trimethylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] (E)-3-thiophen-3-ylprop-2-enoate —— C18H19NO3S2
    [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] (E)-3-thiophen-3-ylprop-2-enoate
    —— 3-benzylsulfanyl-4-[(Z)-(2,5-dimethylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C18H18N4S2
    3-benzylsulfanyl-4-[(Z)-(2,5-dimethylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C15H14N4S3
    3-benzylsulfanyl-4-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(5-methylfuran-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C15H14N4OS2
    3-benzylsulfanyl-4-[(Z)-(5-methylfuran-2-yl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-pyridin-4-ylmethylideneamino]-1H-1,2,4-triazole-5-thione —— C15H13N5S2
    3-benzylsulfanyl-4-[(Z)-pyridin-4-ylmethylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(2-methylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C17H16N4S2
    3-benzylsulfanyl-4-[(Z)-(2-methylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(3-bromophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H13BrN4S2
    3-benzylsulfanyl-4-[(Z)-(3-bromophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-furan-2-ylmethylideneamino]-1H-1,2,4-triazole-5-thione —— C14H12N4OS2
    3-benzylsulfanyl-4-[(Z)-furan-2-ylmethylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(2,4-difluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H12F2N4S2
    3-benzylsulfanyl-4-[(Z)-(2,4-difluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(4-bromophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H13BrN4S2
    3-benzylsulfanyl-4-[(Z)-(4-bromophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(3-fluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H13FN4S2
    3-benzylsulfanyl-4-[(Z)-(3-fluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-thiophen-3-ylmethylideneamino]-1H-1,2,4-triazole-5-thione —— C14H12N4S3
    3-benzylsulfanyl-4-[(Z)-thiophen-3-ylmethylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-pyridin-3-ylmethylideneamino]-1H-1,2,4-triazole-5-thione —— C15H13N5S2
    3-benzylsulfanyl-4-[(Z)-pyridin-3-ylmethylideneamino]-1H-1,2,4-triazole-5-thione
    —— 4-[[(3-benzylsulfanyl-5-sulfanylidene-1H-1,2,4-triazol-4-yl)amino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one —— C17H17N5O2S2
    4-[[(3-benzylsulfanyl-5-sulfanylidene-1H-1,2,4-triazol-4-yl)amino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one
    —— 3-benzylsulfanyl-4-[(Z)-(4-chlorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H13ClN4S2
    3-benzylsulfanyl-4-[(Z)-(4-chlorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 4-[(Z)-benzylideneamino]-3-benzylsulfanyl-1H-1,2,4-triazole-5-thione —— C16H14N4S2
    4-[(Z)-benzylideneamino]-3-benzylsulfanyl-1H-1,2,4-triazole-5-thione
    —— 2-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]-4,6-dimethylpyrimidine —— C16H24N6S
    2-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]-4,6-dimethylpyrimidine
    —— 2-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]pyrazine —— C14H20N6S
    2-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]pyrazine
    —— 4-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]-6-methylpyrimidine —— C15H22N6S
    4-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]-6-methylpyrimidine
    —— 2-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]pyrimidine —— C14H20N6S
    2-[4-(4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-yl]pyrimidine
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C15H12ClN3O2S2
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— 4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[(2S)-oxolan-2-yl]-1H-1,2,4-triazole-5-thione —— C14H16N4OS2
    4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[(2S)-oxolan-2-yl]-1H-1,2,4-triazole-5-thione
    —— 4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[(2R)-oxolan-2-yl]-1H-1,2,4-triazole-5-thione —— C14H16N4OS2
    4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[(2R)-oxolan-2-yl]-1H-1,2,4-triazole-5-thione
    —— 1-(4-fluorophenyl)-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C15H14FN3S2
    1-(4-fluorophenyl)-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— 1-(2-phenylsulfanylethyl)-3-(1H-pyrrole-2-carbonylamino)thiourea —— C14H16N4OS2
    1-(2-phenylsulfanylethyl)-3-(1H-pyrrole-2-carbonylamino)thiourea
    —— 1-[2-(4-chlorophenyl)sulfanylethyl]-3-(1H-pyrrole-2-carbonylamino)thiourea —— C14H15ClN4OS2
    1-[2-(4-chlorophenyl)sulfanylethyl]-3-(1H-pyrrole-2-carbonylamino)thiourea
    —— 1-(2-fluorophenyl)-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C15H14FN3S2
    1-(2-fluorophenyl)-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— 3-[2-(4-chlorophenyl)sulfanylethyl]-1-methyl-1-[(1R)-1-phenylethyl]thiourea —— C18H21ClN2S2
    3-[2-(4-chlorophenyl)sulfanylethyl]-1-methyl-1-[(1R)-1-phenylethyl]thiourea
    —— 3-[2-(4-chlorophenyl)sulfanylethyl]-1-methyl-1-[(1S)-1-phenylethyl]thiourea —— C18H21ClN2S2
    3-[2-(4-chlorophenyl)sulfanylethyl]-1-methyl-1-[(1S)-1-phenylethyl]thiourea
    —— 1-methyl-1-[(1R)-1-phenylethyl]-3-(2-phenylsulfanylethyl)thiourea —— C18H22N2S2
    1-methyl-1-[(1R)-1-phenylethyl]-3-(2-phenylsulfanylethyl)thiourea