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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide —— C21H21N5O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H18F2N4O2S
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]ethanone —— C21H24N4O3S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]ethanone
    —— ethyl (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-2-phenylacetate —— C23H21N3O3S
    ethyl (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-2-phenylacetate
    —— (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide —— C19H20N4O2S
    (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide
    —— N-(2-adamantyl)-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H26N4O2S
    N-(2-adamantyl)-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-benzyl-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H22N4O2S
    (2R)-N-benzyl-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C21H21N5O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— Tert-butyl 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C19H21N3O3S
    Tert-butyl 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C20H22N4O2S
    (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— (2S)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C11H17N3O2S2
    (2S)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2S)-2-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C14H15ClFN3O2S
    (2S)-2-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— N-butyl-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C16H22ClNO3S2
    N-butyl-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— (2S)-N-benzyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide —— C16H22N4O2S
    (2S)-N-benzyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide
    —— (2R)-N-cyclopentyl-2-(2-fluorophenyl)sulfanylpropanamide —— C14H18FNOS
    (2R)-N-cyclopentyl-2-(2-fluorophenyl)sulfanylpropanamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylacetamide —— C15H20ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylacetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C14H18ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— (2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)cyclohexan-1-one —— C15H18O3S
    (2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)cyclohexan-1-one
    —— (2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)cyclohexan-1-one —— C15H18O3S
    (2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)cyclohexan-1-one
    —— 1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone —— C16H23N3O2S
    1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone
    —— (2S)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]propanamide —— C16H22N4O2S
    (2S)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]propanamide
    —— 2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C17H26N4O3S
    2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C15H19ClN4O2S
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C12H19N3O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— (2S)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide —— C16H22N4O2S
    (2S)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide
    —— 2-[(2-chloro-6-fluorophenyl)methyl]-5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C15H16ClFN2O2S
    2-[(2-chloro-6-fluorophenyl)methyl]-5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— (2R)-N-cyclopropyl-2-(2-fluorophenyl)sulfanylpropanamide —— C12H14FNOS
    (2R)-N-cyclopropyl-2-(2-fluorophenyl)sulfanylpropanamide
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H21FN4O2S
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (3S)-3-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C13H10ClFN2O3S
    (3S)-3-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— (2S)-N-cyclohexyl-2-(2-fluorophenyl)sulfanylpropanamide —— C15H20FNOS
    (2S)-N-cyclohexyl-2-(2-fluorophenyl)sulfanylpropanamide
    —— (2R)-N-cyclohexyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide —— C15H26N4O2S
    (2R)-N-cyclohexyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide
    —— 2-[(2-chloro-6-fluorophenyl)methyl]-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C14H14ClFN2O2S
    2-[(2-chloro-6-fluorophenyl)methyl]-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H21FN4O2S
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C11H17N3O2S2
    (2R)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 2-(2,4-dimethylphenyl)-5-[(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C15H16N4O2S
    2-(2,4-dimethylphenyl)-5-[(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H21FN4O2S
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[(2S)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C14H21N3O2S
    2-[(2S)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— (2R)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide —— C16H22N4O2S
    (2R)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide
    —— (2R)-N,N-dimethyl-2-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C12H15N3O2S2
    (2R)-N,N-dimethyl-2-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— ethyl (2S)-2-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C12H14N2O3S2
    ethyl (2S)-2-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 2-[(2-chloro-6-fluorophenyl)methyl]-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C14H14ClFN2O2S
    2-[(2-chloro-6-fluorophenyl)methyl]-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— 2-[(1R)-1-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole —— C14H16N4O2S2
    2-[(1R)-1-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole
    —— (2S)-2-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N,3-trimethylbutanamide —— C16H19ClFN3O2S
    (2S)-2-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N,3-trimethylbutanamide
    —— (2R)-2-[(4-cyclohexyl-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]pentanedinitrile —— C15H21N5S
    (2R)-2-[(4-cyclohexyl-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]pentanedinitrile
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylacetamide —— C15H21NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylacetamide
    —— 2-[(1S)-1-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole —— C14H16N4O2S2
    2-[(1S)-1-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole
    —— 2-[(2-chloro-6-fluorophenyl)methyl]-5-[(1R)-1-pyridin-3-ylethyl]sulfanyl-1,3,4-oxadiazole —— C16H13ClFN3OS
    2-[(2-chloro-6-fluorophenyl)methyl]-5-[(1R)-1-pyridin-3-ylethyl]sulfanyl-1,3,4-oxadiazole
    —— (2R)-N,N,3-trimethyl-2-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanamide —— C14H19N3O2S2
    (2R)-N,N,3-trimethyl-2-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanamide
    —— ethyl (2R)-2-[[5-(2,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C15H18N2O3S
    ethyl (2R)-2-[[5-(2,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (3R)-3-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C11H10N2O3S2
    (3R)-3-[[5-(thiophen-2-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one