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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5R)-3-methyl-7-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1-oxa-3,7-diazaspiro[4.4]nonan-2-one —— C15H19N5O3S
    (5R)-3-methyl-7-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1-oxa-3,7-diazaspiro[4.4]nonan-2-one
    —— 2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[2-(N-ethyl-3-methylanilino)ethyl]acetamide —— C18H25N5OS
    2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[2-(N-ethyl-3-methylanilino)ethyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H23N5OS
    N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2R)-6-methylheptan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H23N3O2S
    N-[(2R)-6-methylheptan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H23N5O2S2
    N-[[4-(dimethylamino)phenyl]methyl]-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H25N5OS
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2S)-heptan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H21N3O2S
    N-[(2S)-heptan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C19H23N3O4S
    N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(furan-2-yl)ethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C12H13N3O3S
    N-[(1S)-1-(furan-2-yl)ethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-pentylacetamide —— C11H17N3O2S
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-pentylacetamide
    —— N-[(1S)-1-cyclopropylethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C11H15N3O2S
    N-[(1S)-1-cyclopropylethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C21H23N3OS2
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-[(5-methylthiophen-2-yl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C20H21N3O2S2
    N-[(5-methylthiophen-2-yl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2,4,4-trimethylpentan-2-yl)acetamide —— C14H23N3O2S
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2,4,4-trimethylpentan-2-yl)acetamide
    —— N-[(2S)-5-methylhexan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H21N3O2S
    N-[(2S)-5-methylhexan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(2R)-octan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H23N3O2S
    N-[(2R)-octan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C19H23N3O4S
    N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(2R)-5-methylhexan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H21N3O2S
    N-[(2R)-5-methylhexan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C20H23FN2O3S
    [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C20H21N3OS2
    N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide —— C17H15N3O2S2
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide
    —— N-[(2-methylphenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H15N3O2S
    N-[(2-methylphenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[2-(N-ethyl-3-methylanilino)ethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H22N4O2S
    N-[2-(N-ethyl-3-methylanilino)ethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-methyl-N-[(3-methylthiophen-2-yl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H15N3O2S2
    N-methyl-N-[(3-methylthiophen-2-yl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H19N3O5S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[2-(4-bromophenyl)sulfanylethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H14BrN3O2S2
    N-[2-(4-bromophenyl)sulfanylethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one —— C13H19N3O2S
    2-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one
    —— 2-[2-(4-benzylsulfonylpiperazin-1-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one —— C17H20N4O4S2
    2-[2-(4-benzylsulfonylpiperazin-1-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one
    —— N-[(5-chlorothiophen-2-yl)methyl]-N-ethyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H14ClN3O2S2
    N-[(5-chlorothiophen-2-yl)methyl]-N-ethyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-cyclohexyl-N-[(4-fluorophenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C19H22FN3O2S
    N-cyclohexyl-N-[(4-fluorophenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-benzyl-N-(furan-2-ylmethyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C18H17N3O3S
    N-benzyl-N-(furan-2-ylmethyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C15H17N3O2S2
    N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylethyl)-N-(thiophen-2-ylmethyl)acetamide —— C19H19N3O2S2
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylethyl)-N-(thiophen-2-ylmethyl)acetamide
    —— N-[(2-fluorophenyl)methyl]-N-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H14FN3O2S
    N-[(2-fluorophenyl)methyl]-N-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1H-pyrimidin-6-one —— C17H17N3O2S
    2-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1H-pyrimidin-6-one
    —— N-benzyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H17N3O4S2
    N-benzyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-benzyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H17N3O4S2
    N-benzyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(thiophen-3-ylmethyl)acetamide —— C12H13N3O2S2
    N-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(thiophen-3-ylmethyl)acetamide
    —— N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-N-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C18H16ClN3O3S
    N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-N-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(5-bromothiophen-2-yl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-prop-2-enylacetamide —— C14H14BrN3O2S2
    N-[(5-bromothiophen-2-yl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-prop-2-enylacetamide
    —— N-cyclopropyl-N-[(2-fluorophenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C16H16FN3O2S
    N-cyclopropyl-N-[(2-fluorophenyl)methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[2-(4-bromophenyl)sulfanylethyl]-2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)acetamide —— C13H15BrN2OS3
    N-[2-(4-bromophenyl)sulfanylethyl]-2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)acetamide
    —— 2-[[5-(2-Methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C16H19N5O2S3
    2-[[5-(2-Methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— N-[2-[[4-(3-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide —— C13H15N3OS3
    N-[2-[[4-(3-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide
    —— 5-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C14H15N5O2S2
    5-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— N-[2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]acetamide —— C13H15N3O2S
    N-[2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]acetamide
    —— (4-Oxo-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-2-yl)methyl 3-(4-fluorophenyl)sulfanylpropanoate —— C20H19FN2O3S2
    (4-Oxo-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-2-yl)methyl 3-(4-fluorophenyl)sulfanylpropanoate
    —— N-prop-2-enyl-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C12H11N5OS3
    N-prop-2-enyl-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide —— C9H14N4OS2
    N-[2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide
    —— 2-[[5-(Prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C16H17N5OS3
    2-[[5-(Prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one