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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone —— C19H17ClN4O2S
    1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone
    —— N-[[(2S)-oxolan-2-yl]methyl]-5-(2-phenylpyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-amine —— C17H17N5OS2
    N-[[(2S)-oxolan-2-yl]methyl]-5-(2-phenylpyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-[[(2R)-oxolan-2-yl]methyl]-5-(2-phenylpyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-amine —— C17H17N5OS2
    N-[[(2R)-oxolan-2-yl]methyl]-5-(2-phenylpyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-[(1S)-1-(2-chlorophenyl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C14H16ClN3OS
    N-[(1S)-1-(2-chlorophenyl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— N-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H22N4OS2
    N-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-Ethanimidoyl-4-(1-methylimidazol-2-yl)sulfanyl-3-oxobutanenitrile —— C10H12N4OS
    2-Ethanimidoyl-4-(1-methylimidazol-2-yl)sulfanyl-3-oxobutanenitrile
    —— 2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-3,5,6-trimethylpyrimidin-4-one —— C14H14ClFN2OS
    2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-3,5,6-trimethylpyrimidin-4-one
    —— 7-{[(1-methyl-1H-imidazol-2-yl)sulfanyl]methyl}-5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C11H10N4OS2
    7-{[(1-methyl-1H-imidazol-2-yl)sulfanyl]methyl}-5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— (3S)-3-[[4-methyl-5-[(2,4,6-trimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide —— C18H25N3O2S2
    (3S)-3-[[4-methyl-5-[(2,4,6-trimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C24H32N4OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— ethyl N-[2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]carbamate —— C15H18N4O3S
    ethyl N-[2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]carbamate
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide —— C15H20N4OS
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide
    —— (2R)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C13H16N4OS
    (2R)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C20H22N4O2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 2-[(5-Benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone —— C19H22N4OS
    2-[(5-Benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— methyl 5-[(2S)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C21H24N4O3S
    methyl 5-[(2S)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S2
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(2-methylphenyl)sulfanylacetamide —— C15H21NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(2-methylphenyl)sulfanylacetamide
    —— 3-pyridin-3-ylpropyl 2-(2-fluorophenyl)sulfanylacetate —— C16H16FNO2S
    3-pyridin-3-ylpropyl 2-(2-fluorophenyl)sulfanylacetate
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(2-methylphenyl)sulfanylacetamide —— C15H21NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(2-methylphenyl)sulfanylacetamide
    —— 2-[(5-Benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]ethanone —— C22H23N5O2S
    2-[(5-Benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]ethanone
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S2
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— (2R)-3-(4-methylphenyl)-2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanenitrile —— C15H12F3N3S
    (2R)-3-(4-methylphenyl)-2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanenitrile
    —— (2S)-3-(4-methylphenyl)-2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanenitrile —— C15H12F3N3S
    (2S)-3-(4-methylphenyl)-2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanenitrile
    —— 6-Tert-butyl-3-methyl-2-{[(3-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one —— C17H22N2OS
    6-Tert-butyl-3-methyl-2-{[(3-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one
    —— N-[(2S)-2-(dimethylamino)-2-(furan-2-yl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H22N4O2S
    N-[(2S)-2-(dimethylamino)-2-(furan-2-yl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-[4-chloro-6-(4-methylpiperidin-1-yl)pyrimidin-2-yl]sulfanyl-N-[(1S)-1-phenylethyl]acetamide —— C20H25ClN4OS
    2-[4-chloro-6-(4-methylpiperidin-1-yl)pyrimidin-2-yl]sulfanyl-N-[(1S)-1-phenylethyl]acetamide
    —— 2-methylsulfanyl-5-[[(2R)-2-(2-phenylethyl)pyrrolidin-1-yl]methyl]-1,3,4-thiadiazole —— C16H21N3S2
    2-methylsulfanyl-5-[[(2R)-2-(2-phenylethyl)pyrrolidin-1-yl]methyl]-1,3,4-thiadiazole
    —— 2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)acetamide —— C19H33ClN5O2S+
    2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)acetamide
    —— 2-[4-chloro-6-(4-methylpiperidin-1-yl)pyrimidin-2-yl]sulfanyl-N-[(1R)-1-phenylethyl]acetamide —— C20H25ClN4OS
    2-[4-chloro-6-(4-methylpiperidin-1-yl)pyrimidin-2-yl]sulfanyl-N-[(1R)-1-phenylethyl]acetamide
    —— 1-[(4R)-5,5-dimethyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-sulfanylidene-1,3-thiazolidin-4-yl]-1-hydroxy-3-methylurea —— C15H20N4O2S3
    1-[(4R)-5,5-dimethyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-sulfanylidene-1,3-thiazolidin-4-yl]-1-hydroxy-3-methylurea
    —— (2R)-2-(cyclopropylmethoxy)-N-[3-(4-fluorophenyl)sulfanylpropyl]propanamide —— C16H22FNO2S
    (2R)-2-(cyclopropylmethoxy)-N-[3-(4-fluorophenyl)sulfanylpropyl]propanamide
    —— (2Z)-3-phenyl-2-{4-[4-(phenylsulfanyl)phenyl]-1,3-thiazol-2-yl}prop-2-enenitrile —— C24H16N2S2
    (2Z)-3-phenyl-2-{4-[4-(phenylsulfanyl)phenyl]-1,3-thiazol-2-yl}prop-2-enenitrile
    —— 3,3-Dimethyl-8-morpholin-4-yl-6-propan-2-ylsulfanyl-1,4-dihydrothiopyrano[3,4-c]pyridin-7-ium-5-carbonitrile —— C18H26N3OS2+
    3,3-Dimethyl-8-morpholin-4-yl-6-propan-2-ylsulfanyl-1,4-dihydrothiopyrano[3,4-c]pyridin-7-ium-5-carbonitrile
    —— (2R)-N-propyl-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H21N5OS
    (2R)-N-propyl-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-propyl-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H21N5OS
    (2S)-N-propyl-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C13H18N4OS2
    2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— methyl 2,4-dimethyl-5-[(2S)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C19H22N4O3S2
    methyl 2,4-dimethyl-5-[(2S)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— methyl 2,4-dimethyl-5-[(2R)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C19H22N4O3S2
    methyl 2,4-dimethyl-5-[(2R)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— 3-[(2-chloro-6-fluorobenzyl)sulfanyl]-4-methyl-5-(thiophen-2-ylmethyl)-4H-1,2,4-triazole —— C15H13ClFN3S2
    3-[(2-chloro-6-fluorobenzyl)sulfanyl]-4-methyl-5-(thiophen-2-ylmethyl)-4H-1,2,4-triazole
    —— 2-(4-Methylphenyl)-4-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole —— C19H18N4S3
    2-(4-Methylphenyl)-4-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole
    —— [2-(2-Methylpropylamino)-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H22N4O4S
    [2-(2-Methylpropylamino)-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H16N4O4S
    [(2S)-1-amino-1-oxopropan-2-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [2-Oxo-2-(thiophen-2-ylmethylamino)ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H18N4O4S2
    [2-Oxo-2-(thiophen-2-ylmethylamino)ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (1R,2R)-2-nitro-N-[(1-phenylsulfanylcyclopropyl)methyl]cyclopropane-1-carboxamide —— C14H16N2O3S
    (1R,2R)-2-nitro-N-[(1-phenylsulfanylcyclopropyl)methyl]cyclopropane-1-carboxamide
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C20H22N4O4S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2-Amino-2-oxoethyl) 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C12H14N4O4S
    (2-Amino-2-oxoethyl) 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (1S,2S)-2-nitro-N-[(1-phenylsulfanylcyclopropyl)methyl]cyclopropane-1-carboxamide —— C14H16N2O3S
    (1S,2S)-2-nitro-N-[(1-phenylsulfanylcyclopropyl)methyl]cyclopropane-1-carboxamide
    —— [2-oxo-2-[[(2S)-pentan-2-yl]amino]ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H24N4O4S
    [2-oxo-2-[[(2S)-pentan-2-yl]amino]ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (1S,2R)-2-nitro-N-[(1-phenylsulfanylcyclopropyl)methyl]cyclopropane-1-carboxamide —— C14H16N2O3S
    (1S,2R)-2-nitro-N-[(1-phenylsulfanylcyclopropyl)methyl]cyclopropane-1-carboxamide