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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-[[(4R)-1,3-dioxan-4-yl]methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione —— C13H14N2O2S3
    5-[[(4R)-1,3-dioxan-4-yl]methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione
    —— (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C17H20N4OS3
    (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C16H15N3OS4
    2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— N-(3-methylbutyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H19N3OS3
    N-(3-methylbutyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-butyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H17N3OS3
    N-butyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 3-Phenyl-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazole-2-thione —— C17H12N4OS3
    3-Phenyl-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazole-2-thione
    —— N,N-dimethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C12H13N3OS3
    N,N-dimethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (1S)-2-(4-chlorophenyl)sulfanyl-1-(4-methylsulfanylphenyl)ethanol —— C15H15ClOS2
    (1S)-2-(4-chlorophenyl)sulfanyl-1-(4-methylsulfanylphenyl)ethanol
    —— (1R)-2-(4-chlorophenyl)sulfanyl-1-(4-methylsulfanylphenyl)ethanol —— C15H15ClOS2
    (1R)-2-(4-chlorophenyl)sulfanyl-1-(4-methylsulfanylphenyl)ethanol
    —— 5-[(3-Fluorophenyl)methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione —— C15H11FN2S3
    5-[(3-Fluorophenyl)methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C19H23N3OS3
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C19H21N3OS3
    1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— 3-phenyl-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole-2-thione —— C16H14N2S3
    3-phenyl-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole-2-thione
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C20H21N3OS3
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H17N3O3S4
    N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 5-[(5-Methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione —— C12H10N4OS3
    5-[(5-Methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C20H21N3OS3
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H17N3O3S4
    N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C20H21N3OS3
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 3-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-5-[2-(1,2,4-triazol-1-yl)ethylsulfanyl]-1,2,4-triazole —— C21H28N6S2
    3-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-5-[2-(1,2,4-triazol-1-yl)ethylsulfanyl]-1,2,4-triazole
    —— 3-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-5-[2-(1,2,4-triazol-1-yl)ethylsulfanyl]-1,2,4-triazole —— C21H28N6S2
    3-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-5-[2-(1,2,4-triazol-1-yl)ethylsulfanyl]-1,2,4-triazole
    —— 2-[[5-cyclohexyl-4-[(Z)-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C21H30N5O2S-
    2-[[5-cyclohexyl-4-[(Z)-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-[[(4R)-4-methylhexyl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethanone —— C19H23N5O2S2
    2-[[5-[[(4R)-4-methylhexyl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethanone
    —— (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C14H18N4OS2
    (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C14H18N4OS2
    (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— (2S)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C12H20N4OS2
    (2S)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— (2R)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C14H18N4OS2
    (2R)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— (2S)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C14H18N4OS2
    (2S)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— (2R)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C12H20N4OS2
    (2R)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C15H26N4OS2
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— 1-(2-Phenylsulfanylphenyl)-3-propan-2-ylthiourea —— C16H18N2S2
    1-(2-Phenylsulfanylphenyl)-3-propan-2-ylthiourea
    —— N-benzyl-N-propan-2-yl-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-benzyl-N-propan-2-yl-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide —— C18H26N4OS
    2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide
    —— 2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C18H26N4OS
    2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— 3-(5-hydroxypentylsulfanyl)-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C12H21N3O3S
    3-(5-hydroxypentylsulfanyl)-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— (2S)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide —— C20H22N4O2S
    (2S)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide
    —— 2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-cyanoethyl)acetamide —— C19H19N5O2S
    2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-cyanoethyl)acetamide
    —— 2-[(4-benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylacetamide —— C21H28N4OS
    2-[(4-benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylacetamide
    —— 2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(1-cyanocyclopentyl)acetamide —— C22H23N5O2S
    2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(1-cyanocyclopentyl)acetamide
    —— 4-Benzyl-3-benzylsulfanyl-5-(2-methylfuran-3-yl)-1,2,4-triazole —— C21H19N3OS
    4-Benzyl-3-benzylsulfanyl-5-(2-methylfuran-3-yl)-1,2,4-triazole
    —— N'-acetyl-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide —— C18H19N5O3S
    N'-acetyl-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide
    —— 2-[[4-Benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C16H14N4OS
    2-[[4-Benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— 2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide —— C22H25N5O2S
    2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide
    —— 4-Benzyl-3-(2-methylfuran-3-yl)-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazole —— C22H21N3OS
    4-Benzyl-3-(2-methylfuran-3-yl)-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazole
    —— 5-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentan-1-ol —— C16H22N2O2S
    5-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentan-1-ol
    —— 4-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-(4-chlorophenyl)-1,3-thiazole —— C20H17ClN4S2
    4-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-(4-chlorophenyl)-1,3-thiazole
    —— 2-[(4-Benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)ethanone —— C23H28N4OS
    2-[(4-Benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)ethanone
    —— 3-(5-hydroxypentylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C12H21N3O3S
    3-(5-hydroxypentylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— 5-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentan-1-ol —— C16H22N2O2S
    5-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentan-1-ol
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2R)-butan-2-yl]carbamoyl]acetamide —— C17H23N5O2S
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2R)-butan-2-yl]carbamoyl]acetamide