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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (2R)-2-(1-propan-2-yltetrazol-5-yl)sulfanylhexanoate —— C11H20N4O2S
    methyl (2R)-2-(1-propan-2-yltetrazol-5-yl)sulfanylhexanoate
    —— methyl (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate —— C17H23N3O2S2
    methyl (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate
    —— methyl (2S)-2-(1-propan-2-yltetrazol-5-yl)sulfanylhexanoate —— C11H20N4O2S
    methyl (2S)-2-(1-propan-2-yltetrazol-5-yl)sulfanylhexanoate
    —— methyl (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate —— C17H23N3O2S2
    methyl (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate
    —— methyl (2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]hexanoate —— C17H23N3O3S
    methyl (2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]hexanoate
    —— methyl (2S)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]hexanoate —— C13H21N3O2S
    methyl (2S)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]hexanoate
    —— methyl (2R)-2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylhexanoate —— C12H15F3N2O2S
    methyl (2R)-2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylhexanoate
    —— methyl (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanylhexanoate —— C12H22N4O2S
    methyl (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanylhexanoate
    —— 2-[2-Oxo-2-(2-phenylsulfanylanilino)ethoxy]benzamide —— C21H18N2O3S
    2-[2-Oxo-2-(2-phenylsulfanylanilino)ethoxy]benzamide
    —— 6-Tert-butyl-2-[(3,5-difluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one —— C16H18F2N2OS
    6-Tert-butyl-2-[(3,5-difluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one
    —— 6-Ethyl-2-[(2-fluorophenyl)methylsulfanyl]-3-methyl-5-[(3-methylphenyl)methyl]pyrimidin-4-one —— C22H23FN2OS
    6-Ethyl-2-[(2-fluorophenyl)methylsulfanyl]-3-methyl-5-[(3-methylphenyl)methyl]pyrimidin-4-one
    —— 2-[(3-Fluorophenyl)methylsulfanyl]-3-methyl-6-propylpyrimidin-4-one —— C15H17FN2OS
    2-[(3-Fluorophenyl)methylsulfanyl]-3-methyl-6-propylpyrimidin-4-one
    —— 2-[(5-Methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate —— C5H5N2O3S-
    2-[(5-Methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— 3-[(5-Benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C14H16N3O2S-
    3-[(5-Benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— N-[(1S)-1-(2,5-dimethylfuran-3-yl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C18H25N3O2S
    N-[(1S)-1-(2,5-dimethylfuran-3-yl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— 2-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl-diethylazanium —— C8H18N5S2+
    2-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl-diethylazanium
    —— (2S)-N-(3-methoxypropyl)-2-(3-methylphenyl)sulfanylpropanamide —— C14H21NO2S
    (2S)-N-(3-methoxypropyl)-2-(3-methylphenyl)sulfanylpropanamide
    —— 2-[(1R)-1-(3-methylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C17H16N2OS
    2-[(1R)-1-(3-methylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— (2S)-N,N-dimethyl-2-(3-methylphenyl)sulfanylpropanamide —— C12H17NOS
    (2S)-N,N-dimethyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2R)-N-(3-methoxypropyl)-2-(3-methylphenyl)sulfanylpropanamide —— C14H21NO2S
    (2R)-N-(3-methoxypropyl)-2-(3-methylphenyl)sulfanylpropanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide
    —— 1-(2-Phenylsulfanylethyl)pyrrolidin-1-ium —— C12H18NS+
    1-(2-Phenylsulfanylethyl)pyrrolidin-1-ium
    —— 2-[(1S)-1-(3-methylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C17H16N2OS
    2-[(1S)-1-(3-methylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-2-(3-methylphenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide —— C15H23NOS
    (2S)-2-(3-methylphenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide
    —— 2-[(1S)-1-(3-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C15H14N2OS2
    2-[(1S)-1-(3-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (2R)-N-(2-methylbutan-2-yl)-2-(3-methylphenyl)sulfanylpropanamide —— C15H23NOS
    (2R)-N-(2-methylbutan-2-yl)-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-2-(3-methylphenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide —— C15H23NOS
    (2S)-2-(3-methylphenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide
    —— (2R)-2-(3-methylphenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide —— C15H23NOS
    (2R)-2-(3-methylphenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide
    —— (2R)-3-methyl-2-(3-methylphenyl)sulfanyl-1-morpholin-4-ylbutan-1-one —— C16H23NO2S
    (2R)-3-methyl-2-(3-methylphenyl)sulfanyl-1-morpholin-4-ylbutan-1-one
    —— (2R)-2-(3-methylphenyl)sulfanyl-N-prop-2-enylpropanamide —— C13H17NOS
    (2R)-2-(3-methylphenyl)sulfanyl-N-prop-2-enylpropanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-3-methyl-2-(3-methylphenyl)sulfanyl-1-morpholin-4-ylbutan-1-one —— C16H23NO2S
    (2S)-3-methyl-2-(3-methylphenyl)sulfanyl-1-morpholin-4-ylbutan-1-one
    —— 2-[(1R)-1-(3-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C15H14N2OS2
    2-[(1R)-1-(3-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (2S)-N-(2-methylbutan-2-yl)-2-(3-methylphenyl)sulfanylpropanamide —— C15H23NOS
    (2S)-N-(2-methylbutan-2-yl)-2-(3-methylphenyl)sulfanylpropanamide
    —— (2R)-2-(3-methylphenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide —— C15H23NOS
    (2R)-2-(3-methylphenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide
    —— (2S)-N-tert-butyl-2-(3-methylphenyl)sulfanylpropanamide —— C14H21NOS
    (2S)-N-tert-butyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2R)-N,N-dimethyl-2-(3-methylphenyl)sulfanylpropanamide —— C12H17NOS
    (2R)-N,N-dimethyl-2-(3-methylphenyl)sulfanylpropanamide
    —— 2-(3-methylphenyl)sulfanyl-N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide —— C18H28N2O2S
    2-(3-methylphenyl)sulfanyl-N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide
    —— (2R)-N-tert-butyl-2-(3-methylphenyl)sulfanylpropanamide —— C14H21NOS
    (2R)-N-tert-butyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C18H18N4S2
    (2S)-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— (2S)-2-(3-methylphenyl)sulfanyl-N-(2-methylpropyl)propanamide —— C14H21NOS
    (2S)-2-(3-methylphenyl)sulfanyl-N-(2-methylpropyl)propanamide
    —— (2R)-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C18H18N4S2
    (2R)-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— N-(2-methoxyethyl)-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H24N4O2S2
    N-(2-methoxyethyl)-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C21H20N4OS2
    2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— 2-(3-methylphenyl)sulfanyl-N-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide —— C18H28N2O2S
    2-(3-methylphenyl)sulfanyl-N-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide
    —— 2-(4-Fluorophenyl)-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole —— C18H12FN3OS2
    2-(4-Fluorophenyl)-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C11H8FN3OS
    (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— 2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C15H9BrF2N2OS
    2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole