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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanylpropanoate —— C10H18N4O2S
    ethyl (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanylpropanoate
    —— ethyl (2S)-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C12H15N3O3S2
    ethyl (2S)-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— ethyl (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C14H17N3O2S2
    ethyl (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— ethyl (2R)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanoate —— C10H13NO3S
    ethyl (2R)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanoate
    —— ethyl (2R)-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C12H15N3O3S2
    ethyl (2R)-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— ethyl (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanoate —— C10H13NO3S
    ethyl (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanoate
    —— N-[(2R)-2-(furan-2-yl)-2-pyrrolidin-1-ylethyl]-2-(2-methylphenyl)sulfanylacetamide —— C19H24N2O2S
    N-[(2R)-2-(furan-2-yl)-2-pyrrolidin-1-ylethyl]-2-(2-methylphenyl)sulfanylacetamide
    —— [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H21FN2O3S
    [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H20FNO3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— N-[(2S)-2-(furan-2-yl)-2-pyrrolidin-1-ium-1-ylethyl]-2-(2-methylphenyl)sulfanylacetamide —— C19H25N2O2S+
    N-[(2S)-2-(furan-2-yl)-2-pyrrolidin-1-ium-1-ylethyl]-2-(2-methylphenyl)sulfanylacetamide
    —— [2-(Cyclopentylamino)-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C16H20FNO3S
    [2-(Cyclopentylamino)-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H23FN2O3S
    [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[(3-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H17ClFNO3S
    [2-[(3-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C20H19FN2O3S2
    [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H17ClFNO3S
    [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— ethyl (2R)-2-[[5-(methylsulfanylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C9H14N2O3S2
    ethyl (2R)-2-[[5-(methylsulfanylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— [(2S)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H23FN2O3S
    [(2S)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H19FN2O3S
    [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(2R)-1-[[(1R,2S)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H26FNO3S
    [(2R)-1-[[(1R,2S)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(2R)-1-amino-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C12H14FNO3S
    [(2R)-1-amino-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(2S)-1-[2-(4-fluorophenyl)ethylamino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C20H21F2NO3S
    [(2S)-1-[2-(4-fluorophenyl)ethylamino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C21H21FN2O4S
    [2-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C16H20FNO4S
    [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-Oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C20H19FN2O3S
    [2-Oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(1S)-1-thiophen-2-ylethyl]amino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H18FNO3S2
    [2-oxo-2-[[(1S)-1-thiophen-2-ylethyl]amino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C12H14FNO3S
    [(2S)-1-amino-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H26FNO3S
    [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(1S)-1-(2,4-difluorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H18F3NO3S
    [2-[[(1S)-1-(2,4-difluorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H19FN2O3S
    [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(1R,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H24FNO3S
    [2-[[(1R,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H24FNO3S
    [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(3R)-3-methyl-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C16H20FNO5S2
    [2-[[(3R)-3-methyl-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[2-(Cyclohexen-1-yl)ethylcarbamoylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C20H25FN2O4S
    [2-[2-(Cyclohexen-1-yl)ethylcarbamoylamino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— (2S)-2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanenitrile —— C19H27N5O2S
    (2S)-2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanenitrile
    —— [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H24FNO3S
    [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C18H25N3O2S2
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— [2-oxo-2-[[(1R)-1-thiophen-2-ylethyl]amino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H18FNO3S2
    [2-oxo-2-[[(1R)-1-thiophen-2-ylethyl]amino]ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— Methyl 2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylacetate —— C19H28N4O4S
    Methyl 2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylacetate
    —— [2-[[(1R)-1-(2,4-difluorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C19H18F3NO3S
    [2-[[(1R)-1-(2,4-difluorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(3S)-3-methyl-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C16H20FNO5S2
    [2-[[(3S)-3-methyl-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H21FN2O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— (2R)-2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanamide —— C19H29N5O3S
    (2R)-2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanamide
    —— 2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N,N-dimethylacetamide —— C20H31N5O3S
    2-(7-hexyl-3-methyl-2,4-dioxo-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N,N-dimethylacetamide
    —— (2-Oxo-2-thiophen-2-ylethyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H19N3O3S3
    (2-Oxo-2-thiophen-2-ylethyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-(2-Cyanoethylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C15H21N5O3S2
    [2-(2-Cyanoethylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— N-[(2R)-2-(4-chlorophenyl)-2-morpholin-4-ylethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C22H29ClN4O2S
    N-[(2R)-2-(4-chlorophenyl)-2-morpholin-4-ylethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(2S)-2-(4-chlorophenyl)-2-morpholin-4-ylethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C22H29ClN4O2S
    N-[(2S)-2-(4-chlorophenyl)-2-morpholin-4-ylethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H27N5O3S2
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— (1R)-N-[(4-chloro-2-phenylsulfanyl-1,3-thiazol-5-yl)methyl]-1-[4-(1,2,4-triazol-1-yl)phenyl]ethanamine —— C20H18ClN5S2
    (1R)-N-[(4-chloro-2-phenylsulfanyl-1,3-thiazol-5-yl)methyl]-1-[4-(1,2,4-triazol-1-yl)phenyl]ethanamine
    —— [2-(Benzylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C19H24N4O3S2
    [2-(Benzylamino)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate