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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[4-Amino-3-[(4-methylphenyl)methylsulfanyl]-5-oxo-1,2,4-triazin-6-yl]propanoate —— C14H15N4O3S-
    3-[4-Amino-3-[(4-methylphenyl)methylsulfanyl]-5-oxo-1,2,4-triazin-6-yl]propanoate
    —— (2R)-1-ethoxy-3-pyrimidin-2-ylsulfanylpropan-2-ol —— C9H14N2O2S
    (2R)-1-ethoxy-3-pyrimidin-2-ylsulfanylpropan-2-ol
    —— (2S)-1-ethoxy-3-pyrimidin-2-ylsulfanylpropan-2-ol —— C9H14N2O2S
    (2S)-1-ethoxy-3-pyrimidin-2-ylsulfanylpropan-2-ol
    —— N-[(2S)-2-(4-methylpiperidin-1-yl)-2-thiophen-2-ylethyl]-2-phenylsulfanylacetamide —— C20H26N2OS2
    N-[(2S)-2-(4-methylpiperidin-1-yl)-2-thiophen-2-ylethyl]-2-phenylsulfanylacetamide
    —— N-[(2R)-2-(4-methylpiperidin-1-yl)-2-thiophen-2-ylethyl]-2-phenylsulfanylacetamide —— C20H26N2OS2
    N-[(2R)-2-(4-methylpiperidin-1-yl)-2-thiophen-2-ylethyl]-2-phenylsulfanylacetamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-piperidin-1-ylpropyl)propanamide —— C18H27ClN2OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-piperidin-1-ylpropyl)propanamide
    —— (2R)-1-(azepan-1-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one —— C14H20N2O2S
    (2R)-1-(azepan-1-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-piperidin-1-ylpropyl)propanamide —— C18H27ClN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-piperidin-1-ylpropyl)propanamide
    —— (2S)-N-(2-bromoprop-2-enyl)-2-propan-2-ylsulfonylpropanamide —— C9H16BrNO3S
    (2S)-N-(2-bromoprop-2-enyl)-2-propan-2-ylsulfonylpropanamide
    —— N-cyclopentyl-2-[4-(3,4-difluorophenyl)-3-oxopyrazin-2-yl]sulfanylacetamide —— C17H17F2N3O2S
    N-cyclopentyl-2-[4-(3,4-difluorophenyl)-3-oxopyrazin-2-yl]sulfanylacetamide
    —— 2-[4-(3,4-difluorophenyl)-3-oxopyrazin-2-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide —— C20H17F2N3O2S
    2-[4-(3,4-difluorophenyl)-3-oxopyrazin-2-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide
    —— 2-[4-(3-fluoro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide —— C21H20FN3O2S
    2-[4-(3-fluoro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide
    —— 2-[4-(4-Bromo-3-methylphenyl)-3-oxopyrazin-2-yl]sulfanylacetamide —— C13H12BrN3O2S
    2-[4-(4-Bromo-3-methylphenyl)-3-oxopyrazin-2-yl]sulfanylacetamide
    —— 2-[4-(3-chloro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-cyclopentylacetamide —— C18H20ClN3O2S
    2-[4-(3-chloro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-cyclopentylacetamide
    —— 2-((4-(3-chloro-4-methylphenyl)-3-oxo-3,4-dihydropyrazin-2-yl)thio)-N-phenethylacetamide —— C21H20ClN3O2S
    2-((4-(3-chloro-4-methylphenyl)-3-oxo-3,4-dihydropyrazin-2-yl)thio)-N-phenethylacetamide
    —— 2-((4-(3,4-difluorophenyl)-3-oxo-3,4-dihydropyrazin-2-yl)thio)-N-phenethylacetamide —— C20H17F2N3O2S
    2-((4-(3,4-difluorophenyl)-3-oxo-3,4-dihydropyrazin-2-yl)thio)-N-phenethylacetamide
    —— (2R)-N-(2-bromoprop-2-enyl)-2-propan-2-ylsulfonylpropanamide —— C9H16BrNO3S
    (2R)-N-(2-bromoprop-2-enyl)-2-propan-2-ylsulfonylpropanamide
    —— 2-[4-(3-chloro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide —— C21H20ClN3O2S
    2-[4-(3-chloro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide
    —— 1-(3,4-Difluorophenyl)-3-{[(3-fluorophenyl)methyl]sulfanyl}-1,2-dihydropyrazin-2-one —— C17H11F3N2OS
    1-(3,4-Difluorophenyl)-3-{[(3-fluorophenyl)methyl]sulfanyl}-1,2-dihydropyrazin-2-one
    —— N-cyclohexyl-2-[4-(3,4-difluorophenyl)-3-oxopyrazin-2-yl]sulfanylacetamide —— C18H19F2N3O2S
    N-cyclohexyl-2-[4-(3,4-difluorophenyl)-3-oxopyrazin-2-yl]sulfanylacetamide
    —— (2S)-1-(azepan-1-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one —— C14H20N2O2S
    (2S)-1-(azepan-1-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one
    —— 2-[4-(3-chloro-4-fluorophenyl)-3-oxopyrazin-2-yl]sulfanyl-N-cyclohexylacetamide —— C18H19ClFN3O2S
    2-[4-(3-chloro-4-fluorophenyl)-3-oxopyrazin-2-yl]sulfanyl-N-cyclohexylacetamide
    —— N-cyclohexyl-2-[4-(3-fluoro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanylacetamide —— C19H22FN3O2S
    N-cyclohexyl-2-[4-(3-fluoro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanylacetamide
    —— N-[(1S)-1-cyanoethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C11H11FN2OS
    N-[(1S)-1-cyanoethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— N-[(1R)-1-cyanoethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C11H11FN2OS
    N-[(1R)-1-cyanoethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— 2-[4-(3-Chloro-4-fluorophenyl)-3-oxopyrazin-2-yl]sulfanylacetamide —— C12H9ClFN3O2S
    2-[4-(3-Chloro-4-fluorophenyl)-3-oxopyrazin-2-yl]sulfanylacetamide
    —— 2-[4-(3-chloro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-cyclohexylacetamide —— C19H22ClN3O2S
    2-[4-(3-chloro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanyl-N-cyclohexylacetamide
    —— N-benzyl-2-[4-(3-fluoro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanylacetamide —— C20H18FN3O2S
    N-benzyl-2-[4-(3-fluoro-4-methylphenyl)-3-oxopyrazin-2-yl]sulfanylacetamide
    —— N-[(1R)-1-cyanoethyl]-3-phenylsulfanylpropanamide —— C12H14N2OS
    N-[(1R)-1-cyanoethyl]-3-phenylsulfanylpropanamide
    —— N-[(1S)-1-cyanoethyl]-2-(4-methylphenyl)sulfanylacetamide —— C12H14N2OS
    N-[(1S)-1-cyanoethyl]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(1S)-1-cyanoethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C13H18N4OS
    N-[(1S)-1-cyanoethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(1S)-1-cyanoethyl]-3-phenylsulfanylpropanamide —— C12H14N2OS
    N-[(1S)-1-cyanoethyl]-3-phenylsulfanylpropanamide
    —— N-[(1R)-1-cyanoethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C13H18N4OS
    N-[(1R)-1-cyanoethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(1R)-1-cyanoethyl]-2-(2-fluorophenyl)sulfanyl-5-nitrobenzamide —— C16H12FN3O3S
    N-[(1R)-1-cyanoethyl]-2-(2-fluorophenyl)sulfanyl-5-nitrobenzamide
    —— 3-(4-chlorophenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide —— C16H24ClN2O2S+
    3-(4-chlorophenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide
    —— N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H22FN3O2S
    N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S)-1-cyanoethyl]-2-(2-fluorophenyl)sulfanyl-5-nitrobenzamide —— C16H12FN3O3S
    N-[(1S)-1-cyanoethyl]-2-(2-fluorophenyl)sulfanyl-5-nitrobenzamide
    —— (2S)-2-(2,5-dimethylphenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide —— C19H23NOS
    (2S)-2-(2,5-dimethylphenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide
    —— N-(furan-2-ylmethyl)-N-methyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H21N3O3S
    N-(furan-2-ylmethyl)-N-methyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2R)-1-methoxypropan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C9H15N3O2S2
    N-[(2R)-1-methoxypropan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-morpholin-4-ylpropyl)propanamide —— C17H25ClN2O2S
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-morpholin-4-ylpropyl)propanamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H15ClN2OS2
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide —— C19H23NOS
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide
    —— N-(furan-2-ylmethyl)-N-methyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H21N3O3S
    N-(furan-2-ylmethyl)-N-methyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-(2-chlorophenyl)-5-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C20H17ClN4O2S
    2-(2-chlorophenyl)-5-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-morpholin-4-ylpropyl)propanamide —— C17H25ClN2O2S
    (2S)-2-(4-chlorophenyl)sulfanyl-N-(2-methyl-2-morpholin-4-ylpropyl)propanamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H15ClN2OS2
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-[(2S)-1-methoxypropan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C9H15N3O2S2
    N-[(2S)-1-methoxypropan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H22FN3O2S
    N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C14H18N4OS2
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide