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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-cyclopropyl-4-(furan-2-ylmethyl)-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C18H19N3OS
    3-cyclopropyl-4-(furan-2-ylmethyl)-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— 3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C15H18ClN3O2S
    3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— tert-butyl 2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C17H22N2O3S
    tert-butyl 2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— 2-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C16H17N3OS2
    2-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide —— C19H27N3O2S
    2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide
    —— [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C15H20ClNO4S
    [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— 4-[[(2S)-oxolan-2-yl]methyl]-3-prop-2-enylsulfanyl-1H-1,2,4-triazol-5-one —— C10H15N3O2S
    4-[[(2S)-oxolan-2-yl]methyl]-3-prop-2-enylsulfanyl-1H-1,2,4-triazol-5-one
    —— (2R)-N-cyclopropyl-2-(3,4-dimethylphenyl)sulfanylpropanamide —— C14H19NOS
    (2R)-N-cyclopropyl-2-(3,4-dimethylphenyl)sulfanylpropanamide
    —— 1-(azepan-1-yl)-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C19H25N3O2S
    1-(azepan-1-yl)-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H22ClNO5S2
    [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H28N4O3S
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— [(2S)-1-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H22ClNO5S2
    [(2S)-1-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— (2R)-N-cyclopropyl-2-(2,5-dimethylphenyl)sulfanylpropanamide —— C14H19NOS
    (2R)-N-cyclopropyl-2-(2,5-dimethylphenyl)sulfanylpropanamide
    —— 4-methyl-3-(2-methylfuran-3-yl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazole —— C13H17N3O2S
    4-methyl-3-(2-methylfuran-3-yl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazole
    —— 1-(azepan-1-yl)-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C19H25N3O2S
    1-(azepan-1-yl)-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C14H17F2NO3S2
    2-(3,4-difluorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-cyclopropyl-4-prop-2-enyl-1,2,4-triazole —— C16H18ClN3S
    3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-cyclopropyl-4-prop-2-enyl-1,2,4-triazole
    —— [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H18ClNO3S2
    [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— N-(1-methylpiperidin-4-yl)-4-phenylsulfanylbutanamide —— C16H24N2OS
    N-(1-methylpiperidin-4-yl)-4-phenylsulfanylbutanamide
    —— (2R)-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide —— C13H17F3N4OS
    (2R)-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide
    —— (2S)-N-cyclohexyl-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C18H28N4OS
    (2S)-N-cyclohexyl-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— (2R)-N-cyclohexyl-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C18H28N4OS
    (2R)-N-cyclohexyl-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— 3-methyl-5-[(1R)-1-phenylethyl]sulfanyl-4-prop-2-enyl-1,2,4-triazole —— C14H17N3S
    3-methyl-5-[(1R)-1-phenylethyl]sulfanyl-4-prop-2-enyl-1,2,4-triazole
    —— (3-Thiophen-3-yl-1,2,4-oxadiazol-5-yl)methyl 3-(4-chlorophenyl)sulfanylpropanoate —— C16H13ClN2O3S2
    (3-Thiophen-3-yl-1,2,4-oxadiazol-5-yl)methyl 3-(4-chlorophenyl)sulfanylpropanoate
    —— 3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5-methyl-4-prop-2-enyl-1,2,4-triazole —— C14H16ClN3S
    3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5-methyl-4-prop-2-enyl-1,2,4-triazole
    —— 5-[[(2S)-oxolan-2-yl]methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione —— C13H14N2OS3
    5-[[(2S)-oxolan-2-yl]methylsulfanyl]-3-phenyl-1,3,4-thiadiazole-2-thione
    —— 2-cyclohexyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C12H16N4O2S
    2-cyclohexyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-(1-methylpiperidin-4-yl)propanamide —— C15H21ClN2OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-(1-methylpiperidin-4-yl)propanamide
    —— 1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C14H22N4O2S
    1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (2S)-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide —— C13H17F3N4OS
    (2S)-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide
    —— 2-methyl-1-[(4-methylsulfanylphenyl)methyl]-3-[[(2S)-oxolan-2-yl]methyl]guanidine —— C15H23N3OS
    2-methyl-1-[(4-methylsulfanylphenyl)methyl]-3-[[(2S)-oxolan-2-yl]methyl]guanidine
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(1-methylpiperidin-4-yl)propanamide —— C15H21ClN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(1-methylpiperidin-4-yl)propanamide
    —— 1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C14H22N4O2S
    1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-methyl-4-prop-2-enyl-1,2,4-triazole —— C14H16ClN3S
    3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-methyl-4-prop-2-enyl-1,2,4-triazole
    —— (1S)-N-[2-(4-methylphenyl)sulfanylethyl]cyclohex-3-ene-1-carboxamide —— C16H21NOS
    (1S)-N-[2-(4-methylphenyl)sulfanylethyl]cyclohex-3-ene-1-carboxamide
    —— 1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C14H22N4O2S
    1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 3-methyl-5-[(1S)-1-phenylethyl]sulfanyl-4-prop-2-enyl-1,2,4-triazole —— C14H17N3S
    3-methyl-5-[(1S)-1-phenylethyl]sulfanyl-4-prop-2-enyl-1,2,4-triazole
    —— 2-[(1S)-1-(4-fluorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C14H11FN2OS2
    2-[(1S)-1-(4-fluorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1S)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C16H16N2OS2
    2-[(1S)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1S)-1-(4-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C15H14N2OS2
    2-[(1S)-1-(4-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-methyl-1-[(4-methylsulfanylphenyl)methyl]-3-[[(2R)-oxolan-2-yl]methyl]guanidine —— C15H23N3OS
    2-methyl-1-[(4-methylsulfanylphenyl)methyl]-3-[[(2R)-oxolan-2-yl]methyl]guanidine
    —— 4-cyclopropyl-3-[(1R)-1-phenylethyl]sulfanyl-5-thiophen-2-yl-1,2,4-triazole —— C17H17N3S2
    4-cyclopropyl-3-[(1R)-1-phenylethyl]sulfanyl-5-thiophen-2-yl-1,2,4-triazole
    —— 2-[(1R)-1-(2-fluorophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C16H13FN2OS
    2-[(1R)-1-(2-fluorophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— (2R)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide —— C14H18N4OS3
    (2R)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide
    —— 2-[(1S)-1-(1-methylimidazol-2-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C14H14N4OS
    2-[(1S)-1-(1-methylimidazol-2-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(1S)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C18H18N2OS
    2-[(1S)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— 4-cyclopropyl-3-[(1S)-1-phenylethyl]sulfanyl-5-thiophen-2-yl-1,2,4-triazole —— C17H17N3S2
    4-cyclopropyl-3-[(1S)-1-phenylethyl]sulfanyl-5-thiophen-2-yl-1,2,4-triazole
    —— [(2S)-1-(tert-butylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C16H22ClNO3S
    [(2S)-1-(tert-butylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2R)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C15H20ClNO4S
    [(2R)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2S)-1-(methoxycarbonylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C14H16ClNO5S
    [(2S)-1-(methoxycarbonylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate