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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-chlorophenyl)sulfanylethyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate —— C17H18ClNO3S
    2-(4-chlorophenyl)sulfanylethyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate
    —— [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C16H16ClN3O5S
    [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— 4-O-[2-(4-chlorophenyl)sulfanylethyl] 2-O-ethyl 3,5-dimethyl-1H-pyrrole-2,4-dicarboxylate —— C18H20ClNO4S
    4-O-[2-(4-chlorophenyl)sulfanylethyl] 2-O-ethyl 3,5-dimethyl-1H-pyrrole-2,4-dicarboxylate
    —— 2-O-[2-(4-chlorophenyl)sulfanylethyl] 4-O-ethyl 3,5-dimethyl-1H-pyrrole-2,4-dicarboxylate —— C18H20ClNO4S
    2-O-[2-(4-chlorophenyl)sulfanylethyl] 4-O-ethyl 3,5-dimethyl-1H-pyrrole-2,4-dicarboxylate
    —— 3-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-5-(trifluoromethyl)-1,2,4-triazol-4-amine —— C11H9F3N6OS2
    3-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-5-(trifluoromethyl)-1,2,4-triazol-4-amine
    —— 3-[(1S)-4-methylsulfonyl-6-oxocyclohexa-2,4-dien-1-yl]propanoic acid —— C10H12O5S
    3-[(1S)-4-methylsulfonyl-6-oxocyclohexa-2,4-dien-1-yl]propanoic acid
    —— [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C17H18ClN3O5S
    [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 3-phenylsulfanylpropanoate —— C16H17N3O5S
    [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— N-benzyl-5-[(1-butyltetrazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N7S2
    N-benzyl-5-[(1-butyltetrazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C15H18BrNO3S2
    2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 6-Amino-1-methyl-5-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]pyrimidine-2,4-dione —— C12H12N4O4S
    6-Amino-1-methyl-5-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]pyrimidine-2,4-dione
    —— 1-butyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)tetrazole —— C8H13N7S
    1-butyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)tetrazole
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H16N4O3S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-[(1R)-1-(1-oxidopyridin-1-ium-2-yl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H11N3O2S2
    2-[(1R)-1-(1-oxidopyridin-1-ium-2-yl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1S)-1-(1-oxidopyridin-1-ium-2-yl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H11N3O2S2
    2-[(1S)-1-(1-oxidopyridin-1-ium-2-yl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C11H17N5O3S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C11H17N5O3S2
    N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— [2-[4-(2,5-dimethylphenyl)sulfanylanilino]-2-oxoethyl] (E)-but-2-enoate —— C20H21NO3S
    [2-[4-(2,5-dimethylphenyl)sulfanylanilino]-2-oxoethyl] (E)-but-2-enoate
    —— (6R)-2,6-diamino-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-5,6,7,8-tetrahydroquinoline-3-carbonitrile —— C17H17N7OS
    (6R)-2,6-diamino-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-5,6,7,8-tetrahydroquinoline-3-carbonitrile
    —— (3S)-3-[[(3S)-1-hydroxyhexan-3-yl]disulfanyl]hexan-1-ol —— C12H26O2S2
    (3S)-3-[[(3S)-1-hydroxyhexan-3-yl]disulfanyl]hexan-1-ol
    —— (6S)-2,6-diamino-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-5,6,7,8-tetrahydroquinoline-3-carbonitrile —— C17H17N7OS
    (6S)-2,6-diamino-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-5,6,7,8-tetrahydroquinoline-3-carbonitrile
    —— (Z)-N-(3-benzylsulfanyl-5-propyl-1,2,4-triazol-4-yl)-1-(2-methylphenyl)methanimine —— C20H22N4S
    (Z)-N-(3-benzylsulfanyl-5-propyl-1,2,4-triazol-4-yl)-1-(2-methylphenyl)methanimine
    —— (3R)-3-[[(3R)-1-hydroxyhexan-3-yl]disulfanyl]hexan-1-ol —— C12H26O2S2
    (3R)-3-[[(3R)-1-hydroxyhexan-3-yl]disulfanyl]hexan-1-ol
    —— 2-methylsulfanyl-5-[1-[(2R)-1-pyridin-3-ylpropan-2-yl]imidazol-2-yl]pyrimidine —— C16H17N5S
    2-methylsulfanyl-5-[1-[(2R)-1-pyridin-3-ylpropan-2-yl]imidazol-2-yl]pyrimidine
    —— (3S)-3-[[(3R)-1-hydroxyhexan-3-yl]disulfanyl]hexan-1-ol —— C12H26O2S2
    (3S)-3-[[(3R)-1-hydroxyhexan-3-yl]disulfanyl]hexan-1-ol
    —— 2-methylsulfanyl-5-[1-[(2S)-1-pyridin-3-ylpropan-2-yl]imidazol-2-yl]pyrimidine —— C16H17N5S
    2-methylsulfanyl-5-[1-[(2S)-1-pyridin-3-ylpropan-2-yl]imidazol-2-yl]pyrimidine
    —— [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (E)-but-2-enoate —— C18H16ClNO3S
    [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (E)-but-2-enoate
    —— 5-[(1-Butyltetrazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C8H13N7S2
    5-[(1-Butyltetrazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C15H18ClNO3S2
    2-(4-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 6-Amino-5-[2-(4-chlorophenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione —— C13H12ClN3O3S
    6-Amino-5-[2-(4-chlorophenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione
    —— 3,3-Diethyl-7,8-dimethyl-1,5-dihydro-2,4-benzodithiepine —— C15H22S2
    3,3-Diethyl-7,8-dimethyl-1,5-dihydro-2,4-benzodithiepine
    —— ethyl (Z)-3-(4-bromophenyl)sulfanyl-2-cyano-3-methylsulfanylprop-2-enoate —— C13H12BrNO2S2
    ethyl (Z)-3-(4-bromophenyl)sulfanyl-2-cyano-3-methylsulfanylprop-2-enoate
    —— 4-[(4-Chloro-3-methylphenyl)sulfanylmethyl]-1,3-thiazol-2-amine —— C11H11ClN2S2
    4-[(4-Chloro-3-methylphenyl)sulfanylmethyl]-1,3-thiazol-2-amine
    —— 1-(1,4-Diazepan-1-yl)-3-thiophen-2-ylsulfanylpropan-1-one —— C12H18N2OS2
    1-(1,4-Diazepan-1-yl)-3-thiophen-2-ylsulfanylpropan-1-one
    —— [(1R)-2-[[2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium —— C16H23N4OS3+
    [(1R)-2-[[2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium
    —— N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C16H22N4OS3
    N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C15H18FN3OS3
    (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H20N4OS3
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-cyclopropyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C10H15N3OS3
    (2S)-N-cyclopropyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-methylpropyl)acetamide —— C10H17N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-methylpropyl)acetamide
    —— ethyl N-[2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]carbamate —— C9H13N3O3S3
    ethyl N-[2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]carbamate
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylacetamide —— C7H11N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylacetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C10H15N3O3S4
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C12H15N3OS4
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H15F2N3OS3
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-cyclopentyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C12H19N3OS3
    (2R)-N-cyclopentyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H23N3OS3
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C18H27N3OS3
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-(1-cyanocyclohexyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H18N4OS3
    N-(1-cyanocyclohexyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H20N4OS3
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide