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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide —— C16H23N3OS
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C18H25N3OS
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-[5-[2-[(4-Methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]thiophen-2-yl]-1-morpholin-4-ylethanone —— C15H18N4O3S2
    2-[5-[2-[(4-Methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]thiophen-2-yl]-1-morpholin-4-ylethanone
    —— N-(2-benzylsulfanylethyl)-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C21H27NOS2
    N-(2-benzylsulfanylethyl)-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide —— C13H17N5OS2
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide
    —— N-(2-benzylsulfanylethyl)-2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanylacetamide —— C20H23N3OS2
    N-(2-benzylsulfanylethyl)-2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanylacetamide
    —— 1-cyclopropyl-2-[(2R)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanylpyrimidin-4-one —— C14H19N3O2S
    1-cyclopropyl-2-[(2R)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanylpyrimidin-4-one
    —— 1-cyclopropyl-2-[(2S)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanylpyrimidin-4-one —— C14H19N3O2S
    1-cyclopropyl-2-[(2S)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanylpyrimidin-4-one
    —— N-(2-benzylsulfanylethyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C15H18N2OS3
    N-(2-benzylsulfanylethyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— [2-(2-Benzylsulfanylethylamino)-2-oxoethyl] 2-phenylsulfanylacetate —— C19H21NO3S2
    [2-(2-Benzylsulfanylethylamino)-2-oxoethyl] 2-phenylsulfanylacetate
    —— [(1S)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]azanium —— C12H16N3OS+
    [(1S)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]azanium
    —— N-(2-benzylsulfanylethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H23N3O2S2
    N-(2-benzylsulfanylethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-(2-benzylsulfanylethyl)-2-(2,4-dimethylphenyl)sulfanylacetamide —— C19H23NOS2
    N-(2-benzylsulfanylethyl)-2-(2,4-dimethylphenyl)sulfanylacetamide
    —— N-(2-benzylsulfanylethyl)-2-(2,5-dimethylphenyl)sulfanylacetamide —— C19H23NOS2
    N-(2-benzylsulfanylethyl)-2-(2,5-dimethylphenyl)sulfanylacetamide
    —— N-(cyclohexen-1-yl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C23H25N3O3S
    N-(cyclohexen-1-yl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— N-(cyclohexen-1-yl)-N-(furan-2-ylmethyl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C21H24N4O3S
    N-(cyclohexen-1-yl)-N-(furan-2-ylmethyl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]methanesulfonamide —— C12H19NO3S2
    N-[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]methanesulfonamide
    —— 2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-benzylsulfanylethyl)acetamide —— C17H19N5O2S2
    2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-benzylsulfanylethyl)acetamide
    —— 2-(3-methylthiophen-2-yl)-5-[(1S)-1-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C14H16N4O2S2
    2-(3-methylthiophen-2-yl)-5-[(1S)-1-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— N-[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]methanesulfonamide —— C12H19NO3S2
    N-[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]methanesulfonamide
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone —— C17H24N2O3S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone
    —— (2S)-1-[(3S)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C16H21N5OS
    (2S)-1-[(3S)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2S)-1-[(3R)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C16H21N5OS
    (2S)-1-[(3R)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— N-(2-benzylsulfanylethyl)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C17H17N3O2S3
    N-(2-benzylsulfanylethyl)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-1-[(3S)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C16H21N5OS
    (2R)-1-[(3S)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2R)-1-[(3R)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C16H21N5OS
    (2R)-1-[(3R)-3-anilinopyrrolidin-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone —— C17H24N2O3S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone
    —— (1R)-2,2-dichloro-1-methyl-N-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]cyclopropane-1-carboxamide —— C16H16Cl2N2OS2
    (1R)-2,2-dichloro-1-methyl-N-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]cyclopropane-1-carboxamide
    —— (1S)-2,2-dichloro-1-methyl-N-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]cyclopropane-1-carboxamide —— C16H16Cl2N2OS2
    (1S)-2,2-dichloro-1-methyl-N-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]cyclopropane-1-carboxamide
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone —— C17H24N2O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone —— C17H24N2O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[4-(2-hydroxy-2-methylpropyl)piperazin-1-yl]methanone
    —— 4-[4-ethyl-5-[(1R)-1-pyridin-4-ylethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine —— C15H21N5OS
    4-[4-ethyl-5-[(1R)-1-pyridin-4-ylethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine
    —— tert-butyl N-[(1S)-1-[5-[2-(dimethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]-2-methylpropyl]carbamate —— C15H26N4O4S
    tert-butyl N-[(1S)-1-[5-[2-(dimethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]-2-methylpropyl]carbamate
    —— 4-[5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-4-ethyl-1,2,4-triazol-3-yl]morpholine —— C13H22N4O3S
    4-[5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-4-ethyl-1,2,4-triazol-3-yl]morpholine
    —— N-(2-benzylsulfanylethyl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H19N3O2S2
    N-(2-benzylsulfanylethyl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 3-[[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]amino]pyrazine-2-carbonitrile —— C16H18N4OS
    3-[[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]amino]pyrazine-2-carbonitrile
    —— 3-[[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]amino]pyrazine-2-carbonitrile —— C16H18N4OS
    3-[[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]amino]pyrazine-2-carbonitrile
    —— (2S)-N-benzyl-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H25N5OS
    (2S)-N-benzyl-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[5-[2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]thiophen-2-yl]-1-morpholin-4-ylethanone —— C16H20N4O3S2
    2-[5-[2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]thiophen-2-yl]-1-morpholin-4-ylethanone
    —— (2R)-N-benzyl-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H25N5OS
    (2R)-N-benzyl-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— [2-(Azepan-1-yl)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H28N4O3S2
    [2-(Azepan-1-yl)-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H24N4O3S2
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H25N5O3S2
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C19H30N4O3S2
    [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(2S)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C17H26N4O3S2
    [(2S)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H28N4O3S2
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[Bis(prop-2-enyl)amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H26N4O3S2
    [2-[Bis(prop-2-enyl)amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— (3,3-Dimethyl-2-oxobutyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H25N3O3S2
    (3,3-Dimethyl-2-oxobutyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— 2-Oxopropyl 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C13H19N3O3S2
    2-Oxopropyl 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C18H25N5O3S2
    [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate