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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(1-Adamantyl)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C20H21FN2O2S
    1-(1-Adamantyl)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C22H26FN3O2S
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-butan-2-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H16FN3O2S
    N-[(2S)-butan-2-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H22FN3O2S
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[(3,5-Dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C14H12FN3O2S
    2-[(3,5-Dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-chlorophenyl)ethyl]acetamide —— C16H16ClN5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-chlorophenyl)ethyl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]acetamide —— C12H17N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]acetamide
    —— 3-[(4-Methylsulfanylphenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine —— C14H14N4S3
    3-[(4-Methylsulfanylphenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C16H17N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cycloheptylacetamide —— C15H21N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cycloheptylacetamide
    —— (2S)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopentylpropanamide —— C14H19N5OS2
    (2S)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopentylpropanamide
    —— 3-[(2-Fluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine —— C13H11FN4S2
    3-[(2-Fluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C16H17N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(4-chlorophenyl)ethyl]acetamide —— C16H16ClN5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(4-chlorophenyl)ethyl]acetamide
    —— 3-[(2-Bromophenyl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazol-4-amine —— C13H11BrN4OS
    3-[(2-Bromophenyl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazol-4-amine
    —— 3-[(3-Bromophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine —— C13H11BrN4S2
    3-[(3-Bromophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine
    —— N-(1-adamantylmethyl)-2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H25N5O2S
    N-(1-adamantylmethyl)-2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-Thiophen-2-yl-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C14H11N5OS3
    3-Thiophen-2-yl-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C20H27N5OS2
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-pentan-3-ylacetamide —— C13H19N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-pentan-3-ylacetamide
    —— N-(1-adamantylmethyl)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C19H25N5OS2
    N-(1-adamantylmethyl)-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide —— C15H14ClN5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide
    —— 2-[(1-amino-5-methyl-1H-imidazol-2-yl)sulfanyl]-6-bromo-7-methyl-5H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C10H9BrN6OS2
    2-[(1-amino-5-methyl-1H-imidazol-2-yl)sulfanyl]-6-bromo-7-methyl-5H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— (4S)-4,6-dimethyl-2-oxo-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C11H16N6O2S
    (4S)-4,6-dimethyl-2-oxo-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— (4R)-4,6-dimethyl-2-oxo-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C11H16N6O2S
    (4R)-4,6-dimethyl-2-oxo-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— 3,6-Dimethyl-5-[(2-methylphenyl)methyl]-2-{[(2-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one —— C22H24N2OS
    3,6-Dimethyl-5-[(2-methylphenyl)methyl]-2-{[(2-methylphenyl)methyl]sulfanyl}-3,4-dihydropyrimidin-4-one
    —— (4S)-2-amino-4-[4-[(1-methyltetrazol-5-yl)sulfanylmethyl]thiophen-2-yl]-5-oxo-4,6,7,8-tetrahydrochromene-3-carbonitrile —— C17H16N6O2S2
    (4S)-2-amino-4-[4-[(1-methyltetrazol-5-yl)sulfanylmethyl]thiophen-2-yl]-5-oxo-4,6,7,8-tetrahydrochromene-3-carbonitrile
    —— (4R)-2-amino-4-[4-[(1-methyltetrazol-5-yl)sulfanylmethyl]thiophen-2-yl]-5-oxo-4,6,7,8-tetrahydrochromene-3-carbonitrile —— C17H16N6O2S2
    (4R)-2-amino-4-[4-[(1-methyltetrazol-5-yl)sulfanylmethyl]thiophen-2-yl]-5-oxo-4,6,7,8-tetrahydrochromene-3-carbonitrile
    —— 1-[(1S)-1-ethyl-3,4-dihydro-1H-pyrrolo[1,2-a]pyrazin-2-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one —— C15H20N4OS2
    1-[(1S)-1-ethyl-3,4-dihydro-1H-pyrrolo[1,2-a]pyrazin-2-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one
    —— 1-[(1R)-1-ethyl-3,4-dihydro-1H-pyrrolo[1,2-a]pyrazin-2-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one —— C15H20N4OS2
    1-[(1R)-1-ethyl-3,4-dihydro-1H-pyrrolo[1,2-a]pyrazin-2-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one
    —— 6-Tert-butyl-2-[(4-fluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one —— C16H19FN2OS
    6-Tert-butyl-2-[(4-fluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one
    —— 6-Ethyl-3-methyl-5-[(3-methylphenyl)methyl]-2-[(4-methylphenyl)methylsulfanyl]pyrimidin-4-one —— C23H26N2OS
    6-Ethyl-3-methyl-5-[(3-methylphenyl)methyl]-2-[(4-methylphenyl)methylsulfanyl]pyrimidin-4-one
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2S)-2-phenylcyclopropyl]acetamide —— C19H20N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2S)-2-phenylcyclopropyl]acetamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-phenylcyclopropyl]acetamide —— C19H20N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-phenylcyclopropyl]acetamide
    —— N-[(1R,2S)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide —— C18H19NOS
    N-[(1R,2S)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide
    —— N-[(1R,2R)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide —— C18H19NOS
    N-[(1R,2R)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide
    —— N-[(1S,2R)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide —— C18H19NOS
    N-[(1S,2R)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R)-2-phenylcyclopropyl]acetamide —— C19H20N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R)-2-phenylcyclopropyl]acetamide
    —— N-[(1R,2R)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(1R,2R)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-Benzylsulfanyl-3-methyl-6-propylpyrimidin-4-one —— C15H18N2OS
    2-Benzylsulfanyl-3-methyl-6-propylpyrimidin-4-one
    —— N-[(1S,2S)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(1S,2S)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2S)-2-phenylcyclopropyl]acetamide —— C19H20N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2S)-2-phenylcyclopropyl]acetamide
    —— N-[(1S,2R)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(1S,2R)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R,2S)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(1R,2S)-2-phenylcyclopropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S,2S)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide —— C18H19NOS
    N-[(1S,2S)-2-phenylcyclopropyl]-3-phenylsulfanylpropanamide
    —— (2R)-2-methyl-N-[2-(2H-triazol-4-ylsulfanyl)ethyl]oxane-2-carboxamide —— C11H18N4O2S
    (2R)-2-methyl-N-[2-(2H-triazol-4-ylsulfanyl)ethyl]oxane-2-carboxamide
    —— (2S)-2-methyl-N-[2-(2H-triazol-4-ylsulfanyl)ethyl]oxane-2-carboxamide —— C11H18N4O2S
    (2S)-2-methyl-N-[2-(2H-triazol-4-ylsulfanyl)ethyl]oxane-2-carboxamide
    —— N,N-di(propan-2-yl)-2-(1,4,5-trimethyl-6-oxopyrimidin-2-yl)sulfanylacetamide —— C15H25N3O2S
    N,N-di(propan-2-yl)-2-(1,4,5-trimethyl-6-oxopyrimidin-2-yl)sulfanylacetamide
    —— 2-[(2,4-Difluorophenyl)methylsulfanyl]-3,5,6-trimethylpyrimidin-4-one —— C14H14F2N2OS
    2-[(2,4-Difluorophenyl)methylsulfanyl]-3,5,6-trimethylpyrimidin-4-one
    —— 3-[(4-chlorophenyl)methyl]-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C17H13ClN4S
    3-[(4-chlorophenyl)methyl]-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine