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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-1-[[(2S)-oxolan-2-yl]methyl]tetrazole —— C15H19ClN4OS2
    5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-1-[[(2S)-oxolan-2-yl]methyl]tetrazole
    —— 5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C16H20ClN3OS3
    5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— (3R)-3-[[5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide —— C17H22ClN3O2S3
    (3R)-3-[[5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide
    —— (3S)-3-[[5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]thiolane 1,1-dioxide —— C16H19ClN2O3S3
    (3S)-3-[[5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]thiolane 1,1-dioxide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H27N5OS
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C16H20ClN3OS3
    5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— (3R)-3-[5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C16H20ClN3O2S3
    (3R)-3-[5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H27N5OS
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(1R,2S)-2-methylcyclopropyl]propanamide —— C13H16BrNOS
    3-(4-bromophenyl)sulfanyl-N-[(1R,2S)-2-methylcyclopropyl]propanamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(1S,2S)-2-methylcyclopropyl]propanamide —— C13H16BrNOS
    3-(4-bromophenyl)sulfanyl-N-[(1S,2S)-2-methylcyclopropyl]propanamide
    —— N-(2-methylphenyl)-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)acetamide —— C18H15N5OS2
    N-(2-methylphenyl)-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)acetamide
    —— 2-((2-(tert-Butyl)-6,8-dimethyl-5,7-dioxo-5,6,7,8-tetrahydropyrimido[4,5-d]pyrimidin-4-yl)thio)-N-cyclohexylacetamide —— C20H29N5O3S
    2-((2-(tert-Butyl)-6,8-dimethyl-5,7-dioxo-5,6,7,8-tetrahydropyrimido[4,5-d]pyrimidin-4-yl)thio)-N-cyclohexylacetamide
    —— 3-Tert-butyl-7-[(3,5-dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H17N5O2S2
    3-Tert-butyl-7-[(3,5-dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclopropyl]benzamide —— C18H16N2OS
    2-(2-cyanophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclopropyl]benzamide
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1S,2R)-2-methylcyclopropyl]benzamide —— C18H16N2OS
    2-(2-cyanophenyl)sulfanyl-N-[(1S,2R)-2-methylcyclopropyl]benzamide
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1S,2S)-2-methylcyclopropyl]benzamide —— C18H16N2OS
    2-(2-cyanophenyl)sulfanyl-N-[(1S,2S)-2-methylcyclopropyl]benzamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclopropyl]propanamide —— C13H16BrNOS
    3-(4-bromophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclopropyl]propanamide
    —— 5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-1-[[(2R)-oxolan-2-yl]methyl]tetrazole —— C15H19ClN4OS2
    5-[3-(2-chlorophenyl)sulfanylpropylsulfanyl]-1-[[(2R)-oxolan-2-yl]methyl]tetrazole
    —— 3-(4-bromophenyl)sulfanyl-N-[(1S,2R)-2-methylcyclopropyl]propanamide —— C13H16BrNOS
    3-(4-bromophenyl)sulfanyl-N-[(1S,2R)-2-methylcyclopropyl]propanamide
    —— 2-(3,4-Dimethylphenyl)sulfanyl-4,7-dimethylquinoline —— C19H19NS
    2-(3,4-Dimethylphenyl)sulfanyl-4,7-dimethylquinoline
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[[5-methyl-4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H28N4OS2
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[[5-methyl-4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-Amino-4-(cyanomethyl)-6-[4-(difluoromethylsulfanyl)anilino]pyridine-3,5-dicarbonitrile —— C16H10F2N6S
    2-Amino-4-(cyanomethyl)-6-[4-(difluoromethylsulfanyl)anilino]pyridine-3,5-dicarbonitrile
    —— 2-Amino-4-(cyanomethyl)-6-[4-(difluoromethylsulfanyl)anilino]pyridin-1-ium-3,5-dicarbonitrile —— C16H11F2N6S+
    2-Amino-4-(cyanomethyl)-6-[4-(difluoromethylsulfanyl)anilino]pyridin-1-ium-3,5-dicarbonitrile
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[[5-methyl-4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H28N4OS2
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[[5-methyl-4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— methyl (2S)-2-[[5-[(4-fluorophenyl)methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate —— C16H20FN3O2S2
    methyl (2S)-2-[[5-[(4-fluorophenyl)methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate
    —— methyl (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate —— C15H21N3O3S
    methyl (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate
    —— methyl (2R)-2-(4,6-diaminopyrimidin-2-yl)sulfanylhexanoate —— C11H18N4O2S
    methyl (2R)-2-(4,6-diaminopyrimidin-2-yl)sulfanylhexanoate
    —— methyl (2R)-2-[[5-[(4-fluorophenyl)methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate —— C16H20FN3O2S2
    methyl (2R)-2-[[5-[(4-fluorophenyl)methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate
    —— methyl (2R)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate —— C15H25N3O2S2
    methyl (2R)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate
    —— methyl (2R)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate —— C12H21N3O2S2
    methyl (2R)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate
    —— methyl (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate —— C15H21N3O3S
    methyl (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]hexanoate
    —— methyl (2S)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate —— C12H21N3O2S2
    methyl (2S)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate
    —— methyl (2S)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate —— C15H25N3O2S2
    methyl (2S)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]hexanoate
    —— 2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C16H18N4O2S
    2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— 4-[[5-(Furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylbutan-1-one —— C15H20N4O3S
    4-[[5-(Furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylbutan-1-one
    —— (5-Thiophen-2-yl-1,3,4-oxadiazol-2-yl)methyl 2-(4-chlorophenyl)sulfanylacetate —— C15H11ClN2O3S2
    (5-Thiophen-2-yl-1,3,4-oxadiazol-2-yl)methyl 2-(4-chlorophenyl)sulfanylacetate
    —— 2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-cyclopropylacetamide —— C14H15N3O2S
    2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-cyclopropylacetamide
    —— 2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1S)-1-(3-chlorophenyl)ethyl]acetamide —— C19H18ClN3O2S
    2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1S)-1-(3-chlorophenyl)ethyl]acetamide
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]ethanone —— C20H18N4O2S2
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]ethanone
    —— Methyl 3-[3-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate —— C21H23N3O4S
    Methyl 3-[3-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(5-bromothiophen-2-yl)ethanone —— C15H11BrN2O2S2
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(5-bromothiophen-2-yl)ethanone
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]ethanone —— C21H20N4O3S
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]ethanone
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone —— C15H11ClN2O2S2
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone
    —— 6-Amino-5-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione —— C18H19N5O4S
    6-Amino-5-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione
    —— (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C20H20FN3O2S
    (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— (2S)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C20H20FN3O2S
    (2S)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(1-ethyl-2,5-dimethylpyrrol-3-yl)ethanone —— C19H21N3O2S
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(1-ethyl-2,5-dimethylpyrrol-3-yl)ethanone
    —— 2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(1-cyanocyclohexyl)acetamide —— C18H20N4O2S
    2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(1-cyanocyclohexyl)acetamide
    —— 2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C15H17N3O4S2
    2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— ethyl N-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]carbamate —— C14H15N3O4S
    ethyl N-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]carbamate