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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-tert-butyl-1-methyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-di(propan-2-yl)acetamide —— C17H29N3O2S
    2-(4-tert-butyl-1-methyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-di(propan-2-yl)acetamide
    —— 2-phenylsulfanyl-N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]acetamide —— C18H16N2OS2
    2-phenylsulfanyl-N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]acetamide
    —— 2-phenylsulfanyl-N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]acetamide —— C18H16N2OS2
    2-phenylsulfanyl-N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]acetamide
    —— (2R)-2-(2,5-dimethylphenyl)sulfanyl-N,N-dimethylpropanamide —— C13H19NOS
    (2R)-2-(2,5-dimethylphenyl)sulfanyl-N,N-dimethylpropanamide
    —— N-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-1-methylpyrazole-4-sulfonamide —— C14H19N3O2S2
    N-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-1-methylpyrazole-4-sulfonamide
    —— (2S)-N-benzyl-N-(2,2-dimethylpropyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H26N4OS
    (2S)-N-benzyl-N-(2,2-dimethylpropyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1-methyl-5-oxopyrrolidin-3-yl]propanamide —— C14H17ClN2O2S
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1-methyl-5-oxopyrrolidin-3-yl]propanamide
    —— (2R,6R)-4-[2-(4-chlorophenyl)sulfanylethyl]-2,6-dimethylmorpholin-4-ium —— C14H21ClNOS+
    (2R,6R)-4-[2-(4-chlorophenyl)sulfanylethyl]-2,6-dimethylmorpholin-4-ium
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1-methyl-5-oxopyrrolidin-3-yl]propanamide —— C14H17ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1-methyl-5-oxopyrrolidin-3-yl]propanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1-methyl-5-oxopyrrolidin-3-yl]propanamide —— C14H17ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1-methyl-5-oxopyrrolidin-3-yl]propanamide
    —— N-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-1-methylpyrazole-4-sulfonamide —— C14H19N3O2S2
    N-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-1-methylpyrazole-4-sulfonamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1-methyl-5-oxopyrrolidin-3-yl]propanamide —— C14H17ClN2O2S
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1-methyl-5-oxopyrrolidin-3-yl]propanamide
    —— N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20ClN3O2S
    N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(3-Bromophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole —— C17H15BrN2OS
    2-[(3-Bromophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole
    —— 2-[(2-Bromophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole —— C17H15BrN2OS
    2-[(2-Bromophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20ClN3O2S
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C22H25N3O2S
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20ClN3O2S
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-[(4,6-dimethyl-2-oxo-1H-pyridin-3-yl)methyl]-3-methyl-2-phenylsulfanylbutanamide —— C19H24N2O2S
    (2S)-N-[(4,6-dimethyl-2-oxo-1H-pyridin-3-yl)methyl]-3-methyl-2-phenylsulfanylbutanamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C22H25N3O2S
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C16H18N2O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C23H27N3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— (2R)-N-[(4,6-dimethyl-2-oxo-1H-pyridin-3-yl)methyl]-3-methyl-2-phenylsulfanylbutanamide —— C19H24N2O2S
    (2R)-N-[(4,6-dimethyl-2-oxo-1H-pyridin-3-yl)methyl]-3-methyl-2-phenylsulfanylbutanamide
    —— N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C22H26N4O2S
    N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— [(1S)-2-[[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium —— C22H27N4O2S+
    [(1S)-2-[[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium
    —— 3-(4-chlorophenyl)sulfanyl-N-[(2S)-2-(dimethylamino)-2-phenylethyl]propanamide —— C19H23ClN2OS
    3-(4-chlorophenyl)sulfanyl-N-[(2S)-2-(dimethylamino)-2-phenylethyl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C23H27N3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H20N4O2S
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C16H18N2O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 3-[[5-(3,4-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C13H13N3OS
    3-[[5-(3,4-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— ethyl (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-phenylacetate —— C20H20N2O3S
    ethyl (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-phenylacetate
    —— 2-(3,4-Dimethylphenyl)-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C19H20N2OS
    2-(3,4-Dimethylphenyl)-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H20N4O2S
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(2R)-2-(dimethylamino)-2-phenylethyl]propanamide —— C19H23ClN2OS
    3-(4-chlorophenyl)sulfanyl-N-[(2R)-2-(dimethylamino)-2-phenylethyl]propanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C21H27N3O2S
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 3,6-Dimethyl-5-[(2-methylphenyl)methyl]-2-[(4-methylphenyl)methylsulfanyl]pyrimidin-4-one —— C22H24N2OS
    3,6-Dimethyl-5-[(2-methylphenyl)methyl]-2-[(4-methylphenyl)methylsulfanyl]pyrimidin-4-one
    —— 2-(3,4-Dimethylphenyl)-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole —— C18H15N3O2S2
    2-(3,4-Dimethylphenyl)-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— [(1R)-2-[[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium —— C22H27N4O2S+
    [(1R)-2-[[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium
    —— 5-[(4-Fluorophenyl)methyl]-3,6-dimethyl-2-[(2-methylphenyl)methylsulfanyl]pyrimidin-4-one —— C21H21FN2OS
    5-[(4-Fluorophenyl)methyl]-3,6-dimethyl-2-[(2-methylphenyl)methylsulfanyl]pyrimidin-4-one
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]acetamide —— C17H18N4O4S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]acetamide
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C21H27N3O2S
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N,N-bis(2-cyanoethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H19N5O2S
    N,N-bis(2-cyanoethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C24H31N3O2S
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C18H23N3O4S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— (2R)-N-cyclohexyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C20H27N3O2S
    (2R)-N-cyclohexyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— (2R)-N-benzyl-2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C14H16N4O2S
    (2R)-N-benzyl-2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C14H16N4O2S
    (2S)-N-benzyl-2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— 4-methoxy-7,7-dimethyl-8,9a-dihydro-6H-pyrimido[4,5-b][1,4]benzothiazin-9-one —— C13H15N3O2S
    4-methoxy-7,7-dimethyl-8,9a-dihydro-6H-pyrimido[4,5-b][1,4]benzothiazin-9-one
    —— (3R)-N-(2-phenylsulfanylethyl)oxolane-3-carboxamide —— C13H17NO2S
    (3R)-N-(2-phenylsulfanylethyl)oxolane-3-carboxamide
    —— (3S)-N-(2-phenylsulfanylethyl)oxolane-3-carboxamide —— C13H17NO2S
    (3S)-N-(2-phenylsulfanylethyl)oxolane-3-carboxamide