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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-1-[[5-(2-chloro-4,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C19H27ClN4O2S2
    (2S)-1-[[5-(2-chloro-4,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2S)-N-(cyclohexylcarbamoyl)-2-(2-fluorophenyl)sulfanylpropanamide —— C16H21FN2O2S
    (2S)-N-(cyclohexylcarbamoyl)-2-(2-fluorophenyl)sulfanylpropanamide
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2-fluorophenyl)sulfanylacetamide —— C14H17FN2OS
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2-fluorophenyl)sulfanylacetamide
    —— (2S)-1-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C22H34N4O2S2
    (2S)-1-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2S)-1-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C22H34N4OS2
    (2S)-1-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2R)-1-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C19H28N4OS2
    (2R)-1-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2S)-1-[[5-(2-chloro-4,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C19H27ClN4O2S2
    (2S)-1-[[5-(2-chloro-4,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2S)-1-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C22H34N4O2S2
    (2S)-1-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C14H18BrNO2S
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C14H18BrNO2S
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— (2S)-1-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C19H28N4O2S2
    (2S)-1-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— 1-[[(2S)-4-benzylmorpholin-2-yl]methyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C23H26N4O2S2
    1-[[(2S)-4-benzylmorpholin-2-yl]methyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 1-[[(2R)-4-benzylmorpholin-2-yl]methyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C23H26N4O2S2
    1-[[(2R)-4-benzylmorpholin-2-yl]methyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— ethyl 4-[2-(2-fluorophenyl)sulfanylacetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate —— C17H18FNO3S
    ethyl 4-[2-(2-fluorophenyl)sulfanylacetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate
    —— 1-(4-Bromophenyl)sulfanyl-4-methylsulfonyl-2-nitrobenzene —— C13H10BrNO4S2
    1-(4-Bromophenyl)sulfanyl-4-methylsulfonyl-2-nitrobenzene
    —— 2-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]-5-nitrobenzonitrile —— C11H7N3O2S2
    2-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]-5-nitrobenzonitrile
    —— N-[4-(2-cyano-4-nitrophenyl)sulfanylphenyl]acetamide —— C15H11N3O3S
    N-[4-(2-cyano-4-nitrophenyl)sulfanylphenyl]acetamide
    —— 1-(4-Chlorophenyl)sulfanyl-4-methylsulfonyl-2-nitrobenzene —— C13H10ClNO4S2
    1-(4-Chlorophenyl)sulfanyl-4-methylsulfonyl-2-nitrobenzene
    —— 1-Methyl-5-(2-nitrophenyl)sulfanyltetrazole —— C8H7N5O2S
    1-Methyl-5-(2-nitrophenyl)sulfanyltetrazole
    —— 1-[4-(3,4-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonyl-4-methylpiperazine —— C19H23N3O4S2
    1-[4-(3,4-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonyl-4-methylpiperazine
    —— 3-(4-bromophenyl)sulfanyl-N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C17H24BrNO3S2
    3-(4-bromophenyl)sulfanyl-N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— 1-[4-(3,4-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonyl-4-methylpiperazin-4-ium —— C19H24N3O4S2+
    1-[4-(3,4-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonyl-4-methylpiperazin-4-ium
    —— 2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-5-nitrobenzonitrile —— C15H10N2O4S
    2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-5-nitrobenzonitrile
    —— 3-(4-bromophenyl)sulfanyl-N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C17H24BrNO3S2
    3-(4-bromophenyl)sulfanyl-N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— 4-Methyl-2-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-1,3-thiazole —— C11H10N2O4S3
    4-Methyl-2-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-1,3-thiazole
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1S)-5-fluoro-2,3-dihydro-1H-inden-1-yl]benzamide —— C23H17FN2OS
    2-(2-cyanophenyl)sulfanyl-N-[(1S)-5-fluoro-2,3-dihydro-1H-inden-1-yl]benzamide
    —— 2-(2-cyanophenyl)sulfanyl-N-[(2R)-1-[(3R)-3-methylpiperidin-1-yl]propan-2-yl]benzamide —— C23H27N3OS
    2-(2-cyanophenyl)sulfanyl-N-[(2R)-1-[(3R)-3-methylpiperidin-1-yl]propan-2-yl]benzamide
    —— N-[(4S)-8-chloro-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide —— C23H17ClN2O2S
    N-[(4S)-8-chloro-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1R)-5-fluoro-2,3-dihydro-1H-inden-1-yl]benzamide —— C23H17FN2OS
    2-(2-cyanophenyl)sulfanyl-N-[(1R)-5-fluoro-2,3-dihydro-1H-inden-1-yl]benzamide
    —— N-[(4R)-8-chloro-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide —— C23H17ClN2O2S
    N-[(4R)-8-chloro-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide
    —— 2-(2-cyanophenyl)sulfanyl-N-[(2R)-1-[(3S)-3-methylpiperidin-1-yl]propan-2-yl]benzamide —— C23H27N3OS
    2-(2-cyanophenyl)sulfanyl-N-[(2R)-1-[(3S)-3-methylpiperidin-1-yl]propan-2-yl]benzamide
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-cyclopropyl-N-[(1S)-1-(furan-2-yl)ethyl]acetamide —— C20H23N3O2S
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-cyclopropyl-N-[(1S)-1-(furan-2-yl)ethyl]acetamide
    —— 2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C13H20N4O2S
    2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-[(3S,5S)-3,5-dimethylpiperidin-1-yl]propan-2-yl]acetamide —— C25H33N5O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-[(3S,5S)-3,5-dimethylpiperidin-1-yl]propan-2-yl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-[(3S,5R)-3,5-dimethylpiperidin-1-yl]propan-2-yl]acetamide —— C25H33N5O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-[(3S,5R)-3,5-dimethylpiperidin-1-yl]propan-2-yl]acetamide
    —— 2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C13H20N4O2S
    2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-[(3R,5R)-3,5-dimethylpiperidin-1-yl]propan-2-yl]acetamide —— C25H33N5O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-[(3R,5R)-3,5-dimethylpiperidin-1-yl]propan-2-yl]acetamide
    —— (Z,1S,4S)-1,7,7-trimethyl-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]heptan-2-imine —— C20H24N6O2S
    (Z,1S,4S)-1,7,7-trimethyl-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]heptan-2-imine
    —— (Z,1R,4R)-1,7,7-trimethyl-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]heptan-2-imine —— C20H24N6O2S
    (Z,1R,4R)-1,7,7-trimethyl-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]heptan-2-imine
    —— 2-phenyl-5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-oxadiazole —— C16H14N2OS
    2-phenyl-5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-oxadiazole
    —— (2R)-N-methoxy-N-methyl-2-propylsulfonylpropanamide —— C8H17NO4S
    (2R)-N-methoxy-N-methyl-2-propylsulfonylpropanamide
    —— 4-[[(2R)-oxolan-2-yl]methyl]-3-(3-phenylpropylsulfanyl)-5-thiophen-2-yl-1,2,4-triazole —— C20H23N3OS2
    4-[[(2R)-oxolan-2-yl]methyl]-3-(3-phenylpropylsulfanyl)-5-thiophen-2-yl-1,2,4-triazole
    —— 2-phenyl-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-oxadiazole —— C16H14N2OS
    2-phenyl-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-Cyclohexyl-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C15H16N4O3S
    2-Cyclohexyl-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— 2-[(5-cyclohexyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(cyclopropylcarbamoyl)acetamide —— C14H20N4O3S
    2-[(5-cyclohexyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(cyclopropylcarbamoyl)acetamide
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(2S)-2-(diethylamino)-2-thiophen-3-ylethyl]acetamide —— C21H28N4OS2
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(2S)-2-(diethylamino)-2-thiophen-3-ylethyl]acetamide
    —— N-[(4R)-6-bromo-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide —— C23H17BrN2O2S
    N-[(4R)-6-bromo-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide
    —— N-[(4S)-6-bromo-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide —— C23H17BrN2O2S
    N-[(4S)-6-bromo-3,4-dihydro-2H-chromen-4-yl]-2-(2-cyanophenyl)sulfanylbenzamide
    —— 3-(2-fluorophenyl)sulfanyl-N-[2-methyl-2-[(3S)-3-methylpiperidin-1-yl]propyl]propanamide —— C19H29FN2OS
    3-(2-fluorophenyl)sulfanyl-N-[2-methyl-2-[(3S)-3-methylpiperidin-1-yl]propyl]propanamide
    —— 2-Ethanimidoyl-4-(1-methyltetrazol-5-yl)sulfanyl-3-oxobutanenitrile —— C8H10N6OS
    2-Ethanimidoyl-4-(1-methyltetrazol-5-yl)sulfanyl-3-oxobutanenitrile