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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C14H19N5OS
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 1-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C18H21N5OS
    1-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H19N5OS
    N-[2-(cyclohexen-1-yl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— (2R)-N-[2-(4-fluorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylpropanamide —— C13H16FN5OS
    (2R)-N-[2-(4-fluorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylpropanamide
    —— (2S)-N-[2-(4-fluorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylpropanamide —— C13H16FN5OS
    (2S)-N-[2-(4-fluorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylpropanamide
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H14BrN5OS
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 1-[2,5-dimethyl-1-[(1R)-1-phenylethyl]pyrrol-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C18H21N5OS
    1-[2,5-dimethyl-1-[(1R)-1-phenylethyl]pyrrol-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— (4S)-1-[(5-cyclohexylsulfanylfuran-2-yl)methyl]-4-(hydroxymethyl)azepan-4-ol —— C18H29NO3S
    (4S)-1-[(5-cyclohexylsulfanylfuran-2-yl)methyl]-4-(hydroxymethyl)azepan-4-ol
    —— (4R)-1-[(5-cyclohexylsulfanylfuran-2-yl)methyl]-4-(hydroxymethyl)azepan-4-ol —— C18H29NO3S
    (4R)-1-[(5-cyclohexylsulfanylfuran-2-yl)methyl]-4-(hydroxymethyl)azepan-4-ol
    —— [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1S,2R)-2-methylcyclopropane-1-carboxylate —— C19H18ClNO3S
    [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1S,2R)-2-methylcyclopropane-1-carboxylate
    —— [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1R,2R)-2-methylcyclopropane-1-carboxylate —— C19H18ClNO3S
    [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1R,2R)-2-methylcyclopropane-1-carboxylate
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C22H22N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1R,2S)-2-methylcyclopropane-1-carboxylate —— C19H18ClNO3S
    [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1R,2S)-2-methylcyclopropane-1-carboxylate
    —— (5S)-3-methyl-7-(2-phenylsulfanylethyl)-1-oxa-3,7-diazaspiro[4.4]nonan-2-one —— C15H20N2O2S
    (5S)-3-methyl-7-(2-phenylsulfanylethyl)-1-oxa-3,7-diazaspiro[4.4]nonan-2-one
    —— [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1S,2S)-2-methylcyclopropane-1-carboxylate —— C19H18ClNO3S
    [2-[2-(4-chlorophenyl)sulfanylanilino]-2-oxoethyl] (1S,2S)-2-methylcyclopropane-1-carboxylate
    —— (5R)-3-methyl-7-(2-phenylsulfanylethyl)-1-oxa-3,7-diazaspiro[4.4]nonan-2-one —— C15H20N2O2S
    (5R)-3-methyl-7-(2-phenylsulfanylethyl)-1-oxa-3,7-diazaspiro[4.4]nonan-2-one
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C22H22N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] cyclobutanecarboxylate —— C19H18ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] cyclobutanecarboxylate
    —— 4-[2-[(2S)-1-(2-phenylsulfanylethyl)piperidin-2-yl]ethyl]morpholine —— C19H30N2OS
    4-[2-[(2S)-1-(2-phenylsulfanylethyl)piperidin-2-yl]ethyl]morpholine
    —— 4-[2-[(2R)-1-(2-phenylsulfanylethyl)piperidin-2-yl]ethyl]morpholine —— C19H30N2OS
    4-[2-[(2R)-1-(2-phenylsulfanylethyl)piperidin-2-yl]ethyl]morpholine
    —— 5-[(2R)-2-(2-aminoethyl)morpholin-4-yl]-2-(2-phenylsulfanylethyl)pyridazin-3-one —— C18H24N4O2S
    5-[(2R)-2-(2-aminoethyl)morpholin-4-yl]-2-(2-phenylsulfanylethyl)pyridazin-3-one
    —— 5-[(2S)-2-(2-aminoethyl)morpholin-4-yl]-2-(2-phenylsulfanylethyl)pyridazin-3-one —— C18H24N4O2S
    5-[(2S)-2-(2-aminoethyl)morpholin-4-yl]-2-(2-phenylsulfanylethyl)pyridazin-3-one
    —— 5-[[(3S)-3-(imidazol-1-ylmethyl)piperidin-1-yl]methyl]-2-methylsulfanylpyrimidine —— C15H21N5S
    5-[[(3S)-3-(imidazol-1-ylmethyl)piperidin-1-yl]methyl]-2-methylsulfanylpyrimidine
    —— 5-[[(3R)-3-(imidazol-1-ylmethyl)piperidin-1-yl]methyl]-2-methylsulfanylpyrimidine —— C15H21N5S
    5-[[(3R)-3-(imidazol-1-ylmethyl)piperidin-1-yl]methyl]-2-methylsulfanylpyrimidine
    —— (2R)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C16H19N3OS2
    (2R)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (5R)-3-methyl-9-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]-1-oxa-3,9-diazaspiro[4.6]undecan-2-one —— C15H21N3O3S2
    (5R)-3-methyl-9-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]-1-oxa-3,9-diazaspiro[4.6]undecan-2-one
    —— (4S)-4-[(dimethylamino)methyl]-1-[(2-propylsulfanylpyrimidin-5-yl)methyl]azepan-4-ol —— C17H30N4OS
    (4S)-4-[(dimethylamino)methyl]-1-[(2-propylsulfanylpyrimidin-5-yl)methyl]azepan-4-ol
    —— (6S)-4-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1,11-dioxa-4,8-diazaspiro[5.6]dodecane —— C20H26N2O3S
    (6S)-4-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1,11-dioxa-4,8-diazaspiro[5.6]dodecane
    —— (6R)-4-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1,11-dioxa-4,8-diazaspiro[5.6]dodecane —— C20H26N2O3S
    (6R)-4-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1,11-dioxa-4,8-diazaspiro[5.6]dodecane
    —— 4-(4-methylphenyl)sulfanyl-1-[[(3R)-pyrrolidin-3-yl]methyl]piperidine —— C17H26N2S
    4-(4-methylphenyl)sulfanyl-1-[[(3R)-pyrrolidin-3-yl]methyl]piperidine
    —— 4-[[4-(3,4-Dimethylphenyl)sulfanylphenyl]sulfonylamino]benzoate —— C21H18NO4S2-
    4-[[4-(3,4-Dimethylphenyl)sulfanylphenyl]sulfonylamino]benzoate
    —— 4-(4-methylphenyl)sulfanyl-1-[[(3S)-pyrrolidin-3-yl]methyl]piperidine —— C17H26N2S
    4-(4-methylphenyl)sulfanyl-1-[[(3S)-pyrrolidin-3-yl]methyl]piperidine
    —— 4-amino-2-[2-(1-benzyl-2,5-dimethylpyrrol-3-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one —— C19H20N4O2S
    4-amino-2-[2-(1-benzyl-2,5-dimethylpyrrol-3-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— Ethyl 2-[2-[2-[(4-chlorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C16H17ClN2O3S2
    Ethyl 2-[2-[2-[(4-chlorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— N-(2-benzylpyrazol-3-yl)-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide —— C23H20N4OS
    N-(2-benzylpyrazol-3-yl)-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide
    —— (5S)-3-methyl-9-(2-methylsulfanylpyrimidin-4-yl)-1-oxa-3,9-diazaspiro[4.6]undecan-2-one —— C14H20N4O2S
    (5S)-3-methyl-9-(2-methylsulfanylpyrimidin-4-yl)-1-oxa-3,9-diazaspiro[4.6]undecan-2-one
    —— 1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C17H15N5OS3
    1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 2-(2-cyanophenyl)sulfanyl-N-(6-methoxypyridin-3-yl)benzamide —— C20H15N3O2S
    2-(2-cyanophenyl)sulfanyl-N-(6-methoxypyridin-3-yl)benzamide
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-[[5-[(2-oxopyrrolidin-1-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H24N4O3S
    N-[(1S,2S)-2-methylcyclohexyl]-2-[[5-[(2-oxopyrrolidin-1-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C7H12N4O2S
    2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S,2R)-2-methylcyclohexyl]-2-[[5-[(2-oxopyrrolidin-1-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H24N4O3S
    N-[(1S,2R)-2-methylcyclohexyl]-2-[[5-[(2-oxopyrrolidin-1-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-pyridin-2-ylsulfanylethanone —— C20H19FN2OS
    1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-pyridin-2-ylsulfanylethanone
    —— (5R)-3-methyl-9-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1-oxa-3,9-diazaspiro[4.6]undecan-2-one —— C21H26N2O3S
    (5R)-3-methyl-9-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1-oxa-3,9-diazaspiro[4.6]undecan-2-one
    —— (5S)-3-methyl-9-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1-oxa-3,9-diazaspiro[4.6]undecan-2-one —— C21H26N2O3S
    (5S)-3-methyl-9-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methyl]-1-oxa-3,9-diazaspiro[4.6]undecan-2-one
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C9H16N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— 1-[(6R)-1,11-dioxa-4,8-diazaspiro[5.6]dodecan-4-yl]-2-(2-ethylsulfanyl-1,3-thiazol-4-yl)ethanone —— C15H23N3O3S2
    1-[(6R)-1,11-dioxa-4,8-diazaspiro[5.6]dodecan-4-yl]-2-(2-ethylsulfanyl-1,3-thiazol-4-yl)ethanone
    —— N-[(2S)-pentan-2-yl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C14H23N3OS
    N-[(2S)-pentan-2-yl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-[(2R)-1-(6,8-dihydro-5H-imidazo[1,5-a]pyrazin-7-yl)-1-oxopropan-2-yl]sulfanyl-4-methyl-1H-pyrimidin-6-one —— C14H17N5O2S
    2-[(2R)-1-(6,8-dihydro-5H-imidazo[1,5-a]pyrazin-7-yl)-1-oxopropan-2-yl]sulfanyl-4-methyl-1H-pyrimidin-6-one