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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-cyanophenyl)sulfanyl-N-[[(2S)-1-(2-methoxyethyl)pyrrolidin-2-yl]methyl]benzamide —— C22H25N3O2S
    2-(2-cyanophenyl)sulfanyl-N-[[(2S)-1-(2-methoxyethyl)pyrrolidin-2-yl]methyl]benzamide
    —— (2R)-N-(2-methoxyethyl)-2-[(4-methylsulfanylphenyl)methylsulfanyl]propanamide —— C14H21NO2S2
    (2R)-N-(2-methoxyethyl)-2-[(4-methylsulfanylphenyl)methylsulfanyl]propanamide
    —— (2S)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide —— C21H24N4OS2
    (2S)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide
    —— 2-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone —— C15H18ClN4O2S+
    2-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone
    —— (2S)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C21H24N4OS2
    (2S)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone —— C16H21N4O2S+
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone
    —— (3R)-1-methyl-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-5-oxopyrrolidine-3-carboxamide —— C16H18N4O2S
    (3R)-1-methyl-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-5-oxopyrrolidine-3-carboxamide
    —— (3S)-1-methyl-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-5-oxopyrrolidine-3-carboxamide —— C16H18N4O2S
    (3S)-1-methyl-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-5-oxopyrrolidine-3-carboxamide
    —— (2R)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide —— C21H24N4OS2
    (2R)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide
    —— (2R)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C21H24N4OS2
    (2R)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— N'-[(3-oxo-1-benzothiophen-2-ylidene)methyl]-2-[(E)-1-phenylethylideneamino]oxyacetohydrazide —— C19H17N3O3S
    N'-[(3-oxo-1-benzothiophen-2-ylidene)methyl]-2-[(E)-1-phenylethylideneamino]oxyacetohydrazide
    —— methyl (2S)-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C11H20N4O2S
    methyl (2S)-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— methyl (2R)-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C11H20N4O2S
    methyl (2R)-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 1-[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]-3-(1H-pyrazol-4-yl)urea —— C15H20N4O2S
    1-[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]-3-(1H-pyrazol-4-yl)urea
    —— 1-[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]-3-(1H-pyrazol-4-yl)urea —— C15H20N4O2S
    1-[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]-3-(1H-pyrazol-4-yl)urea
    —— [(2S)-2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone —— C17H28N4O2S
    [(2S)-2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone
    —— [(2R)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone —— C22H30N4O2S
    [(2R)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone
    —— 2-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl-(4-methylcyclohexyl)azanium —— C14H27N4S+
    2-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl-(4-methylcyclohexyl)azanium
    —— (4-methoxycyclohexyl)-[(2R)-2-[4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methanone —— C21H35N5O2S
    (4-methoxycyclohexyl)-[(2R)-2-[4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methanone
    —— 3-benzylsulfanyl-4-methyl-5-[(2R)-1-methylsulfonylpyrrolidin-2-yl]-1,2,4-triazole —— C15H20N4O2S2
    3-benzylsulfanyl-4-methyl-5-[(2R)-1-methylsulfonylpyrrolidin-2-yl]-1,2,4-triazole
    —— [(2R)-2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone —— C17H28N4O2S
    [(2R)-2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone
    —— [(2S)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone —— C22H30N4O2S
    [(2S)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone
    —— Cyclopentyl-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]azanium —— C12H23N4S+
    Cyclopentyl-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]azanium
    —— (2S)-N-[(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]oxolane-2-carboxamide —— C11H18N4O2S
    (2S)-N-[(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]oxolane-2-carboxamide
    —— [(2R)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-[(2S)-oxolan-2-yl]methanone —— C19H24N4O2S
    [(2R)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-[(2S)-oxolan-2-yl]methanone
    —— (2S)-N-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide —— C12H20N4O2S
    (2S)-N-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide
    —— Cyclohexyl-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]azanium —— C13H25N4S+
    Cyclohexyl-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]azanium
    —— (4-methoxycyclohexyl)-[(2S)-2-[4-methyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methanone —— C21H36N5O2S+
    (4-methoxycyclohexyl)-[(2S)-2-[4-methyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methanone
    —— (2S)-4-[[5-(3-chloro-4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile —— C22H16ClN5OS3
    (2S)-4-[[5-(3-chloro-4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile
    —— (3R)-3-[4-ethyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine —— C16H29N5O2S2
    (3R)-3-[4-ethyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine
    —— (2R)-4-[[5-(3-chloro-4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile —— C22H16ClN5OS3
    (2R)-4-[[5-(3-chloro-4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile
    —— (2S)-N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide —— C17H22N4O2S
    (2S)-N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide
    —— (3R)-3-(5-ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine —— C13H24N4O2S2
    (3R)-3-(5-ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine
    —— (3R)-3-[4-ethyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine —— C16H30N5O2S2+
    (3R)-3-[4-ethyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine
    —— (3R)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine —— C16H22N4O2S2
    (3R)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine
    —— (2S)-N-cyclopropyl-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C13H23N5OS
    (2S)-N-cyclopropyl-2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (3S)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-1-(4-methylcyclohexyl)piperidin-1-ium —— C17H31N4S+
    (3S)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-1-(4-methylcyclohexyl)piperidin-1-ium
    —— 3-[(2S)-1-cyclohexylpyrrolidin-1-ium-2-yl]-4-methyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazole —— C19H35N5S+2
    3-[(2S)-1-cyclohexylpyrrolidin-1-ium-2-yl]-4-methyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazole
    —— (3R)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-1-(4-methylcyclohexyl)piperidine —— C17H30N4S
    (3R)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-1-(4-methylcyclohexyl)piperidine
    —— (3S)-3-(5-ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine —— C13H24N4O2S2
    (3S)-3-(5-ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine
    —— 3-[(2R)-1-(furan-2-ylmethyl)pyrrolidin-1-ium-2-yl]-4-methyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazole —— C18H29N5OS+2
    3-[(2R)-1-(furan-2-ylmethyl)pyrrolidin-1-ium-2-yl]-4-methyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazole
    —— [(2S)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-[(2R)-oxolan-2-yl]methanone —— C19H24N4O2S
    [(2S)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-[(2R)-oxolan-2-yl]methanone
    —— (2R)-N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide —— C17H22N4O2S
    (2R)-N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide
    —— 4-methyl-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5-[(2S)-1-(thiophen-2-ylmethyl)pyrrolidin-1-ium-2-yl]-1,2,4-triazole —— C18H29N5S2+2
    4-methyl-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5-[(2S)-1-(thiophen-2-ylmethyl)pyrrolidin-1-ium-2-yl]-1,2,4-triazole
    —— (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine —— C16H22N4O2S2
    (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-methylsulfonylpiperidine
    —— (3R)-1-(furan-2-ylmethyl)-3-[4-propan-2-yl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]piperidine —— C21H33N5OS
    (3R)-1-(furan-2-ylmethyl)-3-[4-propan-2-yl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]piperidine
    —— (2R)-N-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide —— C12H20N4O2S
    (2R)-N-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide
    —— (3R)-1-(4-methylcyclohexyl)-3-(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidine —— C18H32N4S
    (3R)-1-(4-methylcyclohexyl)-3-(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidine
    —— (3R)-1-(furan-2-ylmethyl)-3-[4-propan-2-yl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]piperidin-1-ium —— C21H35N5OS+2
    (3R)-1-(furan-2-ylmethyl)-3-[4-propan-2-yl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]piperidin-1-ium
    —— (3R)-1-cyclohexyl-3-(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidin-1-ium —— C17H31N4S+
    (3R)-1-cyclohexyl-3-(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidin-1-ium