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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C11H13N3O3S
    methyl (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C14H14N4O3S
    2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— cyclohexyl 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate —— C15H19N3O3S
    cyclohexyl 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— (2S)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid —— C10H11N3O3S
    (2S)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid
    —— 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C17H18N4O2S
    2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— cyclohexyl (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C16H21N3O3S
    cyclohexyl (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— 2-[[4-[(2S)-1-thiophen-2-ylpropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C11H13N3O2S2
    2-[[4-[(2S)-1-thiophen-2-ylpropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— N-[(2R)-butan-2-yl]-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C13H18N4O2S
    N-[(2R)-butan-2-yl]-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 3-phenylpropyl 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate —— C18H19N3O3S
    3-phenylpropyl 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— 2-[(3-Bromobenzyl)sulfanyl]-4-ethyl-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile —— C14H12BrN3OS
    2-[(3-Bromobenzyl)sulfanyl]-4-ethyl-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile
    —— (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid —— C10H11N3O3S
    (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid
    —— (2S)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C10H10N3O3S-
    (2S)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— 4-ethyl-2-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-6-oxo-1H-pyrimidine-5-carbonitrile —— C13H16N4O3S
    4-ethyl-2-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-6-oxo-1H-pyrimidine-5-carbonitrile
    —— methyl (2S)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C11H13N3O3S
    methyl (2S)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— 4-ethyl-2-[(2-fluorophenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile —— C14H12FN3OS
    4-ethyl-2-[(2-fluorophenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile
    —— N-[(2R)-2-hydroxy-3-methoxypropyl]-2-(2-methylphenyl)sulfanylacetamide —— C13H19NO3S
    N-[(2R)-2-hydroxy-3-methoxypropyl]-2-(2-methylphenyl)sulfanylacetamide
    —— 2-[(2-chloro-6-fluorophenyl)methylsulfanyl]-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile —— C14H11ClFN3OS
    2-[(2-chloro-6-fluorophenyl)methylsulfanyl]-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile
    —— 5-fluoro-N'-hydroxy-2-(1,3-thiazol-2-ylsulfanylmethyl)benzenecarboximidamide —— C11H10FN3OS2
    5-fluoro-N'-hydroxy-2-(1,3-thiazol-2-ylsulfanylmethyl)benzenecarboximidamide
    —— 2-[(4-bromophenyl)methylsulfanyl]-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile —— C14H12BrN3OS
    2-[(4-bromophenyl)methylsulfanyl]-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile
    —— N-benzyl-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-methylacetamide —— C17H18N4O2S
    N-benzyl-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-methylacetamide
    —— 4-[(3S)-piperidin-3-yl]sulfanylpyridine —— C10H14N2S
    4-[(3S)-piperidin-3-yl]sulfanylpyridine
    —— 2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide —— C19H17N3O2S2
    2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide
    —— 3-((2-Fluorobenzyl)thio)-5-methyl-4h-1,2,4-triazol-4-amine —— C10H11FN4S
    3-((2-Fluorobenzyl)thio)-5-methyl-4h-1,2,4-triazol-4-amine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine —— C14H11ClN4S2
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine
    —— 3-[[2-[(4-Amino-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-methyl-1,2,4-triazol-4-amine —— C14H18N8S2
    3-[[2-[(4-Amino-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-methyl-1,2,4-triazol-4-amine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine —— C16H17ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine —— C15H13ClN4S2
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-4-ylmethanimine —— C15H12ClN5S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-4-ylmethanimine
    —— (Z,Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine —— C19H17ClN4S
    (Z,Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine —— C18H17ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(1S)-cyclohex-3-en-1-yl]methanimine —— C16H17ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(1S)-cyclohex-3-en-1-yl]methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-phenylmethanimine —— C16H13ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-phenylmethanimine
    —— 3-Ethyl-5-[(2-fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C11H13FN4S
    3-Ethyl-5-[(2-fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— (Z)-1-(2-chloro-6-fluorophenyl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H11Cl2FN4S
    (Z)-1-(2-chloro-6-fluorophenyl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine —— C15H13ClN4OS
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-fluorophenyl)methanimine —— C16H12ClFN4S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-fluorophenyl)methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine —— C15H12ClN5S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine —— C14H11ClN4OS
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine —— C17H15ClN4S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine —— C17H15ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine —— C16H17ClN4S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine —— C14H11ClN4OS
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylphenyl)methanimine —— C17H15ClN4S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylphenyl)methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-phenylmethanimine —— C16H13ClN4S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-phenylmethanimine
    —— (Z)-1-(2-chlorophenyl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12Cl2N4S
    (Z)-1-(2-chlorophenyl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-1-(3-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12BrClN4S
    (Z)-1-(3-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-fluorophenyl)methanimine —— C16H12ClFN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-fluorophenyl)methanimine
    —— 3-[[2-[(4-Amino-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-propyl-1,2,4-triazol-4-amine —— C18H26N8S2
    3-[[2-[(4-Amino-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-propyl-1,2,4-triazol-4-amine
    —— (Z)-1-(2-chloro-6-fluorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H11Cl2FN4S
    (Z)-1-(2-chloro-6-fluorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 3-[(Z)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]phenol —— C16H13ClN4OS
    3-[(Z)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]phenol