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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptylpropanamide —— C15H24N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptylpropanamide
    —— [(2R)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C15H17N3O4S
    [(2R)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— ethyl 2-[5-[(3S)-3-cyano-4-imino-2-oxopentyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]acetate —— C13H17N5O3S
    ethyl 2-[5-[(3S)-3-cyano-4-imino-2-oxopentyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]acetate
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-1-(azepan-1-yl)propan-1-one —— C14H22N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-1-(azepan-1-yl)propan-1-one
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide —— C16H20N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2-cyanoethyl)-N-methylpropanamide —— C12H17N5OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2-cyanoethyl)-N-methylpropanamide
    —— [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C15H17N3O4S
    [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C14H22N4O3S2
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— [(2R)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C19H25N3O4S
    [(2R)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-1-(azepan-1-yl)propan-1-one —— C14H22N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-1-(azepan-1-yl)propan-1-one
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]propanamide —— C15H17ClN4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]propanamide
    —— (1R)-1-[4-butyl-5-[(5-tert-butyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C18H32N6OS
    (1R)-1-[4-butyl-5-[(5-tert-butyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-4-pyrazol-1-ylpyrimidine —— C16H14N4O2S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-4-pyrazol-1-ylpyrimidine
    —— [(2S)-1-[(4-methylphenyl)methylamino]-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C20H21N3O4S
    [(2S)-1-[(4-methylphenyl)methylamino]-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— [(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C19H25N3O4S
    [(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide —— C16H20N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-propylpropanamide —— C11H18N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-propylpropanamide
    —— 5-[(5-tert-butyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-4-prop-2-enyl-1,2,4-triazol-3-amine —— C12H18N6OS
    5-[(5-tert-butyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-4-prop-2-enyl-1,2,4-triazol-3-amine
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C13H20N4O3S2
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C15H19N3O5S
    [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2-cyanoethyl)-N-methylpropanamide —— C12H17N5OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2-cyanoethyl)-N-methylpropanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C14H22N4O3S2
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-tert-butylpropanamide —— C12H20N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-tert-butylpropanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]propanamide —— C15H17ClN4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]propanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C12H18N4O3S2
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-prop-2-enylpropanamide —— C11H16N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-prop-2-enylpropanamide
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-prop-2-enylpropanamide —— C11H16N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-prop-2-enylpropanamide
    —— methyl N-[(2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanylpropanoyl]carbamate —— C10H14N4O3S
    methyl N-[(2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanylpropanoyl]carbamate
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptylpropanamide —— C15H24N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-cycloheptylpropanamide
    —— (2R)-N-[(4-fluorophenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H19FN4OS
    (2R)-N-[(4-fluorophenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-[(4-methylphenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H22N4OS
    (2S)-N-[(4-methylphenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (1S)-1-[4-butyl-5-[(5-tert-butyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C18H32N6OS
    (1S)-1-[4-butyl-5-[(5-tert-butyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H19ClN4O2S2
    (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C12H20N4O3S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2-phenylethyl)propanamide —— C16H20N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2-phenylethyl)propanamide
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C12H18N4O3S2
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C12H18N4O3S2
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-tert-butylpropanamide —— C12H20N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-tert-butylpropanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C12H20N4O3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C11H18N4O2S2
    (2R)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— 7-Methyl-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C12H14N6OS2
    7-Methyl-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(1-cyanocyclohexyl)-N-methylpropanamide —— C16H23N5OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(1-cyanocyclohexyl)-N-methylpropanamide
    —— 2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethylcarbamoyl)acetamide —— C10H14F3N5O3S2
    2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethylcarbamoyl)acetamide
    —— methyl N-[(2S)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]carbamate —— C10H16N4O3S
    methyl N-[(2S)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]carbamate
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H19ClN4OS
    (2S)-N-[(2-chlorophenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-(2-methylpropyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C16H20N2OS2
    (2R)-N-(2-methylpropyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(4-methylphenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H22N4OS
    (2R)-N-[(4-methylphenyl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-(2-cyanoethyl)-N-methyl-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C16H17N3OS2
    (2R)-N-(2-cyanoethyl)-N-methyl-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C16H22N4O2S2
    (2S)-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2S)-N-(2-phenylsulfanylphenyl)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C20H22N4OS2
    (2S)-N-(2-phenylsulfanylphenyl)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide