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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1R)-1-[(2R)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidin-2-yl]ethanamine —— C15H23FN2S
    (1R)-1-[(2R)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidin-2-yl]ethanamine
    —— (1R)-1-[(2S)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidin-2-yl]ethanamine —— C15H23FN2S
    (1R)-1-[(2S)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidin-2-yl]ethanamine
    —— 1,3-bis[(E)-3,3-dimethylbutan-2-ylideneamino]thiourea —— C13H26N4S
    1,3-bis[(E)-3,3-dimethylbutan-2-ylideneamino]thiourea
    —— methyl (4S)-4-(5-ethylsulfanyl-2-methylfuran-3-yl)-2-methyl-5-oxo-4a,6,7,8-tetrahydro-4H-quinoline-3-carboxylate —— C19H23NO4S
    methyl (4S)-4-(5-ethylsulfanyl-2-methylfuran-3-yl)-2-methyl-5-oxo-4a,6,7,8-tetrahydro-4H-quinoline-3-carboxylate
    —— (2R)-2-fluoro-2-pyrimidin-2-ylsulfanylacetate —— C6H4FN2O2S-
    (2R)-2-fluoro-2-pyrimidin-2-ylsulfanylacetate
    —— methyl (4R)-4-(5-ethylsulfanyl-2-methylfuran-3-yl)-2-methyl-5-oxo-4a,6,7,8-tetrahydro-4H-quinoline-3-carboxylate —— C19H23NO4S
    methyl (4R)-4-(5-ethylsulfanyl-2-methylfuran-3-yl)-2-methyl-5-oxo-4a,6,7,8-tetrahydro-4H-quinoline-3-carboxylate
    —— (2S)-2-fluoro-2-pyrimidin-2-ylsulfanylacetate —— C6H4FN2O2S-
    (2S)-2-fluoro-2-pyrimidin-2-ylsulfanylacetate
    —— (3-Cyano-4-imino-2-oxopentyl) 2-phenylsulfanylacetate —— C14H14N2O3S
    (3-Cyano-4-imino-2-oxopentyl) 2-phenylsulfanylacetate
    —— N-methyl-1-[(2S)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]methanamine —— C16H26N2S
    N-methyl-1-[(2S)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]methanamine
    —— dimethyl (1'R,3'R,5'R,7'R)-6'-oxospiro[1,3-dithiolane-2,2'-bicyclo[3.3.1]nonane]-3',7'-dicarboxylate —— C15H20O5S2
    dimethyl (1'R,3'R,5'R,7'R)-6'-oxospiro[1,3-dithiolane-2,2'-bicyclo[3.3.1]nonane]-3',7'-dicarboxylate
    —— 1-[(2S)-1-[2-(2-fluorophenyl)sulfanylethyl]piperidin-2-yl]-N-methylmethanamine —— C15H23FN2S
    1-[(2S)-1-[2-(2-fluorophenyl)sulfanylethyl]piperidin-2-yl]-N-methylmethanamine
    —— (2S)-2-ethanimidoyl-4-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C15H15N5OS2
    (2S)-2-ethanimidoyl-4-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— N-methyl-1-[(2R)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]methanamine —— C16H26N2S
    N-methyl-1-[(2R)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]methanamine
    —— (2S)-2-(1-methylpyrrol-2-yl)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]pyrrolidine-1-carboxamide —— C20H22N4OS2
    (2S)-2-(1-methylpyrrol-2-yl)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]pyrrolidine-1-carboxamide
    —— (E)-3-azanyl-2-[2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanoyl]but-2-enenitrile —— C15H13ClN4OS3
    (E)-3-azanyl-2-[2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanoyl]but-2-enenitrile
    —— 1-[(2S)-1-methoxypropan-2-yl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C15H19N3O2S2
    1-[(2S)-1-methoxypropan-2-yl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 4-[(5-Cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C17H23N5OS
    4-[(5-Cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— 1-[2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C19H26N4O2S2
    1-[2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 1-ethyl-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-1-[[(3R)-oxolan-3-yl]methyl]urea —— C18H23N3O2S2
    1-ethyl-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-1-[[(3R)-oxolan-3-yl]methyl]urea
    —— 1-[(2R)-1-[2-(2-fluorophenyl)sulfanylethyl]piperidin-2-yl]-N-methylmethanamine —— C15H23FN2S
    1-[(2R)-1-[2-(2-fluorophenyl)sulfanylethyl]piperidin-2-yl]-N-methylmethanamine
    —— N-methyl-1-[1-[(1R)-1-(4-methylsulfanylphenyl)ethyl]piperidin-4-yl]methanamine —— C16H26N2S
    N-methyl-1-[1-[(1R)-1-(4-methylsulfanylphenyl)ethyl]piperidin-4-yl]methanamine
    —— 1-[[(2S)-1,4-dioxan-2-yl]methyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C16H19N3O3S2
    1-[[(2S)-1,4-dioxan-2-yl]methyl]-3-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 1-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3-[[(2S)-oxolan-2-yl]methyl]urea —— C16H19N3O2S2
    1-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3-[[(2S)-oxolan-2-yl]methyl]urea
    —— (2R)-4-[[5-(2,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C16H17N5OS2
    (2R)-4-[[5-(2,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— (3-Cyano-4-imino-2-oxopentyl) 3-phenylsulfanylpropanoate —— C15H16N2O3S
    (3-Cyano-4-imino-2-oxopentyl) 3-phenylsulfanylpropanoate
    —— (2S)-4-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C16H17N5OS2
    (2S)-4-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— (2S)-2-ethanimidoyl-3-oxo-4-[[5-(propan-2-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C11H15N5OS2
    (2S)-2-ethanimidoyl-3-oxo-4-[[5-(propan-2-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— ethyl 2-[2-[(3R)-3-cyano-4-imino-2-oxopentyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C13H15N3O3S2
    ethyl 2-[2-[(3R)-3-cyano-4-imino-2-oxopentyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— (E)-3-amino-2-[2-[[4-amino-5-(2-fluorobenzyl)-1,2,4-triazol-3-yl]thio]acetyl]but-2-enenitrile —— C15H15FN6OS
    (E)-3-amino-2-[2-[[4-amino-5-(2-fluorobenzyl)-1,2,4-triazol-3-yl]thio]acetyl]but-2-enenitrile
    —— 4-Imino-3-phenylsulfanylpentan-2-one —— C11H13NOS
    4-Imino-3-phenylsulfanylpentan-2-one
    —— 3-chloro-2-[(1S)-1-(1H-pyrazol-5-yl)ethyl]sulfanyl-5-(trifluoromethyl)pyridine —— C11H9ClF3N3S
    3-chloro-2-[(1S)-1-(1H-pyrazol-5-yl)ethyl]sulfanyl-5-(trifluoromethyl)pyridine
    —— 2-[2-[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylethanimidoyl]propanedinitrile —— C11H6ClF3N4S
    2-[2-[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylethanimidoyl]propanedinitrile
    —— 4-{[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl}-1,2-dihydropyrazol-3-one —— C9H5ClF3N3OS
    4-{[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl}-1,2-dihydropyrazol-3-one
    —— (2S)-2-[(5-morpholin-4-yl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-pentan-2-yl]propanamide —— C14H24N4O2S2
    (2S)-2-[(5-morpholin-4-yl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-pentan-2-yl]propanamide
    —— (1R)-1-(3-bromophenyl)-2-[(5-morpholin-4-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanol —— C14H16BrN3O2S2
    (1R)-1-(3-bromophenyl)-2-[(5-morpholin-4-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanol
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-morpholin-4-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C18H24N4O2S2
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-morpholin-4-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 4-[5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-yl]morpholine —— C11H17N3O2S2
    4-[5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-yl]morpholine
    —— (2S)-N-[2-[cyclopropyl(methyl)amino]ethyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C15H20N2OS
    (2S)-N-[2-[cyclopropyl(methyl)amino]ethyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— 6-[(2S,3R,4R,5R)-3,4,5-trihydroxyoxan-2-yl]sulfanyl-2H-1,2,4-triazine-3,5-dione —— C8H11N3O6S
    6-[(2S,3R,4R,5R)-3,4,5-trihydroxyoxan-2-yl]sulfanyl-2H-1,2,4-triazine-3,5-dione
    —— N-[(2S)-4-amino-4-sulfanylidenebutan-2-yl]-N,2-dimethylpropanamide —— C9H18N2OS
    N-[(2S)-4-amino-4-sulfanylidenebutan-2-yl]-N,2-dimethylpropanamide
    —— N-[(2R)-4-amino-4-sulfanylidenebutan-2-yl]-N,2-dimethylpropanamide —— C9H18N2OS
    N-[(2R)-4-amino-4-sulfanylidenebutan-2-yl]-N,2-dimethylpropanamide
    —— 2-[(5-methyl-4-nitro-1H-pyrazol-3-yl)sulfanyl]-N-(3-morpholin-4-ium-4-ylpropyl)acetamide —— C13H22N5O4S+
    2-[(5-methyl-4-nitro-1H-pyrazol-3-yl)sulfanyl]-N-(3-morpholin-4-ium-4-ylpropyl)acetamide
    —— 2-[(3-Methyl-4-nitro-1H-pyrazol-5-YL)sulfanyl]-N-[3-(morpholin-4-YL)propyl]acetamide —— C13H21N5O4S
    2-[(3-Methyl-4-nitro-1H-pyrazol-5-YL)sulfanyl]-N-[3-(morpholin-4-YL)propyl]acetamide
    —— N-[2-[(3-oxo-1-benzothiophen-2-yl)methylideneamino]ethyl]acetamide —— C13H14N2O2S
    N-[2-[(3-oxo-1-benzothiophen-2-yl)methylideneamino]ethyl]acetamide
    —— (5aS,8R,9aR)-5,5,8-trimethyl-5a,6,7,8,9,9a-hexahydro-3H-isothiochromeno[3,4-d][1,3]thiazol-2-one —— C13H19NOS2
    (5aS,8R,9aR)-5,5,8-trimethyl-5a,6,7,8,9,9a-hexahydro-3H-isothiochromeno[3,4-d][1,3]thiazol-2-one
    —— (5aS,8S,9aR)-5,5,8-trimethyl-5a,6,7,8,9,9a-hexahydro-3H-isothiochromeno[3,4-d][1,3]thiazol-2-one —— C13H19NOS2
    (5aS,8S,9aR)-5,5,8-trimethyl-5a,6,7,8,9,9a-hexahydro-3H-isothiochromeno[3,4-d][1,3]thiazol-2-one
    —— (5aR,8S,9aR)-5,5,8-trimethyl-5a,6,7,8,9,9a-hexahydro-3H-isothiochromeno[3,4-d][1,3]thiazol-2-one —— C13H19NOS2
    (5aR,8S,9aR)-5,5,8-trimethyl-5a,6,7,8,9,9a-hexahydro-3H-isothiochromeno[3,4-d][1,3]thiazol-2-one
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide —— C14H19NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide
    —— (2S)-2-(2,2-dimethylpyrrolidin-1-yl)-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2S
    (2S)-2-(2,2-dimethylpyrrolidin-1-yl)-2-(4-methylsulfanylphenyl)ethanamine
    —— (1S,8S,9R)-8-(4-methylphenyl)-2,6-dithia-4,11-diazatricyclo[7.3.0.03,7]dodec-3(7)-ene-5,10,12-trione —— C15H12N2O3S2
    (1S,8S,9R)-8-(4-methylphenyl)-2,6-dithia-4,11-diazatricyclo[7.3.0.03,7]dodec-3(7)-ene-5,10,12-trione