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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-thiophen-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C16H13F2N3OS3
    (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-thiophen-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— 3-chloro-N'-hydroxy-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]benzenecarboximidamide —— C10H10ClN5O2S
    3-chloro-N'-hydroxy-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]benzenecarboximidamide
    —— 3-chloro-N'-hydroxy-4-(1-methylimidazol-2-yl)sulfanylbenzenecarboximidamide —— C11H11ClN4OS
    3-chloro-N'-hydroxy-4-(1-methylimidazol-2-yl)sulfanylbenzenecarboximidamide
    —— 3-chloro-N'-hydroxy-4-(4-methylpyrimidin-2-yl)sulfanylbenzenecarboximidamide —— C12H11ClN4OS
    3-chloro-N'-hydroxy-4-(4-methylpyrimidin-2-yl)sulfanylbenzenecarboximidamide
    —— ethyl N-[(1R)-2,2,2-trichloro-1-phenylsulfanylethyl]carbamate —— C11H12Cl3NO2S
    ethyl N-[(1R)-2,2,2-trichloro-1-phenylsulfanylethyl]carbamate
    —— ethyl N-[(1S)-2,2,2-trichloro-1-phenylsulfanylethyl]carbamate —— C11H12Cl3NO2S
    ethyl N-[(1S)-2,2,2-trichloro-1-phenylsulfanylethyl]carbamate
    —— 4-chloro-N'-hydroxy-2-(3-methylphenyl)sulfanylbenzenecarboximidamide —— C14H13ClN2OS
    4-chloro-N'-hydroxy-2-(3-methylphenyl)sulfanylbenzenecarboximidamide
    —— 4-chloro-2-(4-fluorophenyl)sulfanyl-N'-hydroxybenzenecarboximidamide —— C13H10ClFN2OS
    4-chloro-2-(4-fluorophenyl)sulfanyl-N'-hydroxybenzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-(2-methylphenyl)sulfanylbenzenecarboximidamide —— C14H13ClN2OS
    4-chloro-N'-hydroxy-2-(2-methylphenyl)sulfanylbenzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-(1H-1,2,4-triazol-5-ylsulfanyl)benzenecarboximidamide —— C9H8ClN5OS
    4-chloro-N'-hydroxy-2-(1H-1,2,4-triazol-5-ylsulfanyl)benzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-[(1R,3R)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide —— C14H19ClN2OS
    4-chloro-N'-hydroxy-2-[(1R,3R)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]benzenecarboximidamide —— C10H9ClN4O2S
    4-chloro-N'-hydroxy-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]benzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-phenylsulfanylbenzenecarboximidamide —— C13H11ClN2OS
    4-chloro-N'-hydroxy-2-phenylsulfanylbenzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]benzenecarboximidamide —— C11H10ClN3OS2
    4-chloro-N'-hydroxy-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]benzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-[(1S,3R)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide —— C14H19ClN2OS
    4-chloro-N'-hydroxy-2-[(1S,3R)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-[(1S,3S)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide —— C14H19ClN2OS
    4-chloro-N'-hydroxy-2-[(1S,3S)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide
    —— 4-chloro-N'-hydroxy-2-[(1R,3S)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide —— C14H19ClN2OS
    4-chloro-N'-hydroxy-2-[(1R,3S)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide
    —— N-[(1S)-2,2,2-trichloro-1-phenylsulfanylethyl]hexanamide —— C14H18Cl3NOS
    N-[(1S)-2,2,2-trichloro-1-phenylsulfanylethyl]hexanamide
    —— 2-(6-Amino-3,5-dicyano-4-propan-2-ylpyridin-1-ium-2-yl)sulfanylacetamide —— C12H14N5OS+
    2-(6-Amino-3,5-dicyano-4-propan-2-ylpyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[(1R)-2,2,2-trichloro-1-phenylsulfanylethyl]hexanamide —— C14H18Cl3NOS
    N-[(1R)-2,2,2-trichloro-1-phenylsulfanylethyl]hexanamide
    —— (2Z)-2-[[4-(dimethylamino)anilino]methylidene]-1-benzothiophen-3-one —— C17H16N2OS
    (2Z)-2-[[4-(dimethylamino)anilino]methylidene]-1-benzothiophen-3-one
    —— 1-Morpholin-4-yl-3-propan-2-ylsulfanyl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C17H24N3OS+
    1-Morpholin-4-yl-3-propan-2-ylsulfanyl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 1-(2,6-dichlorophenyl)-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]methanimine —— C18H15Cl2N3S
    1-(2,6-dichlorophenyl)-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]methanimine
    —— N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-1-pyridin-2-ylmethanimine —— C17H16N4S
    N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-1-pyridin-2-ylmethanimine
    —— ethyl 4-[(2S)-2-[(4-fluorophenyl)sulfanylmethyl]-1,3-thiazolidin-3-yl]-4-oxobutanoate —— C16H20FNO3S2
    ethyl 4-[(2S)-2-[(4-fluorophenyl)sulfanylmethyl]-1,3-thiazolidin-3-yl]-4-oxobutanoate
    —— 2-[[5-(Carboxylatomethylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C6H4N2O4S3-2
    2-[[5-(Carboxylatomethylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— 4-[(1S)-1-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]pyrimidin-2-amine —— C12H10ClF3N4S
    4-[(1S)-1-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]pyrimidin-2-amine
    —— (3R)-1-benzyl-3-chloro-3-(4-chlorophenyl)sulfanylpyrrolidine-2,5-dione —— C17H13Cl2NO2S
    (3R)-1-benzyl-3-chloro-3-(4-chlorophenyl)sulfanylpyrrolidine-2,5-dione
    —— [1-Amino-2-(4-chlorophenyl)sulfanylethylidene]-(phenylcarbamothioyl)azanium —— C15H15ClN3S2+
    [1-Amino-2-(4-chlorophenyl)sulfanylethylidene]-(phenylcarbamothioyl)azanium
    —— ethyl (2S)-2-[(5-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C10H14N2O4S
    ethyl (2S)-2-[(5-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— 2-[(3-Amino-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetate —— C6H4N5O3S2-
    2-[(3-Amino-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetate
    —— N-[(2S)-1-(furan-2-yl)propan-2-yl]-3-methylsulfanylaniline —— C14H17NOS
    N-[(2S)-1-(furan-2-yl)propan-2-yl]-3-methylsulfanylaniline
    —— N-[(2R)-1-(furan-2-yl)propan-2-yl]-3-methylsulfanylaniline —— C14H17NOS
    N-[(2R)-1-(furan-2-yl)propan-2-yl]-3-methylsulfanylaniline
    —— ethyl (2S)-2-[2-phenyl-6-(phenylsulfanylmethyl)pyrimidin-4-yl]sulfanylpropanoate —— C22H22N2O2S2
    ethyl (2S)-2-[2-phenyl-6-(phenylsulfanylmethyl)pyrimidin-4-yl]sulfanylpropanoate
    —— ethyl (2R)-2-[2-phenyl-6-(phenylsulfanylmethyl)pyrimidin-4-yl]sulfanylpropanoate —— C22H22N2O2S2
    ethyl (2R)-2-[2-phenyl-6-(phenylsulfanylmethyl)pyrimidin-4-yl]sulfanylpropanoate
    —— (1R,2R)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H13N3O3S
    (1R,2R)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (3R)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-4,4,4-trifluorobutanoic acid —— C8H10F3N3O3S
    (3R)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-4,4,4-trifluorobutanoic acid
    —— (3S)-3-(3-bromophenyl)sulfanyl-4,4,4-trifluorobutanoic acid —— C10H8BrF3O2S
    (3S)-3-(3-bromophenyl)sulfanyl-4,4,4-trifluorobutanoic acid
    —— methyl (2R)-2,3,3,3-tetrafluoro-2-(4-hydroxyphenyl)sulfanylpropanoate —— C10H8F4O3S
    methyl (2R)-2,3,3,3-tetrafluoro-2-(4-hydroxyphenyl)sulfanylpropanoate
    —— (1S,2R)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H13N3O3S
    (1S,2R)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (3S)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-4,4,4-trifluorobutanoic acid —— C8H10F3N3O3S
    (3S)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-4,4,4-trifluorobutanoic acid
    —— (1R,2R)-2-(5-methylpyrimidin-2-yl)sulfanylcycloheptane-1-carboxylic acid —— C13H18N2O2S
    (1R,2R)-2-(5-methylpyrimidin-2-yl)sulfanylcycloheptane-1-carboxylic acid
    —— (3R)-3-(3-bromophenyl)sulfanyl-4,4,4-trifluorobutanoic acid —— C10H8BrF3O2S
    (3R)-3-(3-bromophenyl)sulfanyl-4,4,4-trifluorobutanoic acid
    —— 2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-[2-[2,2-dichloro-1-(2,2-dimethylpropanoylamino)ethenyl]sulfanyl-6-methylpyrimidin-4-yl]oxyethyl]propanamide —— C19H25Cl5N4O3S
    2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-[2-[2,2-dichloro-1-(2,2-dimethylpropanoylamino)ethenyl]sulfanyl-6-methylpyrimidin-4-yl]oxyethyl]propanamide
    —— (1S,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclopentane-1-carboxylic acid —— C11H14N2O2S
    (1S,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclopentane-1-carboxylic acid
    —— (1S,2S)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H12N2O3S
    (1S,2S)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1S,2R)-2-(1-methylpyrazol-4-yl)sulfanylcyclohexane-1-carboxylic acid —— C11H16N2O2S
    (1S,2R)-2-(1-methylpyrazol-4-yl)sulfanylcyclohexane-1-carboxylic acid
    —— (1R,2S)-2-(3-methylphenyl)sulfanylcycloheptane-1-carboxylic acid —— C15H20O2S
    (1R,2S)-2-(3-methylphenyl)sulfanylcycloheptane-1-carboxylic acid
    —— (1S,2S)-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H13N3O2S
    (1S,2S)-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (2R)-2-ethoxy-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid —— C9H15N3O4S
    (2R)-2-ethoxy-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid