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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1R,2R,4R)-2-(1-methylpyrazol-4-yl)sulfanyl-4-propylcyclohexane-1-carboxylic acid —— C14H22N2O2S
    (1R,2R,4R)-2-(1-methylpyrazol-4-yl)sulfanyl-4-propylcyclohexane-1-carboxylic acid
    —— (1R,2R)-2-(3-chlorophenyl)sulfanylcyclohexane-1-carboxylic acid —— C13H15ClO2S
    (1R,2R)-2-(3-chlorophenyl)sulfanylcyclohexane-1-carboxylic acid
    —— (1S,2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C10H12N2O3S
    (1S,2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1S,2R)-2-pyrimidin-2-ylsulfanylcyclohexane-1-carboxylic acid —— C11H14N2O2S
    (1S,2R)-2-pyrimidin-2-ylsulfanylcyclohexane-1-carboxylic acid
    —— (1S,2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclohexane-1-carboxylic acid —— C9H13N3O2S
    (1S,2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclohexane-1-carboxylic acid
    —— (1S,2R)-2-(2,4-difluorophenyl)sulfanylcyclohexane-1-carboxylic acid —— C13H14F2O2S
    (1S,2R)-2-(2,4-difluorophenyl)sulfanylcyclohexane-1-carboxylic acid
    —— (1S,2R,4S)-4-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C12H16N2O3S
    (1S,2R,4S)-4-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1R,2S)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylcycloheptane-1-carboxylic acid —— C14H20N2O2S
    (1R,2S)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylcycloheptane-1-carboxylic acid
    —— (1S,2R)-2-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cycloheptane-1-carboxylic acid —— C13H18N2O3S
    (1S,2R)-2-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cycloheptane-1-carboxylic acid
    —— (3S)-3-(2,5-dimethylphenyl)sulfanyl-4,4,4-trifluorobutanoic acid —— C12H13F3O2S
    (3S)-3-(2,5-dimethylphenyl)sulfanyl-4,4,4-trifluorobutanoic acid
    —— (1R,2R)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C10H14N2O3S
    (1R,2R)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1S,2S)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C10H12N2O3S
    (1S,2S)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (3S)-4,4,4-trifluoro-3-(4-methylpyrimidin-2-yl)sulfanylbutanoic acid —— C9H9F3N2O2S
    (3S)-4,4,4-trifluoro-3-(4-methylpyrimidin-2-yl)sulfanylbutanoic acid
    —— (1S,2S)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C13H18N2O3S
    (1S,2S)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1R,2R)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H12N2O3S
    (1R,2R)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1R,2R,4R)-4-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C12H17NO2S2
    (1R,2R,4R)-4-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1R,2R,4S)-4-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C12H16N2O3S
    (1R,2R,4S)-4-methyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1R,2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H13N3O2S
    (1R,2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1S,2R,4S)-4-ethyl-2-pyrimidin-2-ylsulfanylcyclohexane-1-carboxylic acid —— C13H18N2O2S
    (1S,2R,4S)-4-ethyl-2-pyrimidin-2-ylsulfanylcyclohexane-1-carboxylic acid
    —— (1R,2S)-2-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cycloheptane-1-carboxylic acid —— C13H18N2O3S
    (1R,2S)-2-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cycloheptane-1-carboxylic acid
    —— (1S,2R,4R)-2-(4-chlorophenyl)sulfanyl-4-methylcyclohexane-1-carboxylic acid —— C14H17ClO2S
    (1S,2R,4R)-2-(4-chlorophenyl)sulfanyl-4-methylcyclohexane-1-carboxylic acid
    —— (2R)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylpropanoic acid —— C12H12N2O2S2
    (2R)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylpropanoic acid
    —— (2S)-2-ethoxy-4-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C11H16N2O4S
    (2S)-2-ethoxy-4-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— (1S,2R,4R)-2-(2,5-difluorophenyl)sulfanyl-4-methylcyclohexane-1-carboxylic acid —— C14H16F2O2S
    (1S,2R,4R)-2-(2,5-difluorophenyl)sulfanyl-4-methylcyclohexane-1-carboxylic acid
    —— (1S,2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C10H15N3O2S
    (1S,2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1R,2S)-2-pyrimidin-2-ylsulfanylcyclopentane-1-carboxylic acid —— C10H12N2O2S
    (1R,2S)-2-pyrimidin-2-ylsulfanylcyclopentane-1-carboxylic acid
    —— (1S,2S)-2-(2,4-difluorophenyl)sulfanylcyclohexane-1-carboxylic acid —— C13H14F2O2S
    (1S,2S)-2-(2,4-difluorophenyl)sulfanylcyclohexane-1-carboxylic acid
    —— (1S,2S)-2-(4-fluorophenyl)sulfanylcyclohexane-1-carboxylic acid —— C13H15FO2S
    (1S,2S)-2-(4-fluorophenyl)sulfanylcyclohexane-1-carboxylic acid
    —— (1S,2R)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)cyclopentane-1-carboxylic acid —— C13H19N3O2S
    (1S,2R)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)cyclopentane-1-carboxylic acid
    —— (1R,2R,4S)-4-ethyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)cyclohexane-1-carboxylic acid —— C11H16N2O2S2
    (1R,2R,4S)-4-ethyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)cyclohexane-1-carboxylic acid
    —— (1S,2R,4S)-4-propyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclohexane-1-carboxylic acid —— C12H19N3O2S
    (1S,2R,4S)-4-propyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclohexane-1-carboxylic acid
    —— (1R,2R,4S)-4-methyl-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexane-1-carboxylic acid —— C13H18N2O2S
    (1R,2R,4S)-4-methyl-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexane-1-carboxylic acid
    —— (3R)-3-(2,5-dimethylphenyl)sulfanyl-4,4,4-trifluorobutanoic acid —— C12H13F3O2S
    (3R)-3-(2,5-dimethylphenyl)sulfanyl-4,4,4-trifluorobutanoic acid
    —— (1R,2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C10H12N2O3S
    (1R,2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1S,2R)-2-pyrimidin-2-ylsulfanylcyclopentane-1-carboxylic acid —— C10H12N2O2S
    (1S,2R)-2-pyrimidin-2-ylsulfanylcyclopentane-1-carboxylic acid
    —— (1R,2R,4S)-4-ethyl-2-(2-fluorophenyl)sulfanylcyclohexane-1-carboxylic acid —— C15H19FO2S
    (1R,2R,4S)-4-ethyl-2-(2-fluorophenyl)sulfanylcyclohexane-1-carboxylic acid
    —— (1R,2R,4R)-4-ethyl-2-pyridin-2-ylsulfanylcyclohexane-1-carboxylic acid —— C14H19NO2S
    (1R,2R,4R)-4-ethyl-2-pyridin-2-ylsulfanylcyclohexane-1-carboxylic acid
    —— (1R,2S,4S)-4-methyl-2-(4-methylphenyl)sulfanylcyclohexane-1-carboxylic acid —— C15H20O2S
    (1R,2S,4S)-4-methyl-2-(4-methylphenyl)sulfanylcyclohexane-1-carboxylic acid
    —— (1S,2R,4S)-4-ethyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)cyclohexane-1-carboxylic acid —— C11H16N2O2S2
    (1S,2R,4S)-4-ethyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)cyclohexane-1-carboxylic acid
    —— (1S,2R)-2-(1,3,4-thiadiazol-2-ylsulfanyl)cyclohexane-1-carboxylic acid —— C9H12N2O2S2
    (1S,2R)-2-(1,3,4-thiadiazol-2-ylsulfanyl)cyclohexane-1-carboxylic acid
    —— (1R,2R)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C13H18N2O3S
    (1R,2R)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1S,2R,4R)-4-methyl-2-(1-methyltetrazol-5-yl)sulfanylcyclohexane-1-carboxylic acid —— C10H16N4O2S
    (1S,2R,4R)-4-methyl-2-(1-methyltetrazol-5-yl)sulfanylcyclohexane-1-carboxylic acid
    —— (1S,2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cycloheptane-1-carboxylic acid —— C10H15N3O2S
    (1S,2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cycloheptane-1-carboxylic acid
    —— (1R,2R,4S)-4-ethyl-2-pyrimidin-2-ylsulfanylcyclohexane-1-carboxylic acid —— C13H18N2O2S
    (1R,2R,4S)-4-ethyl-2-pyrimidin-2-ylsulfanylcyclohexane-1-carboxylic acid
    —— (1R,2S,4S)-4-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C12H17NO2S2
    (1R,2S,4S)-4-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1R,2R,4S)-4-ethyl-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C12H19N3O2S
    (1R,2R,4S)-4-ethyl-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (1S,2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C9H13N3O2S
    (1S,2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1R,2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C10H13NO2S2
    (1R,2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— (1S,2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carboxylic acid —— C10H15N3O2S
    (1S,2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carboxylic acid
    —— (2R)-3-(2,5-dimethylphenyl)sulfanyl-2-ethoxypropanoic acid —— C13H18O3S
    (2R)-3-(2,5-dimethylphenyl)sulfanyl-2-ethoxypropanoic acid