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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4S)-N-methyl-8-methylsulfonyloctan-4-amine —— C10H23NO2S
    (4S)-N-methyl-8-methylsulfonyloctan-4-amine
    —— (1S)-1-cyclohexyl-N-(3-methylsulfonylpropyl)propan-1-amine —— C13H27NO2S
    (1S)-1-cyclohexyl-N-(3-methylsulfonylpropyl)propan-1-amine
    —— (2R,3S)-6-methylsulfonyl-3-propan-2-yl-N-propylhexan-2-amine —— C13H29NO2S
    (2R,3S)-6-methylsulfonyl-3-propan-2-yl-N-propylhexan-2-amine
    —— (1R)-1-cyclohexyl-N-(3-methylsulfonylpropyl)propan-1-amine —— C13H27NO2S
    (1R)-1-cyclohexyl-N-(3-methylsulfonylpropyl)propan-1-amine
    —— (2S,4S)-2-(3-methylsulfonylpropyl)-4-propylcyclohexan-1-one —— C13H24O3S
    (2S,4S)-2-(3-methylsulfonylpropyl)-4-propylcyclohexan-1-one
    —— (2R,3R)-6-methylsulfonyl-3-propan-2-yl-N-propylhexan-2-amine —— C13H29NO2S
    (2R,3R)-6-methylsulfonyl-3-propan-2-yl-N-propylhexan-2-amine
    —— (2R,4R)-2-(3-methylsulfonylpropyl)-4-propylcyclohexan-1-one —— C13H24O3S
    (2R,4R)-2-(3-methylsulfonylpropyl)-4-propylcyclohexan-1-one
    —— (2S,4R)-2-(3-methylsulfonylpropyl)-4-propylcyclohexan-1-one —— C13H24O3S
    (2S,4R)-2-(3-methylsulfonylpropyl)-4-propylcyclohexan-1-one
    —— propan-2-yl (2S)-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]propanoate —— C9H13N3O4S
    propan-2-yl (2S)-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]propanoate
    —— (4R)-N-methyl-8-methylsulfonyloctan-4-amine —— C10H23NO2S
    (4R)-N-methyl-8-methylsulfonyloctan-4-amine
    —— (2S,3S)-6-methylsulfonyl-3-propan-2-yl-N-propylhexan-2-amine —— C13H29NO2S
    (2S,3S)-6-methylsulfonyl-3-propan-2-yl-N-propylhexan-2-amine
    —— (E)-4-hydroxy-3-[(R)-phenyl(phenylsulfanyl)methyl]pent-3-en-2-one —— C18H18O2S
    (E)-4-hydroxy-3-[(R)-phenyl(phenylsulfanyl)methyl]pent-3-en-2-one
    —— (5S,7R)-3-[(1R)-1-aminoethyl]adamantane-1-thiol —— C12H21NS
    (5S,7R)-3-[(1R)-1-aminoethyl]adamantane-1-thiol
    —— (Z)-4-hydroxy-3-[(S)-phenyl(phenylsulfanyl)methyl]pent-3-en-2-one —— C18H18O2S
    (Z)-4-hydroxy-3-[(S)-phenyl(phenylsulfanyl)methyl]pent-3-en-2-one
    —— (2R)-2-[3-(pyridin-2-ylamino)pyridin-2-yl]sulfanylbutanoate —— C14H14N3O2S-
    (2R)-2-[3-(pyridin-2-ylamino)pyridin-2-yl]sulfanylbutanoate
    —— (R)-2-Methylbutan-1-thiol —— C5H12S
    (R)-2-Methylbutan-1-thiol
    —— (2S)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile —— C18H11Cl2N3S
    (2S)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile
    —— diethyl (8R)-10-amino-8-phenyl-2,4-dithia-12-azatricyclo[7.3.0.03,7]dodeca-1(9),3(7),5,10-tetraene-5,11-dicarboxylate —— C21H20N2O4S2
    diethyl (8R)-10-amino-8-phenyl-2,4-dithia-12-azatricyclo[7.3.0.03,7]dodeca-1(9),3(7),5,10-tetraene-5,11-dicarboxylate
    —— diethyl (8S)-10-amino-8-phenyl-2,4-dithia-12-azatricyclo[7.3.0.03,7]dodeca-1(9),3(7),5,10-tetraene-5,11-dicarboxylate —— C21H20N2O4S2
    diethyl (8S)-10-amino-8-phenyl-2,4-dithia-12-azatricyclo[7.3.0.03,7]dodeca-1(9),3(7),5,10-tetraene-5,11-dicarboxylate
    —— (2R)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H13Cl2N3OS
    (2R)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— (2S)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H13Cl2N3OS
    (2S)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— (2R)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile —— C18H11Cl2N3S
    (2R)-2-(2,6-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile
    —— 1-Oxido-4-phenylsulfanylpyridin-1-ium-3-carboxylate —— C12H8NO3S-
    1-Oxido-4-phenylsulfanylpyridin-1-ium-3-carboxylate
    —— (2S)-1-[(4R)-4-methylazepan-1-yl]-2-phenylsulfanylpropan-1-one —— C16H23NOS
    (2S)-1-[(4R)-4-methylazepan-1-yl]-2-phenylsulfanylpropan-1-one
    —— 4-methyl-5-[3-[(4R)-4-methylazepan-1-yl]-3-oxopropyl]-2-methylsulfanyl-1H-pyrimidin-6-one —— C16H25N3O2S
    4-methyl-5-[3-[(4R)-4-methylazepan-1-yl]-3-oxopropyl]-2-methylsulfanyl-1H-pyrimidin-6-one
    —— (2R)-2-(2-methylsulfanylphenyl)azepane —— C13H19NS
    (2R)-2-(2-methylsulfanylphenyl)azepane
    —— (2R)-2-(2-methylsulfanylphenyl)azepan-1-ium —— C13H20NS+
    (2R)-2-(2-methylsulfanylphenyl)azepan-1-ium
    —— (2S)-2-(2-methylsulfanylphenyl)azepane —— C13H19NS
    (2S)-2-(2-methylsulfanylphenyl)azepane
    —— 2-(2-Amino-5-chlorophenyl)sulfanylacetate —— C8H7ClNO2S-
    2-(2-Amino-5-chlorophenyl)sulfanylacetate
    —— 4-(4-Piperidin-1-ium-1-ylbutylsulfanyl)phenol —— C15H24NOS+
    4-(4-Piperidin-1-ium-1-ylbutylsulfanyl)phenol
    —— (2S)-2,3,3,3-tetrafluoro-2-methoxy-N-(3-nitro-5-phenylsulfanylphenyl)propanamide —— C16H12F4N2O4S
    (2S)-2,3,3,3-tetrafluoro-2-methoxy-N-(3-nitro-5-phenylsulfanylphenyl)propanamide
    —— (3S)-3-(ethenylsulfonylmethyl)heptane —— C10H20O2S
    (3S)-3-(ethenylsulfonylmethyl)heptane
    —— (5R,7R)-5,7-diethyl-2-sulfanylidene-[1,3]dithiolo[4,5-b][1,4]dithiepin-6-one —— C10H12OS5
    (5R,7R)-5,7-diethyl-2-sulfanylidene-[1,3]dithiolo[4,5-b][1,4]dithiepin-6-one
    —— (3R)-3-(ethenylsulfonylmethyl)heptane —— C10H20O2S
    (3R)-3-(ethenylsulfonylmethyl)heptane
    —— (2S)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2S)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide
    —— (2R)-2-[[5-[(2S)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2R)-2-[[5-[(2S)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide
    —— 2-methylpropyl (6R)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate —— C20H24N2O3S2
    2-methylpropyl (6R)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate
    —— (2S)-2-[[5-[(2S)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2S)-2-[[5-[(2S)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide
    —— 2-methylpropyl (6S)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate —— C20H24N2O3S2
    2-methylpropyl (6S)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate
    —— (1S,5R,6S)-2-amino-4,4-dimethoxy-6-(4-methylsulfanylphenyl)-3-azoniabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitrile —— C16H17N4O2S+
    (1S,5R,6S)-2-amino-4,4-dimethoxy-6-(4-methylsulfanylphenyl)-3-azoniabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitrile
    —— (1S,5R,6S)-2-amino-4,4-dimethoxy-6-(4-methylsulfanylphenyl)-3-azabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitrile —— C16H16N4O2S
    (1S,5R,6S)-2-amino-4,4-dimethoxy-6-(4-methylsulfanylphenyl)-3-azabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitrile
    —— [(1R)-1-[4-benzyl-5-[(2S)-1-(cyclohexylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1R)-1-[4-benzyl-5-[(2S)-1-(cyclohexylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C18H24N4O2S
    2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— (2S)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide —— C23H35N5OS
    (2S)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide
    —— (2S)-2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide —— C23H35N5OS
    (2S)-2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide
    —— (2R)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide —— C23H35N5OS
    (2R)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide
    —— N-cyclohexyl-N-ethyl-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H22FN3OS3
    N-cyclohexyl-N-ethyl-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— [(1S)-1-[4-butyl-5-[2-(cyclohexylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C19H36N5OS+
    [(1S)-1-[4-butyl-5-[2-(cyclohexylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[2-[(4-methylcyclohexyl)amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1R)-1-[4-benzyl-5-[2-[(4-methylcyclohexyl)amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylacetamide —— C19H35N5OS
    2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylacetamide