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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-pentan-3-ylacetamide —— C19H28N4O2S
    2-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-pentan-3-ylacetamide
    —— [(1R)-1-[4-butyl-5-[2-(cyclohexylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C19H36N5OS+
    [(1R)-1-[4-butyl-5-[2-(cyclohexylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[(2R)-1-(cyclohexylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1S)-1-[4-benzyl-5-[(2R)-1-(cyclohexylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide —— C23H35N5OS
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide
    —— [(1S)-1-[4-benzyl-5-[2-[(4-methylcyclohexyl)amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1S)-1-[4-benzyl-5-[2-[(4-methylcyclohexyl)amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylacetamide —— C19H35N5OS
    2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylacetamide
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide —— C23H35N5OS
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide
    —— (1S)-1-[4-(cyclopentylmethylsulfanyl)phenyl]-N-ethylethanamine —— C16H25NS
    (1S)-1-[4-(cyclopentylmethylsulfanyl)phenyl]-N-ethylethanamine
    —— (1R)-1-[4-(cyclopentylmethylsulfanyl)phenyl]-N-ethylethanamine —— C16H25NS
    (1R)-1-[4-(cyclopentylmethylsulfanyl)phenyl]-N-ethylethanamine
    —— ethyl N-[2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]carbamate —— C16H24N4O3S
    ethyl N-[2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]carbamate
    —— 2-(cyclopentylmethylsulfanyl)-N'-hydroxy-4,6-dimethylpyridine-3-carboximidamide —— C14H21N3OS
    2-(cyclopentylmethylsulfanyl)-N'-hydroxy-4,6-dimethylpyridine-3-carboximidamide
    —— 4-chloro-2-(cyclopentylmethylsulfanyl)-N'-hydroxybenzenecarboximidamide —— C13H17ClN2OS
    4-chloro-2-(cyclopentylmethylsulfanyl)-N'-hydroxybenzenecarboximidamide
    —— (2R)-N-cyclohexyl-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C18H26N4OS2
    (2R)-N-cyclohexyl-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— [(3S)-5-(4-bromophenyl)sulfanyl-3-cyano-4-oxopent-1-en-2-yl]azanium —— C12H12BrN2OS+
    [(3S)-5-(4-bromophenyl)sulfanyl-3-cyano-4-oxopent-1-en-2-yl]azanium
    —— (2S)-N-cyclohexyl-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C18H26N4OS2
    (2S)-N-cyclohexyl-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— (2S)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-methylpropanamide —— C23H28N4O2S
    (2S)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-methylpropanamide
    —— 4-(cyclopentylmethylsulfanyl)-N'-hydroxy-3-methylbenzenecarboximidamide —— C14H20N2OS
    4-(cyclopentylmethylsulfanyl)-N'-hydroxy-3-methylbenzenecarboximidamide
    —— (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-methylpropanamide —— C23H28N4O2S
    (2R)-2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-methylpropanamide
    —— 1-[(3R,7E)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3,4,5,6-tetrahydro-1H-indazol-2-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone —— C22H22N4O3S
    1-[(3R,7E)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3,4,5,6-tetrahydro-1H-indazol-2-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone
    —— 6-(cyclopentylmethylsulfanyl)-N'-hydroxypyridine-3-carboximidamide —— C12H17N3OS
    6-(cyclopentylmethylsulfanyl)-N'-hydroxypyridine-3-carboximidamide
    —— (1S)-1-(4-cyclopentylsulfanylphenyl)-N-methylethanamine —— C14H21NS
    (1S)-1-(4-cyclopentylsulfanylphenyl)-N-methylethanamine
    —— 2-[(R)-cyclopentylsulfinyl]ethanamine —— C7H15NOS
    2-[(R)-cyclopentylsulfinyl]ethanamine
    —— 2-cyclopentylsulfanyl-N'-hydroxy-6-methylpyridine-3-carboximidamide —— C12H17N3OS
    2-cyclopentylsulfanyl-N'-hydroxy-6-methylpyridine-3-carboximidamide
    —— 2-cyclopentylsulfanyl-N'-hydroxy-5-nitropyridine-3-carboximidamide —— C11H14N4O3S
    2-cyclopentylsulfanyl-N'-hydroxy-5-nitropyridine-3-carboximidamide
    —— [(3R)-5-[2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]oxy-3-cyano-4-oxopent-1-en-2-yl]azanium —— C21H20N5O4S+
    [(3R)-5-[2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]oxy-3-cyano-4-oxopent-1-en-2-yl]azanium
    —— (1R)-1-(4-cyclopentylsulfanylphenyl)-N-methylethanamine —— C14H21NS
    (1R)-1-(4-cyclopentylsulfanylphenyl)-N-methylethanamine
    —— (1S)-1-(2-cyclopentylsulfanyl-6-fluorophenyl)-N-methylethanamine —— C14H20FNS
    (1S)-1-(2-cyclopentylsulfanyl-6-fluorophenyl)-N-methylethanamine
    —— N-cyclohexyl-N-ethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C18H23N3OS3
    N-cyclohexyl-N-ethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-cyclopentylsulfanylpropan-1-amine —— C8H17NS
    (2R)-2-cyclopentylsulfanylpropan-1-amine
    —— (2R)-2-cyclopentylsulfanyl-2-(4-methylsulfanylphenyl)propanoic acid —— C15H20O2S2
    (2R)-2-cyclopentylsulfanyl-2-(4-methylsulfanylphenyl)propanoic acid
    —— N-(4-methylcyclohexyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C17H21N3OS3
    N-(4-methylcyclohexyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (1R)-1-(2-cyclopentylsulfanyl-5-fluorophenyl)-N-methylethanamine —— C14H20FNS
    (1R)-1-(2-cyclopentylsulfanyl-5-fluorophenyl)-N-methylethanamine
    —— 2-[(S)-cyclopentylsulfinyl]ethanamine —— C7H15NOS
    2-[(S)-cyclopentylsulfinyl]ethanamine
    —— 3-chloro-4-cyclopentylsulfanyl-N'-hydroxybenzenecarboximidamide —— C12H15ClN2OS
    3-chloro-4-cyclopentylsulfanyl-N'-hydroxybenzenecarboximidamide
    —— (2S)-2-cyclopentylsulfanylpropan-1-amine —— C8H17NS
    (2S)-2-cyclopentylsulfanylpropan-1-amine
    —— (2S)-2-cyclopentylsulfanyl-2-(4-methylsulfanylphenyl)propanoic acid —— C15H20O2S2
    (2S)-2-cyclopentylsulfanyl-2-(4-methylsulfanylphenyl)propanoic acid
    —— (1S)-1-(3-bromo-4-cyclopentylsulfanylphenyl)-N-methylethanamine —— C14H20BrNS
    (1S)-1-(3-bromo-4-cyclopentylsulfanylphenyl)-N-methylethanamine
    —— 2-chloro-6-cyclopentylsulfanyl-N'-hydroxybenzenecarboximidamide —— C12H15ClN2OS
    2-chloro-6-cyclopentylsulfanyl-N'-hydroxybenzenecarboximidamide
    —— (1R)-1-(3-bromo-4-cyclopentylsulfanylphenyl)-N-methylethanamine —— C14H20BrNS
    (1R)-1-(3-bromo-4-cyclopentylsulfanylphenyl)-N-methylethanamine
    —— (1S)-1-(2-cyclopentylsulfanyl-5-fluorophenyl)-N-methylethanamine —— C14H20FNS
    (1S)-1-(2-cyclopentylsulfanyl-5-fluorophenyl)-N-methylethanamine
    —— (1R)-1-(2-cyclopentylsulfanyl-6-fluorophenyl)-N-methylethanamine —— C14H20FNS
    (1R)-1-(2-cyclopentylsulfanyl-6-fluorophenyl)-N-methylethanamine
    —— 2-[[3-cyano-4-(furan-2-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl]acetate —— C15H11N2O3S-
    2-[[3-cyano-4-(furan-2-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl]acetate
    —— [(3R)-3-cyano-5-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]-4-oxopent-1-en-2-yl]azanium —— C15H14F2N5OS3+
    [(3R)-3-cyano-5-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]-4-oxopent-1-en-2-yl]azanium
    —— (1'R,5'R)-spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-carboxylate —— C11H15O2S2-
    (1'R,5'R)-spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-carboxylate
    —— [(3R)-3-cyano-4-oxo-5-[[5-(propan-2-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]pent-1-en-2-yl]azanium —— C11H16N5OS2+
    [(3R)-3-cyano-4-oxo-5-[[5-(propan-2-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]pent-1-en-2-yl]azanium
    —— 2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-5-(trifluoromethyl)pyridine —— C17H15F3N4OS2
    2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-5-(trifluoromethyl)pyridine
    —— [(3R)-5-(2-chlorophenyl)sulfanyl-3-cyano-4-oxopent-1-en-2-yl]azanium —— C12H12ClN2OS+
    [(3R)-5-(2-chlorophenyl)sulfanyl-3-cyano-4-oxopent-1-en-2-yl]azanium
    —— [(3S)-3-cyano-5-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-4-oxopent-1-en-2-yl]azanium —— C10H12N3OS2+
    [(3S)-3-cyano-5-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-4-oxopent-1-en-2-yl]azanium
    —— 5-ethyl-6-methyl-2-(3-nitropyridin-2-yl)sulfanyl-3-[[(2R)-oxolan-2-yl]methyl]thieno[2,3-d]pyrimidin-4-one —— C19H20N4O4S2
    5-ethyl-6-methyl-2-(3-nitropyridin-2-yl)sulfanyl-3-[[(2R)-oxolan-2-yl]methyl]thieno[2,3-d]pyrimidin-4-one
    —— 2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-5-(trifluoromethyl)pyridine —— C17H15F3N4OS2
    2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-5-(trifluoromethyl)pyridine