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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [4-(2-Hydroxyethyl)piperazin-4-ium-1-yl]-(4-methylsulfanylphenyl)methanethione —— C14H21N2OS2+
    [4-(2-Hydroxyethyl)piperazin-4-ium-1-yl]-(4-methylsulfanylphenyl)methanethione
    —— N-[(2-fluorophenyl)methyl]-2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]acetamide —— C17H16FN3O2S
    N-[(2-fluorophenyl)methyl]-2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]acetamide
    —— (2R)-1-[[5-(2-chloro-4,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C19H27ClN4O2S2
    (2R)-1-[[5-(2-chloro-4,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— N-[(3-fluorophenyl)methyl]-2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]acetamide —— C17H16FN3O2S
    N-[(3-fluorophenyl)methyl]-2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]acetamide
    —— 2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C15H19N3O3S
    2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]-N-[(3-methylphenyl)methyl]acetamide —— C18H19N3O2S
    2-[(3S)-1-methyl-2-oxopyrido[2,3-b][1,4]thiazin-3-yl]-N-[(3-methylphenyl)methyl]acetamide
    —— (2R)-1-(4-methylpiperidin-1-yl)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol —— C15H21N3O2S2
    (2R)-1-(4-methylpiperidin-1-yl)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2R)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C17H30N4OS2
    (2R)-1-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2R)-1-(4-methylpiperidin-1-yl)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol —— C12H21N3OS2
    (2R)-1-(4-methylpiperidin-1-yl)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2R)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C15H28N4O2S
    (2R)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2S)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol —— C12H21N3O2S2
    (2S)-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-2-ol
    —— (2R)-1-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol —— C19H28N4O2S2
    (2R)-1-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propan-2-ol
    —— (2S)-1-(4-methylpiperidin-1-yl)-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol —— C11H21N5OS
    (2S)-1-(4-methylpiperidin-1-yl)-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol
    —— (2R)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol —— C18H26N4O2S2
    (2R)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-2-ol
    —— (2R)-1-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol —— C18H26N4OS2
    (2R)-1-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— 2-[(2S)-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-hydroxypropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile —— C17H25N3O2S
    2-[(2S)-3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-hydroxypropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol —— C11H21N5O2S
    (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-(1-methyltetrazol-5-yl)sulfanylpropan-2-ol
    —— 4-Ethylsulfanylbenzenethiolate —— C8H9S2-
    4-Ethylsulfanylbenzenethiolate
    —— (2S)-1-(1-methylimidazol-2-yl)sulfanyl-3-(4-methylpiperidin-1-yl)propan-2-ol —— C13H23N3OS
    (2S)-1-(1-methylimidazol-2-yl)sulfanyl-3-(4-methylpiperidin-1-yl)propan-2-ol
    —— (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-(1-methylimidazol-2-yl)sulfanylpropan-2-ol —— C13H23N3O2S
    (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-3-(1-methylimidazol-2-yl)sulfanylpropan-2-ol
    —— N-[2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-2-methylpropyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C15H26N4OS2
    N-[2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-2-methylpropyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-Tert-butyl-2-({1-[(furan-2-YL)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C14H19N3O2S
    N-Tert-butyl-2-({1-[(furan-2-YL)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— 2-[(1-Benzyl-1H-imidazol-2-YL)sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide —— C19H18FN3OS
    2-[(1-Benzyl-1H-imidazol-2-YL)sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide
    —— N-(2-chlorobenzyl)-2-((6-methyl-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)acetamide —— C13H13ClN4O2S
    N-(2-chlorobenzyl)-2-((6-methyl-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)acetamide
    —— N-[(4-Fluorophenyl)methyl]-2-({1-[(4-fluorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C19H17F2N3OS
    N-[(4-Fluorophenyl)methyl]-2-({1-[(4-fluorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— 2-({1-[(4-Fluorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-[(furan-2-YL)methyl]acetamide —— C17H16FN3O2S
    2-({1-[(4-Fluorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-[(furan-2-YL)methyl]acetamide
    —— N-Benzyl-2-({1-[(4-chlorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C19H18ClN3OS
    N-Benzyl-2-({1-[(4-chlorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— N-cyclohexyl-2-[1-[(4-methylphenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C19H25N3OS
    N-cyclohexyl-2-[1-[(4-methylphenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— N-[(4-fluorophenyl)methyl]-2-[1-(furan-2-ylmethyl)imidazol-2-yl]sulfanylacetamide —— C17H16FN3O2S
    N-[(4-fluorophenyl)methyl]-2-[1-(furan-2-ylmethyl)imidazol-2-yl]sulfanylacetamide
    —— 2-[(1-Benzyl-1H-imidazol-2-YL)sulfanyl]-N-(2-methoxyethyl)acetamide —— C15H19N3O2S
    2-[(1-Benzyl-1H-imidazol-2-YL)sulfanyl]-N-(2-methoxyethyl)acetamide
    —— 2-({1-[(4-Chlorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-cyclohexylacetamide —— C18H22ClN3OS
    2-({1-[(4-Chlorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-cyclohexylacetamide
    —— 2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanyl-N-methylacetamide —— C13H14ClN3OS
    2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanyl-N-methylacetamide
    —— N-cyclohexyl-2-((1-(4-fluorobenzyl)-1H-imidazol-2-yl)thio)acetamide —— C18H22FN3OS
    N-cyclohexyl-2-((1-(4-fluorobenzyl)-1H-imidazol-2-yl)thio)acetamide
    —— 2-((1-(furan-2-ylmethyl)-1H-imidazol-2-yl)thio)acetamide —— C10H11N3O2S
    2-((1-(furan-2-ylmethyl)-1H-imidazol-2-yl)thio)acetamide
    —— N-(2-Methoxyethyl)-2-({1-[(4-methylphenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C16H21N3O2S
    N-(2-Methoxyethyl)-2-({1-[(4-methylphenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— N-Benzyl-2-({1-[(4-fluorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C19H18FN3OS
    N-Benzyl-2-({1-[(4-fluorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— 2-({1-[(4-Methylphenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-(2-phenylethyl)acetamide —— C21H23N3OS
    2-({1-[(4-Methylphenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-(2-phenylethyl)acetamide
    —— 2-[(1-benzyl-1H-imidazol-2-yl)thio]-N-(2-phenylethyl)acetamide —— C20H21N3OS
    2-[(1-benzyl-1H-imidazol-2-yl)thio]-N-(2-phenylethyl)acetamide
    —— 2-[(1-Benzyl-1H-imidazol-2-YL)sulfanyl]-N-(propan-2-YL)acetamide —— C15H19N3OS
    2-[(1-Benzyl-1H-imidazol-2-YL)sulfanyl]-N-(propan-2-YL)acetamide
    —— 2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide —— C20H25FN4OS
    2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide
    —— 2-[6-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C21H28N4OS2
    2-[6-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— 2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide —— C21H28N4OS
    2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide
    —— 2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C21H28N4OS2
    2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— 2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide —— C20H25FN4OS
    2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide
    —— 2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide —— C21H28N4OS
    2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-methylphenyl)methyl]acetamide
    —— 2-[6-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide —— C20H25FN4OS
    2-[6-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide
    —— N-benzyl-2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetamide —— C20H26N4OS
    N-benzyl-2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetamide
    —— N-[(2R)-butan-2-yl]-2-(4-methyl-3,5-dioxopyridazino[4,5-b][1,4]thiazin-6-yl)acetamide —— C13H18N4O3S
    N-[(2R)-butan-2-yl]-2-(4-methyl-3,5-dioxopyridazino[4,5-b][1,4]thiazin-6-yl)acetamide
    —— N-benzyl-2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetamide —— C20H26N4OS
    N-benzyl-2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetamide
    —— N-[(4-chlorophenyl)methyl]-2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetamide —— C20H25ClN4OS
    N-[(4-chlorophenyl)methyl]-2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetamide