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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-chlorophenyl)propanoate —— C12H12ClN3O2S2
    methyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-chlorophenyl)propanoate
    —— methyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-butylphenyl)propanoate —— C16H21N3O2S2
    methyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-butylphenyl)propanoate
    —— ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(3-methylphenyl)propanoate —— C14H17N3O2S2
    ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(3-methylphenyl)propanoate
    —— ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(3-methylphenyl)propanoate —— C14H17N3O2S2
    ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(3-methylphenyl)propanoate
    —— ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(2-chlorophenyl)propanoate —— C13H14ClN3O2S2
    ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(2-chlorophenyl)propanoate
    —— ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(2-chlorophenyl)propanoate —— C13H14ClN3O2S2
    ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(2-chlorophenyl)propanoate
    —— methyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-chlorophenyl)propanoate —— C12H12ClN3O2S2
    methyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-chlorophenyl)propanoate
    —— 5-[(2Z)-2-benzylidenehydrazinyl]-3-benzylsulfanyl-1,2-thiazole-4-carbonitrile —— C18H14N4S2
    5-[(2Z)-2-benzylidenehydrazinyl]-3-benzylsulfanyl-1,2-thiazole-4-carbonitrile
    —— 5-(Butylsulfonyl)-6-[2-(butylsulfonyl)vinyl]bicyclo[2.2.1]hept-2-ene —— C17H28O4S2
    5-(Butylsulfonyl)-6-[2-(butylsulfonyl)vinyl]bicyclo[2.2.1]hept-2-ene
    —— 5-[(2Z)-2-[(3-hydroxyphenyl)methylidene]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile —— C12H10N4OS2
    5-[(2Z)-2-[(3-hydroxyphenyl)methylidene]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile
    —— (2R)-N-(cyclooctylmethyl)-2-propan-2-ylsulfonylpropanamide —— C15H29NO3S
    (2R)-N-(cyclooctylmethyl)-2-propan-2-ylsulfonylpropanamide
    —— 2-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-5-(methylsulfanylmethyl)-1,3,4-oxadiazole —— C12H13FN2OS2
    2-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-5-(methylsulfanylmethyl)-1,3,4-oxadiazole
    —— 4-methyl-5-[3-[(4S)-4-methylazepan-1-yl]-3-oxopropyl]-2-methylsulfanyl-1H-pyrimidin-6-one —— C16H25N3O2S
    4-methyl-5-[3-[(4S)-4-methylazepan-1-yl]-3-oxopropyl]-2-methylsulfanyl-1H-pyrimidin-6-one
    —— 6-methyl-2-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanylpyrimidin-4-amine —— C13H13N5OS2
    6-methyl-2-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanylpyrimidin-4-amine
    —— 6-methyl-2-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanylpyrimidin-4-amine —— C13H13N5OS2
    6-methyl-2-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanylpyrimidin-4-amine
    —— 1-[[5-[[(3R)-1,4-dioxaspiro[4.4]nonan-3-yl]methylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one —— C15H21N3O4S
    1-[[5-[[(3R)-1,4-dioxaspiro[4.4]nonan-3-yl]methylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one
    —— 1-[[5-[[(3S)-1,4-dioxaspiro[4.4]nonan-3-yl]methylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one —— C15H21N3O4S
    1-[[5-[[(3S)-1,4-dioxaspiro[4.4]nonan-3-yl]methylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-phenylbutan-2-ylideneamino]acetamide —— C18H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-phenylbutan-2-ylideneamino]acetamide
    —— 4-[2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]morpholin-4-ium —— C12H16N3O3S+
    4-[2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]morpholin-4-ium
    —— (2R)-5-ethoxy-2-[N-[(4-fluorophenyl)methyl]-C-methylcarbonimidoyl]-1-benzothiophen-3-one —— C19H18FNO2S
    (2R)-5-ethoxy-2-[N-[(4-fluorophenyl)methyl]-C-methylcarbonimidoyl]-1-benzothiophen-3-one
    —— 3-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C7H10N3O2S-
    3-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— 3-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoic acid —— C7H11N3O2S
    3-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoic acid
    —— 5-[(1S)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C11H16N4OS3
    5-[(1S)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— (2S)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile —— C14H16N4S
    (2S)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 5-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C11H16N4OS3
    5-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— (2R)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile —— C14H16N4S
    (2R)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 1-[5-ethylsulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]piperidine —— C14H24N4OS
    1-[5-ethylsulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]piperidine
    —— 1-[5-ethylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]piperidine —— C14H24N4OS
    1-[5-ethylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]piperidine
    —— methyl (2R)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanoate —— C10H17N3O2S
    methyl (2R)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanoate
    —— methyl (2R)-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C11H17N3O3S2
    methyl (2R)-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 3-methyl-1-benzofuran-2-carboxylate —— C24H19NO4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 3-methyl-1-benzofuran-2-carboxylate
    —— methyl (2S)-2-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C11H17N3O3S2
    methyl (2S)-2-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 1-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropan-2-ol —— C15H30N4OS
    1-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropan-2-ol
    —— 1-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropan-2-ol —— C15H30N4OS
    1-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropan-2-ol
    —— methyl (2S)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanoate —— C10H17N3O2S
    methyl (2S)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanoate
    —— methyl (2R)-2-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C11H17N3O3S2
    methyl (2R)-2-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 2-[(2,6-Difluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one —— C20H17F3N2OS
    2-[(2,6-Difluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one
    —— methyl (2S)-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C11H17N3O3S2
    methyl (2S)-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 3-Methyl-2-[(4-methylphenyl)methylsulfanyl]-6-propan-2-ylpyrimidin-4-one —— C16H20N2OS
    3-Methyl-2-[(4-methylphenyl)methylsulfanyl]-6-propan-2-ylpyrimidin-4-one
    —— (2R)-N-[[4-(difluoromethylsulfanyl)phenyl]methyl]-N-methyloxolane-2-carboxamide —— C14H17F2NO2S
    (2R)-N-[[4-(difluoromethylsulfanyl)phenyl]methyl]-N-methyloxolane-2-carboxamide
    —— 3-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C13H16ClNO3S2
    3-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— 3-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C13H16ClNO3S2
    3-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-[(2R)-oxolan-2-yl]acetamide —— C16H19N3O2S
    N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-[(2R)-oxolan-2-yl]acetamide
    —— N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-[(2S)-oxolan-2-yl]acetamide —— C16H19N3O2S
    N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-[(2S)-oxolan-2-yl]acetamide
    —— 2-[(2,4-difluorobenzyl)sulfanyl]-3,6-dimethyl-5-(3-methylbenzyl)-4(3H)-pyrimidinone —— C21H20F2N2OS
    2-[(2,4-difluorobenzyl)sulfanyl]-3,6-dimethyl-5-(3-methylbenzyl)-4(3H)-pyrimidinone
    —— (1S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-fluorophenyl)ethanol —— C10H10FN3OS2
    (1S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-fluorophenyl)ethanol
    —— (8R,8aS)-6-imino-8-(4-methylsulfanylphenyl)-2-propyl-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile —— C22H24N5S+
    (8R,8aS)-6-imino-8-(4-methylsulfanylphenyl)-2-propyl-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile
    —— N-[(R)-cyano-(2,4-difluorophenyl)methyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H14F2N4OS
    N-[(R)-cyano-(2,4-difluorophenyl)methyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (1R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-fluorophenyl)ethanol —— C10H10FN3OS2
    (1R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-fluorophenyl)ethanol
    —— (8R,8aS)-2-ethyl-6-imino-8-(4-methylsulfanylphenyl)-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile —— C21H22N5S+
    (8R,8aS)-2-ethyl-6-imino-8-(4-methylsulfanylphenyl)-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile