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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [4-Oxo-6-(pyrimidin-2-ylsulfanylmethyl)pyran-3-yl] 2-(4-chlorophenyl)acetate —— C18H13ClN2O4S
    [4-Oxo-6-(pyrimidin-2-ylsulfanylmethyl)pyran-3-yl] 2-(4-chlorophenyl)acetate
    —— [6-[(4-Methylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 2-(4-chlorophenyl)acetate —— C19H15ClN2O4S
    [6-[(4-Methylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 2-(4-chlorophenyl)acetate
    —— [4-Oxo-6-(pyrimidin-2-ylsulfanylmethyl)pyran-3-yl] 2-(4-fluorophenyl)acetate —— C18H13FN2O4S
    [4-Oxo-6-(pyrimidin-2-ylsulfanylmethyl)pyran-3-yl] 2-(4-fluorophenyl)acetate
    —— [4-Oxo-6-(pyrimidin-2-ylsulfanylmethyl)pyran-3-yl] 2-phenylacetate —— C18H14N2O4S
    [4-Oxo-6-(pyrimidin-2-ylsulfanylmethyl)pyran-3-yl] 2-phenylacetate
    —— [6-[(4,6-Dimethylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 2-phenylacetate —— C20H18N2O4S
    [6-[(4,6-Dimethylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 2-phenylacetate
    —— 4-oxo-6-((pyrimidin-2-ylthio)methyl)-4H-pyran-3-yl 2-(thiophen-2-yl)acetate —— C16H12N2O4S2
    4-oxo-6-((pyrimidin-2-ylthio)methyl)-4H-pyran-3-yl 2-(thiophen-2-yl)acetate
    —— [6-[(4-Methylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 2-(4-fluorophenyl)acetate —— C19H15FN2O4S
    [6-[(4-Methylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 2-(4-fluorophenyl)acetate
    —— (4S)-N-methyl-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-6-oxo-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridine-3-carboxamide —— C15H15N7O3S
    (4S)-N-methyl-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-6-oxo-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridine-3-carboxamide
    —— 1-(2-hydroxyethyl)-3-[(1R,5S)-3,3,5-trimethylcyclohexyl]thiourea —— C12H24N2OS
    1-(2-hydroxyethyl)-3-[(1R,5S)-3,3,5-trimethylcyclohexyl]thiourea
    —— 2-Ethylsulfanyl-5-[(4-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one —— C15H17FN2OS
    2-Ethylsulfanyl-5-[(4-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one
    —— 2-(4-tert-butyl-1-methyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-diethylacetamide —— C15H25N3O2S
    2-(4-tert-butyl-1-methyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-diethylacetamide
    —— methyl (2S)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C17H19FN2O3S
    methyl (2S)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylpropanoate
    —— 3,6-Dimethyl-5-[(2-methylphenyl)methyl]-2-prop-2-enylsulfanylpyrimidin-4-one —— C17H20N2OS
    3,6-Dimethyl-5-[(2-methylphenyl)methyl]-2-prop-2-enylsulfanylpyrimidin-4-one
    —— methyl (2R)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C17H19FN2O3S
    methyl (2R)-2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylpropanoate
    —— 6-Ethyl-3-methyl-2-[(2-methylphenyl)methylsulfanyl]pyrimidin-4-one —— C15H18N2OS
    6-Ethyl-3-methyl-2-[(2-methylphenyl)methylsulfanyl]pyrimidin-4-one
    —— 3-[(5-Imino-1,2,4-dithiazol-3-yl)sulfanyl]propanoate —— C5H5N2O2S3-
    3-[(5-Imino-1,2,4-dithiazol-3-yl)sulfanyl]propanoate
    —— 2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(1R)-1-propan-2-yloxyethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C14H21N5O3S
    2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(1R)-1-propan-2-yloxyethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5-cyclohexyl-4-prop-2-enyl-1,2,4-triazole —— C18H21ClFN3S
    3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5-cyclohexyl-4-prop-2-enyl-1,2,4-triazole
    —— 2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(1S)-1-propan-2-yloxyethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C14H21N5O3S
    2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(1S)-1-propan-2-yloxyethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (3R)-1-[2-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethylamino]pyrimidin-4-yl]piperidin-3-ol —— C13H19N7OS
    (3R)-1-[2-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethylamino]pyrimidin-4-yl]piperidin-3-ol
    —— (3S)-1-[2-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethylamino]pyrimidin-4-yl]piperidin-3-ol —— C13H19N7OS
    (3S)-1-[2-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethylamino]pyrimidin-4-yl]piperidin-3-ol
    —— ethyl (2S)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-phenylacetate —— C15H16N2O3S
    ethyl (2S)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-phenylacetate
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C14H15N3O2S
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— (2S)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C11H10BrN3O2S
    (2S)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C13H14BrN3O3S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C11H10BrN3O2S
    (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-{[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-N-tert-butylacetamide —— C14H16BrN3O2S
    2-{[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-N-tert-butylacetamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propylacetamide —— C13H14BrN3O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide —— C11H10BrN3O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 5-({5-[(4-Chlorophenyl)sulfanyl]thien-2-yl}methylene)-3-ethyl-2-(ethylimino)-1,3-thiazolidin-4-one —— C18H17ClN2OS3
    5-({5-[(4-Chlorophenyl)sulfanyl]thien-2-yl}methylene)-3-ethyl-2-(ethylimino)-1,3-thiazolidin-4-one
    —— (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide —— C14H14BrN3O2S
    (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H17BrN4O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide
    —— (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C11H8BrN3OS
    (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide —— C12H12BrN3O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C14H16BrN3O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1-cyanocyclopentyl)acetamide —— C16H15BrN4O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1-cyanocyclopentyl)acetamide
    —— 1-[2-[[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one —— C14H12BrN3O3S
    1-[2-[[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one
    —— (2S)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(methylcarbamoyl)propanamide —— C13H13BrN4O3S
    (2S)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(methylcarbamoyl)propanamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H17BrN4O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-cyanoethyl)acetamide —— C13H11BrN4O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-cyanoethyl)acetamide
    —— (2S)-4-phenyl-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]butan-2-amine —— C14H20N4S
    (2S)-4-phenyl-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]butan-2-amine
    —— (2R)-4-phenyl-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]butan-2-amine —— C14H20N4S
    (2R)-4-phenyl-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]butan-2-amine
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 5-chlorothiophene-2-carboxylate —— C19H14ClNO3S2
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 5-chlorothiophene-2-carboxylate
    —— 2-(2-methylquinazolin-4-yl)sulfanyl-N-(2-phenylsulfanylphenyl)acetamide —— C23H19N3OS2
    2-(2-methylquinazolin-4-yl)sulfanyl-N-(2-phenylsulfanylphenyl)acetamide
    —— (5aR,9aR)-2-chloro-6,7,8,9,9a,12-hexahydro-5aH-benzo[d][3,6,1]benzoxathiazocin-11-one —— C13H14ClNO2S
    (5aR,9aR)-2-chloro-6,7,8,9,9a,12-hexahydro-5aH-benzo[d][3,6,1]benzoxathiazocin-11-one
    —— (5aS,9aR)-2-chloro-6,7,8,9,9a,12-hexahydro-5aH-benzo[d][3,6,1]benzoxathiazocin-11-one —— C13H14ClNO2S
    (5aS,9aR)-2-chloro-6,7,8,9,9a,12-hexahydro-5aH-benzo[d][3,6,1]benzoxathiazocin-11-one
    —— (2S)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-N,6-dimethyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C17H20N4OS
    (2S)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-N,6-dimethyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2R)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-N,6-dimethyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C17H20N4OS
    (2R)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-N,6-dimethyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (4S)-4-[5-(4-methylphenyl)sulfanylfuran-2-yl]-6-oxo-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridine-3-carboxamide —— C18H16N4O3S
    (4S)-4-[5-(4-methylphenyl)sulfanylfuran-2-yl]-6-oxo-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridine-3-carboxamide
    —— N,N-diethyl-4-[(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]aniline —— C20H21N3OS
    N,N-diethyl-4-[(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]aniline