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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-((4-amino-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)-N-(4-fluorobenzyl)acetamide —— C12H12FN5O2S
    2-((4-amino-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)-N-(4-fluorobenzyl)acetamide
    —— 4-Amino-3-[(2-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-one 869067-98-1 C11H11ClN4OS
    4-Amino-3-[(2-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-one
    —— Methyl 2-(6-amino-3,5-dicyano-4-propan-2-ylpyridin-1-ium-2-yl)sulfanylacetate —— C13H15N4O2S+
    Methyl 2-(6-amino-3,5-dicyano-4-propan-2-ylpyridin-1-ium-2-yl)sulfanylacetate
    —— 2-((4-amino-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)-N-benzylacetamide —— C12H13N5O2S
    2-((4-amino-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)-N-benzylacetamide
    —— 4-amino-3-((4-fluorobenzyl)thio)-6-methyl-1,2,4-triazin-5(4H)-one —— C11H11FN4OS
    4-amino-3-((4-fluorobenzyl)thio)-6-methyl-1,2,4-triazin-5(4H)-one
    —— 4-amino-3-((2-chlorobenzyl)thio)-1,2,4-triazin-5(4H)-one —— C10H9ClN4OS
    4-amino-3-((2-chlorobenzyl)thio)-1,2,4-triazin-5(4H)-one
    —— 4-Methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-1-ium-9-amine —— C13H17N4OS+
    4-Methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-1-ium-9-amine
    —— 4-amino-3-((4-fluorobenzyl)thio)-1,2,4-triazin-5(4H)-one —— C10H9FN4OS
    4-amino-3-((4-fluorobenzyl)thio)-1,2,4-triazin-5(4H)-one
    —— 4-Amino-6-methyl-3-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazin-5-one —— C12H14N4OS
    4-Amino-6-methyl-3-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazin-5-one
    —— 2-((4-amino-6-methyl-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)-N-(2-chlorobenzyl)acetamide —— C13H14ClN5O2S
    2-((4-amino-6-methyl-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)-N-(2-chlorobenzyl)acetamide
    —— 4-amino-3-((2-chloro-6-fluorobenzyl)thio)-6-methyl-1,2,4-triazin-5(4H)-one —— C11H10ClFN4OS
    4-amino-3-((2-chloro-6-fluorobenzyl)thio)-6-methyl-1,2,4-triazin-5(4H)-one
    —— 4-Amino-3-[2-(azepan-1-yl)-2-oxoethyl]sulfanyl-6-methyl-1,2,4-triazin-5-one 869067-50-5 C12H19N5O2S
    4-Amino-3-[2-(azepan-1-yl)-2-oxoethyl]sulfanyl-6-methyl-1,2,4-triazin-5-one
    —— 4-Amino-3-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazin-5-one —— C11H12N4OS
    4-Amino-3-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazin-5-one
    —— 2-[(1S)-1-(5-benzyl-1H-1,2,4-triazol-3-yl)ethyl]sulfanyl-4,6-dimethylpyrimidine —— C17H19N5S
    2-[(1S)-1-(5-benzyl-1H-1,2,4-triazol-3-yl)ethyl]sulfanyl-4,6-dimethylpyrimidine
    —— (5R)-3-hydroxy-5-phenyl-2-phenylsulfanylcyclohex-2-en-1-one —— C18H16O2S
    (5R)-3-hydroxy-5-phenyl-2-phenylsulfanylcyclohex-2-en-1-one
    —— 5-[4-[(2R)-oxan-2-yl]oxybutylsulfanyl]-1,3,4-thiadiazol-2-amine —— C11H19N3O2S2
    5-[4-[(2R)-oxan-2-yl]oxybutylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2R)-N-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-2-cyclopentyl-2-phenylacetamide —— C24H23ClN2OS
    (2R)-N-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-2-cyclopentyl-2-phenylacetamide
    —— (2R)-2-cyclopentyl-2-phenyl-N-(2-phenylsulfanylpyridin-3-yl)acetamide —— C24H24N2OS
    (2R)-2-cyclopentyl-2-phenyl-N-(2-phenylsulfanylpyridin-3-yl)acetamide
    —— 5-[4-[(2S)-oxan-2-yl]oxybutylsulfanyl]-1,3,4-thiadiazol-2-amine —— C11H19N3O2S2
    5-[4-[(2S)-oxan-2-yl]oxybutylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-(4-methylphenyl)sulfanylacetamide —— C13H17NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— 2-((2-oxo-1-(pyridin-4-ylmethyl)-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)-N-phenethylacetamide —— C23H24N4O2S
    2-((2-oxo-1-(pyridin-4-ylmethyl)-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)-N-phenethylacetamide
    —— 4-[2-(azepan-1-yl)-2-oxoethyl]sulfanyl-1-(pyridin-3-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C21H26N4O2S
    4-[2-(azepan-1-yl)-2-oxoethyl]sulfanyl-1-(pyridin-3-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— N-[(4-methylphenyl)methyl]-2-[[2-oxo-1-(pyridin-4-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]sulfanyl]acetamide —— C23H24N4O2S
    N-[(4-methylphenyl)methyl]-2-[[2-oxo-1-(pyridin-4-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]sulfanyl]acetamide
    —— 4-(2-oxo-2-pyrrolidin-1-ylethyl)sulfanyl-1-(pyridin-3-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C19H22N4O2S
    4-(2-oxo-2-pyrrolidin-1-ylethyl)sulfanyl-1-(pyridin-3-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— 4-[(2-fluorophenyl)methylsulfanyl]-1-(pyridin-3-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C20H18FN3OS
    4-[(2-fluorophenyl)methylsulfanyl]-1-(pyridin-3-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C20H22ClNO3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C19H26ClNO3S
    [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-(Ethoxycarbonylamino)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C15H18ClNO5S
    [2-(Ethoxycarbonylamino)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-[(2-Chlorophenyl)methylamino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C19H19Cl2NO3S
    [2-[(2-Chlorophenyl)methylamino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 4-(4-chlorophenyl)sulfanylbutanoate —— C17H15ClN2O3S2
    (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 4-(4-chlorophenyl)sulfanylbutanoate
    —— [(1S)-1-cyanoethyl] 2-[2-nitro-4-(trifluoromethyl)phenyl]sulfanylbenzoate —— C17H11F3N2O4S
    [(1S)-1-cyanoethyl] 2-[2-nitro-4-(trifluoromethyl)phenyl]sulfanylbenzoate
    —— (3-Methyl-5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 4-(4-chlorophenyl)sulfanylbutanoate —— C18H17ClN2O3S2
    (3-Methyl-5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C16H20ClNO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C20H22ClNO4S
    [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C20H21ClFNO3S
    [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C19H26ClNO3S
    [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— 2-(2-fluorophenyl)sulfanylethyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate —— C17H18FNO3S
    2-(2-fluorophenyl)sulfanylethyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate
    —— 2-[5-[2-(4-Thiophen-2-ylpyrimidin-2-yl)sulfanylacetyl]thiophen-2-yl]acetate —— C16H11N2O3S3-
    2-[5-[2-(4-Thiophen-2-ylpyrimidin-2-yl)sulfanylacetyl]thiophen-2-yl]acetate
    —— 4-Oxo-4-[2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylanilino]but-2-enoate —— C15H9F3N3O3S-
    4-Oxo-4-[2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylanilino]but-2-enoate
    —— 2-[2-[(2,5-Dichlorothiophen-3-yl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium —— C15H15Cl2N2S2+
    2-[2-[(2,5-Dichlorothiophen-3-yl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-phenoxybutanoate —— C24H23NO4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-phenoxybutanoate
    —— 3-[3-[(4-methylphenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate —— C14H14N3O3S-
    3-[3-[(4-methylphenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate
    —— 3-[3-[(3-chlorophenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate —— C13H11ClN3O3S-
    3-[3-[(3-chlorophenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate
    —— 3-(3-((2-Chlorobenzyl)thio)-5-oxo-4,5-dihydro-1,2,4-triazin-6-yl)propanoic acid —— C13H12ClN3O3S
    3-(3-((2-Chlorobenzyl)thio)-5-oxo-4,5-dihydro-1,2,4-triazin-6-yl)propanoic acid
    —— 3-[3-[(3-methylphenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate —— C14H14N3O3S-
    3-[3-[(3-methylphenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate
    —— 3-(3-((4-Fluorobenzyl)thio)-5-oxo-4,5-dihydro-1,2,4-triazin-6-yl)propanoic acid —— C13H12FN3O3S
    3-(3-((4-Fluorobenzyl)thio)-5-oxo-4,5-dihydro-1,2,4-triazin-6-yl)propanoic acid
    —— 3-[3-[(2-chlorophenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate —— C13H11ClN3O3S-
    3-[3-[(2-chlorophenyl)methylsulfanyl]-5-oxo-4H-1,2,4-triazin-6-yl]propanoate
    —— 4-((2-methylbenzyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C15H16N2OS
    4-((2-methylbenzyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— 4-[(4-Fluorophenyl)methylsulfanyl]-1,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-one —— C14H13FN2OS
    4-[(4-Fluorophenyl)methylsulfanyl]-1,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-one
    —— 2-(2,5-dichlorophenoxy)-N-(2-phenylsulfanylphenyl)acetamide —— C20H15Cl2NO2S
    2-(2,5-dichlorophenoxy)-N-(2-phenylsulfanylphenyl)acetamide