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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-dimethyl-4-[(2S,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C19H22N5OS2+
    N,N-dimethyl-4-[(2S,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— 6-Amino-5-[2-(4-fluorophenyl)sulfanylacetyl]-1-propylpyrimidine-2,4-dione —— C15H16FN3O3S
    6-Amino-5-[2-(4-fluorophenyl)sulfanylacetyl]-1-propylpyrimidine-2,4-dione
    —— N,N-dimethyl-4-[(2S,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C19H21N5OS2
    N,N-dimethyl-4-[(2S,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— N,N-dimethyl-4-[(2R,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C19H22N5OS2+
    N,N-dimethyl-4-[(2R,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— (4R)-3-methyl-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-4,5-dihydro-2H-[1,2]thiazolo[5,4-b]pyridin-6-one —— C14H13N5O2S2
    (4R)-3-methyl-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-4,5-dihydro-2H-[1,2]thiazolo[5,4-b]pyridin-6-one
    —— N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C13H13FN2O3S2
    N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidin-1-ium —— C15H21N4S+
    (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidin-1-ium
    —— 1-[[(2S)-oxolan-2-yl]methyl]-5-prop-2-enylsulfanyltetrazole —— C9H14N4OS
    1-[[(2S)-oxolan-2-yl]methyl]-5-prop-2-enylsulfanyltetrazole
    —— 1-[[(2R)-oxolan-2-yl]methyl]-5-prop-2-enylsulfanyltetrazole —— C9H14N4OS
    1-[[(2R)-oxolan-2-yl]methyl]-5-prop-2-enylsulfanyltetrazole
    —— (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine —— C15H20N4S
    (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine
    —— 2-[4-chloro-6-[cyclohexyl(methyl)amino]pyrimidin-2-yl]sulfanyl-N-(2-piperidin-1-ium-1-ylethyl)acetamide —— C20H33ClN5OS+
    2-[4-chloro-6-[cyclohexyl(methyl)amino]pyrimidin-2-yl]sulfanyl-N-(2-piperidin-1-ium-1-ylethyl)acetamide
    —— 2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide —— C17H29ClN4OS
    2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— (3-Cyano-4-imino-2-oxopentyl) 2-(2-fluorophenyl)sulfanylacetate —— C14H13FN2O3S
    (3-Cyano-4-imino-2-oxopentyl) 2-(2-fluorophenyl)sulfanylacetate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] imidazo[1,2-a]pyridine-2-carboxylate —— C22H17N3O3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] imidazo[1,2-a]pyridine-2-carboxylate
    —— 2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-[(2R)-3-methylbutan-2-yl]acetamide —— C17H29ClN4OS
    2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— [(3S)-3-cyano-4-imino-2-oxopentyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C16H18N2O3S
    [(3S)-3-cyano-4-imino-2-oxopentyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(3R)-3-cyano-4-imino-2-oxopentyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C16H18N2O3S
    [(3R)-3-cyano-4-imino-2-oxopentyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— 6-Ethyl-2-[(4-fluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one —— C14H15FN2OS
    6-Ethyl-2-[(4-fluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one
    —— (1R)-1-(3-fluorophenyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C17H16FN3OS2
    (1R)-1-(3-fluorophenyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 2-(4-chloro-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanyl-N-[(2S)-5-(diethylamino)pentan-2-yl]acetamide —— C19H32ClN5OS
    2-(4-chloro-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanyl-N-[(2S)-5-(diethylamino)pentan-2-yl]acetamide
    —— 2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(R)-hydroxy(phenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H17N5O3S
    2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(R)-hydroxy(phenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-(4-chloro-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanyl-N-[(2R)-5-(diethylamino)pentan-2-yl]acetamide —— C19H32ClN5OS
    2-(4-chloro-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanyl-N-[(2R)-5-(diethylamino)pentan-2-yl]acetamide
    —— 2-[(4-Fluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(4-methylphenyl)methyl]pyrimidin-4-one —— C21H21FN2OS
    2-[(4-Fluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(4-methylphenyl)methyl]pyrimidin-4-one
    —— (1S)-1-(3-fluorophenyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C17H16FN3OS2
    (1S)-1-(3-fluorophenyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 2-[(4-Bromophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one —— C15H17BrN2OS
    2-[(4-Bromophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one
    —— (3R)-1-methyl-3-[(1-propan-2-yltetrazol-5-yl)sulfanylmethyl]piperidine —— C11H21N5S
    (3R)-1-methyl-3-[(1-propan-2-yltetrazol-5-yl)sulfanylmethyl]piperidine
    —— (3S)-1-methyl-3-[(1-propan-2-yltetrazol-5-yl)sulfanylmethyl]piperidine —— C11H21N5S
    (3S)-1-methyl-3-[(1-propan-2-yltetrazol-5-yl)sulfanylmethyl]piperidine
    —— 2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(S)-hydroxy(phenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H17N5O3S
    2-[[4-(2,5-dimethylpyrazol-3-yl)-5-[(S)-hydroxy(phenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 1-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C20H24N4OS3
    1-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 1-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C20H24N4OS3
    1-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-(2-morpholin-4-ium-4-ylethyl)acetamide —— C18H31ClN5O2S+
    2-[4-chloro-6-(dipropylamino)pyrimidin-2-yl]sulfanyl-N-(2-morpholin-4-ium-4-ylethyl)acetamide
    —— N-[[(1S)-1-(1-adamantyl)ethyl]carbamothioyl]adamantane-1-carboxamide —— C24H36N2OS
    N-[[(1S)-1-(1-adamantyl)ethyl]carbamothioyl]adamantane-1-carboxamide
    —— (2S,3R,4R,5R)-1,1-bis(ethylsulfanyl)hexane-2,3,4,5-tetrol —— C10H22O4S2
    (2S,3R,4R,5R)-1,1-bis(ethylsulfanyl)hexane-2,3,4,5-tetrol
    —— (2S,3S,4R,5R)-1,1-Bis-ethylsulfanyl-hexane-2,3,4,5-tetraol 6748-70-5 C10H22O4S2
    (2S,3S,4R,5R)-1,1-Bis-ethylsulfanyl-hexane-2,3,4,5-tetraol
    —— (3R)-3-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one —— C15H18N4O3S
    (3R)-3-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one
    —— N-[[(1R)-1-(1-adamantyl)ethyl]carbamothioyl]adamantane-1-carboxamide —— C24H36N2OS
    N-[[(1R)-1-(1-adamantyl)ethyl]carbamothioyl]adamantane-1-carboxamide
    —— (3S)-3-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one —— C15H18N4O3S
    (3S)-3-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one
    —— 2-[(2S)-oxolan-2-yl]-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)acetamide —— C16H17N3O2S
    2-[(2S)-oxolan-2-yl]-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)acetamide
    —— 2-[(2R)-oxolan-2-yl]-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)acetamide —— C16H17N3O2S
    2-[(2R)-oxolan-2-yl]-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)acetamide
    —— ethyl (2R)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C14H18N4O2S
    ethyl (2R)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— ethyl (2S)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C14H18N4O2S
    ethyl (2S)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[1-(2-methylpropyl)piperidin-4-yl]propanamide —— C18H27ClN2OS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[1-(2-methylpropyl)piperidin-4-yl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[1-(2-methylpropyl)piperidin-4-yl]propanamide —— C18H27ClN2OS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[1-(2-methylpropyl)piperidin-4-yl]propanamide
    —— 4-[(4-fluorophenyl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C17H15FN2S2
    4-[(4-fluorophenyl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine
    —— 2-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-4-(trifluoromethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile —— C18H23F3N3S+
    2-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-4-(trifluoromethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile
    —— (4R)-4-[5-(4-methylphenyl)sulfanylfuran-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine —— C17H17N3OS
    (4R)-4-[5-(4-methylphenyl)sulfanylfuran-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine
    —— (4S)-4-[5-(4-methylphenyl)sulfanylfuran-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine —— C17H17N3OS
    (4S)-4-[5-(4-methylphenyl)sulfanylfuran-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine
    —— 4-[[5-(4-methylpiperidin-1-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]butanenitrile —— C17H27N5OS
    4-[[5-(4-methylpiperidin-1-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]butanenitrile
    —— 4-[[5-(4-methylpiperidin-1-yl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]butanenitrile —— C17H27N5OS
    4-[[5-(4-methylpiperidin-1-yl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]butanenitrile
    —— 4-[(2S)-2-methylbutyl]-3-[(5-nitro-1,3-thiazol-2-yl)sulfanyl]-1H-1,2,4-triazol-5-one —— C10H13N5O3S2
    4-[(2S)-2-methylbutyl]-3-[(5-nitro-1,3-thiazol-2-yl)sulfanyl]-1H-1,2,4-triazol-5-one