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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (+/-)-<i>cis</i>-(2-methyl-cyclohexyl)-isothiocyanate —— C8H13NS
    (+/-)-<i>cis</i>-(2-methyl-cyclohexyl)-isothiocyanate
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C21H31N5O2S
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C21H31N5O2S
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— [(1R)-1-[4-benzyl-5-[2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C21H32N5O2S+
    [(1R)-1-[4-benzyl-5-[2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C21H32N5O2S+
    [(1S)-1-[4-benzyl-5-[2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C21H32N5O2S+
    [(1S)-1-[4-benzyl-5-[2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (5R)-2-(1-adamantyl)-5-phenyl-5,6-dihydro-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one —— C21H23N3OS
    (5R)-2-(1-adamantyl)-5-phenyl-5,6-dihydro-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one
    —— (5S)-2-(1-adamantyl)-5-phenyl-5,6-dihydro-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one —— C21H23N3OS
    (5S)-2-(1-adamantyl)-5-phenyl-5,6-dihydro-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one
    —— 2-[(2R)-2,3-dibromopropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile —— C11H12Br2N2S
    2-[(2R)-2,3-dibromopropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— 4-Cyclohexyl-3-cyclopropyl-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazole —— C19H25N3S
    4-Cyclohexyl-3-cyclopropyl-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazole
    —— (1R,4S)-4,7,7-trimethyl-3-oxo-N-(2-phenylsulfanylphenyl)-2-oxabicyclo[2.2.1]heptane-1-carboxamide —— C22H23NO3S
    (1R,4S)-4,7,7-trimethyl-3-oxo-N-(2-phenylsulfanylphenyl)-2-oxabicyclo[2.2.1]heptane-1-carboxamide
    —— (5R)-2-(1-adamantyl)-5-(3-fluorophenyl)-5,6-dihydro-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one —— C21H22FN3OS
    (5R)-2-(1-adamantyl)-5-(3-fluorophenyl)-5,6-dihydro-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one
    —— dimethyl (7S)-7-(4-chlorophenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C16H12ClNO5S2
    dimethyl (7S)-7-(4-chlorophenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— dimethyl (7R)-7-(4-chlorophenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C16H12ClNO5S2
    dimethyl (7R)-7-(4-chlorophenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (1R,4R)-4,7,7-trimethyl-2,3-dioxo-N-(2-phenylsulfanylphenyl)bicyclo[2.2.1]heptane-1-carboxamide —— C23H23NO3S
    (1R,4R)-4,7,7-trimethyl-2,3-dioxo-N-(2-phenylsulfanylphenyl)bicyclo[2.2.1]heptane-1-carboxamide
    —— dimethyl (5R,6R,7S)-7-(4-chlorophenyl)-2-oxo-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C16H14ClNO5S2
    dimethyl (5R,6R,7S)-7-(4-chlorophenyl)-2-oxo-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— 6-(1-Adamantyl)-2-(2-piperidin-1-ium-1-ylethylsulfanyl)pyridine-3-carbonitrile —— C23H32N3S+
    6-(1-Adamantyl)-2-(2-piperidin-1-ium-1-ylethylsulfanyl)pyridine-3-carbonitrile
    —— 1-thiophen-2-yl-2-[[(1R,8S)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]ethanone —— C17H19N3OS2
    1-thiophen-2-yl-2-[[(1R,8S)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]ethanone
    —— 1-thiophen-2-yl-2-[[(1S,8R)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]ethanone —— C17H19N3OS2
    1-thiophen-2-yl-2-[[(1S,8R)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]ethanone
    —— (2R)-2-[[5-[(3-chloroanilino)methyl]-4-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C20H20ClN4O2S-
    (2R)-2-[[5-[(3-chloroanilino)methyl]-4-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 2-((3-(o-Tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide —— C11H11N3OS2
    2-((3-(o-Tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— N-(4-fluorobenzyl)-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)acetamide —— C17H14FN3OS2
    N-(4-fluorobenzyl)-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— 2-[[3-(2-Methylphenyl)-1,2,4-thiadiazol-5-yl]sulfanyl]-1-morpholin-4-ylethanone —— C15H17N3O2S2
    2-[[3-(2-Methylphenyl)-1,2,4-thiadiazol-5-yl]sulfanyl]-1-morpholin-4-ylethanone
    —— N-(4-fluorobenzyl)-2-((3-(p-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide —— C18H16FN3OS2
    N-(4-fluorobenzyl)-2-((3-(p-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— N-(furan-2-ylmethyl)-2-((3-(p-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide —— C16H15N3O2S2
    N-(furan-2-ylmethyl)-2-((3-(p-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— 1-(Azepan-1-yl)-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)ethanone —— C16H19N3OS2
    1-(Azepan-1-yl)-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)ethanone
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]acetamide —— C15H17N3O2S2
    N-[[(2S)-oxolan-2-yl]methyl]-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]acetamide
    —— N-(4-fluorobenzyl)-2-((3-(o-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide —— C18H16FN3OS2
    N-(4-fluorobenzyl)-2-((3-(o-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— (3-phenyl-[1,2,4]thiadiazol-5-ylsulfanyl)-acetic acid ethyl ester 33062-15-6 C12H12N2O2S2
    (3-phenyl-[1,2,4]thiadiazol-5-ylsulfanyl)-acetic acid ethyl ester
    —— 2-(3-phenyl-[1,2,4]thiadiazol-5-ylsulfanyl)-acetamide 32991-61-0 C10H9N3OS2
    2-(3-phenyl-[1,2,4]thiadiazol-5-ylsulfanyl)-acetamide
    —— 1-Morpholin-4-yl-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]ethanone 864855-89-0 C14H15N3O2S2
    1-Morpholin-4-yl-2-[(3-phenyl-1,2,4-thiadiazol-5-yl)sulfanyl]ethanone
    —— N-cyclopentyl-2-((3-(o-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide —— C16H19N3OS2
    N-cyclopentyl-2-((3-(o-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— N-benzyl-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)acetamide —— C17H15N3OS2
    N-benzyl-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— (2R)-2-[[5-[(3-chloroanilino)methyl]-4-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoic acid —— C20H21ClN4O2S
    (2R)-2-[[5-[(3-chloroanilino)methyl]-4-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoic acid
    —— (2S)-2-[[5-[(3-chloroanilino)methyl]-4-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C20H20ClN4O2S-
    (2S)-2-[[5-[(3-chloroanilino)methyl]-4-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 2-[[3-(4-methylphenyl)-1,2,4-thiadiazol-5-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C16H19N3O2S2
    2-[[3-(4-methylphenyl)-1,2,4-thiadiazol-5-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— N-[(2R)-butan-2-yl]-2-[6-[(4-methylphenyl)methylamino]pyridazin-3-yl]sulfanylacetamide —— C18H24N4OS
    N-[(2R)-butan-2-yl]-2-[6-[(4-methylphenyl)methylamino]pyridazin-3-yl]sulfanylacetamide
    —— N-[(2S)-butan-2-yl]-2-[6-[(4-methylphenyl)methylamino]pyridazin-3-yl]sulfanylacetamide —— C18H24N4OS
    N-[(2S)-butan-2-yl]-2-[6-[(4-methylphenyl)methylamino]pyridazin-3-yl]sulfanylacetamide
    —— N-(furan-2-ylmethyl)-2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide —— C18H21N5O2S2
    N-(furan-2-ylmethyl)-2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide
    —— 2-[2-[[5-[(1R)-1-(dimethylamino)propyl]-4-(2-morpholin-4-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethylamino]ethanol —— C17H34N6O2S
    2-[2-[[5-[(1R)-1-(dimethylamino)propyl]-4-(2-morpholin-4-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethylamino]ethanol
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C15H24N4O3S3
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C15H24N4O3S3
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylacetamide
    —— 2-Amino-6-ethylsulfanyl-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C13H11N4S2+
    2-Amino-6-ethylsulfanyl-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— 2-[[2-(3-methylbutyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C20H25N3OS2
    2-[[2-(3-methylbutyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— (3R)-3-[[4-methyl-5-[(2,4,6-trimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide —— C18H25N3O2S2
    (3R)-3-[[4-methyl-5-[(2,4,6-trimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide
    —— 2-Amino-6-ethylsulfanyl-4-thiophen-2-ylpyridine-3,5-dicarbonitrile —— C13H10N4S2
    2-Amino-6-ethylsulfanyl-4-thiophen-2-ylpyridine-3,5-dicarbonitrile
    —— 3-[6-(1-Adamantyl)-3-cyano-4-(trifluoromethyl)pyridin-2-yl]sulfanylpropanoate —— C20H20F3N2O2S-
    3-[6-(1-Adamantyl)-3-cyano-4-(trifluoromethyl)pyridin-2-yl]sulfanylpropanoate
    —— 1-ethyl-3-[(E)-1-(4-methylsulfanylphenyl)ethylideneamino]urea —— C12H17N3OS
    1-ethyl-3-[(E)-1-(4-methylsulfanylphenyl)ethylideneamino]urea
    —— (3R)-1'-methyl-3-(2-methylphenyl)spiro[3H-1-benzothiophene-2,4'-piperidin-1-ium] —— C20H24NS+
    (3R)-1'-methyl-3-(2-methylphenyl)spiro[3H-1-benzothiophene-2,4'-piperidin-1-ium]
    —— (3S)-1'-methyl-3-(2-methylphenyl)spiro[3H-1-benzothiophene-2,4'-piperidin-1-ium] —— C20H24NS+
    (3S)-1'-methyl-3-(2-methylphenyl)spiro[3H-1-benzothiophene-2,4'-piperidin-1-ium]