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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19N5OS2
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— ethyl 4-[2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate —— C19H22N4O3S2
    ethyl 4-[2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate
    —— 4-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one —— C21H19N3O2S2
    4-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— 2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide —— C19H22N4OS2
    2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide
    —— 4-Benzyl-3-[(2,5-dimethylphenyl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazole —— C22H21N3OS
    4-Benzyl-3-[(2,5-dimethylphenyl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazole
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H19ClN4OS2
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-Benzyl-3-[(2-chloro-6-fluorophenyl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazole —— C20H15ClFN3OS
    4-Benzyl-3-[(2-chloro-6-fluorophenyl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazole
    —— 4-benzyl-3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazole —— C21H18ClN3OS
    4-benzyl-3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazole
    —— 4-benzyl-3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazole —— C21H18ClN3OS
    4-benzyl-3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazole
    —— 4-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3,5-dimethyl-1,2-oxazole —— C19H18N4O2S
    4-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3,5-dimethyl-1,2-oxazole
    —— N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H19ClN4OS2
    N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H19ClN4OS2
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-Benzyl-3-(furan-2-yl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,2,4-triazole —— C21H19N3OS2
    4-Benzyl-3-(furan-2-yl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,2,4-triazole
    —— (3S)-1-[6-(4-bromophenyl)sulfanylpyridazin-3-yl]-N-(pyridin-2-ylmethyl)piperidine-3-carboxamide —— C22H22BrN5OS
    (3S)-1-[6-(4-bromophenyl)sulfanylpyridazin-3-yl]-N-(pyridin-2-ylmethyl)piperidine-3-carboxamide
    —— 4-((pyridin-3-ylmethyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C13H13N3OS
    4-((pyridin-3-ylmethyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— 4-((pyridin-2-ylmethyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C13H13N3OS
    4-((pyridin-2-ylmethyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— 1-[(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-3-[(3-methylsulfanylphenyl)carbamothioylamino]thiourea —— C16H20N4S3
    1-[(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-3-[(3-methylsulfanylphenyl)carbamothioylamino]thiourea
    —— 6-methyl-4-(pyridin-2-ylmethylsulfanyl)-1H-pyrimidin-2-one —— C11H11N3OS
    6-methyl-4-(pyridin-2-ylmethylsulfanyl)-1H-pyrimidin-2-one
    —— dimethyl (7S)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C16H13NO6S2
    dimethyl (7S)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— dimethyl (7R)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C16H13NO6S2
    dimethyl (7R)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— 6,7-Diphenyl-3-prop-2-enylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazine —— C19H15N5S
    6,7-Diphenyl-3-prop-2-enylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazine
    —— 2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]acetate —— C6H6N3O3S-
    2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]acetate
    —— 2-[2-[5-(Trifluoromethyl)pyridin-2-yl]sulfanylethyliminomethyl]propanedinitrile —— C12H9F3N4S
    2-[2-[5-(Trifluoromethyl)pyridin-2-yl]sulfanylethyliminomethyl]propanedinitrile
    —— (E)-2-phenylsulfanylbut-2-enedioate —— C10H6O4S-2
    (E)-2-phenylsulfanylbut-2-enedioate
    —— (2R)-1-(4-fluorophenyl)sulfanyl-3-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethylamino]propan-2-ol —— C16H18F4N4OS
    (2R)-1-(4-fluorophenyl)sulfanyl-3-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethylamino]propan-2-ol
    —— [(2S)-3-(4-fluorophenyl)sulfanyl-2-hydroxypropyl]-[2-[[5-(trifluoromethyl)pyridin-1-ium-2-yl]amino]ethyl]azanium —— C17H21F4N3OS+2
    [(2S)-3-(4-fluorophenyl)sulfanyl-2-hydroxypropyl]-[2-[[5-(trifluoromethyl)pyridin-1-ium-2-yl]amino]ethyl]azanium
    —— (2S)-1-(4-fluorophenyl)sulfanyl-3-[2-[[5-(trifluoromethyl)pyridin-2-yl]amino]ethylamino]propan-2-ol —— C17H19F4N3OS
    (2S)-1-(4-fluorophenyl)sulfanyl-3-[2-[[5-(trifluoromethyl)pyridin-2-yl]amino]ethylamino]propan-2-ol
    —— (2R)-1-phenylsulfanyl-3-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethylamino]propan-2-ol —— C16H19F3N4OS
    (2R)-1-phenylsulfanyl-3-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethylamino]propan-2-ol
    —— [(2R)-2-hydroxy-3-phenylsulfanylpropyl]-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethyl]azanium —— C16H20F3N4OS+
    [(2R)-2-hydroxy-3-phenylsulfanylpropyl]-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethyl]azanium
    —— [(2S)-2-hydroxy-3-phenylsulfanylpropyl]-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethyl]azanium —— C16H20F3N4OS+
    [(2S)-2-hydroxy-3-phenylsulfanylpropyl]-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethyl]azanium
    —— [(2S)-3-(4-fluorophenyl)sulfanyl-2-hydroxypropyl]-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethyl]azanium —— C16H19F4N4OS+
    [(2S)-3-(4-fluorophenyl)sulfanyl-2-hydroxypropyl]-[2-[[4-(trifluoromethyl)pyrimidin-2-yl]amino]ethyl]azanium
    —— [(2R)-3-(4-fluorophenyl)sulfanyl-2-hydroxypropyl]-[2-[[5-(trifluoromethyl)pyridin-1-ium-2-yl]amino]ethyl]azanium —— C17H21F4N3OS+2
    [(2R)-3-(4-fluorophenyl)sulfanyl-2-hydroxypropyl]-[2-[[5-(trifluoromethyl)pyridin-1-ium-2-yl]amino]ethyl]azanium
    —— (2R)-1-(4-fluorophenyl)sulfanyl-3-[2-[[5-(trifluoromethyl)pyridin-2-yl]amino]ethylamino]propan-2-ol —— C17H19F4N3OS
    (2R)-1-(4-fluorophenyl)sulfanyl-3-[2-[[5-(trifluoromethyl)pyridin-2-yl]amino]ethylamino]propan-2-ol
    —— 5-((4-Methylpyrimidin-2-yl)thio)furan-2-carbaldehyde —— C10H8N2O2S
    5-((4-Methylpyrimidin-2-yl)thio)furan-2-carbaldehyde
    —— 2-[(5-Methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetate —— C8H10N3O2S-
    2-[(5-Methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetate
    —— 2-[(4,5-Diethyl-1,2,4-triazol-3-yl)sulfanyl]acetate —— C8H12N3O2S-
    2-[(4,5-Diethyl-1,2,4-triazol-3-yl)sulfanyl]acetate
    —— 2-[[5-(Furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C11H10N3O3S-
    2-[[5-(Furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (4-Allyl-5-ethyl-4H-[1,2,4]triazol-3-ylsulfanyl) acetic acid —— C9H13N3O2S
    (4-Allyl-5-ethyl-4H-[1,2,4]triazol-3-ylsulfanyl) acetic acid
    —— 2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide —— C14H21N7O2S
    2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide
    —— Ethyl 2-((4-(1-ethyl-3-methyl-1H-pyrazol-4-yl)-6-(trifluoromethyl)pyrimidin-2-yl)thio)acetate —— C15H17F3N4O2S
    Ethyl 2-((4-(1-ethyl-3-methyl-1H-pyrazol-4-yl)-6-(trifluoromethyl)pyrimidin-2-yl)thio)acetate
    —— 2-((4,5-Diethyl-4H-1,2,4-triazol-3-yl)thio)acetic acid —— C8H13N3O2S
    2-((4,5-Diethyl-4H-1,2,4-triazol-3-yl)thio)acetic acid
    —— 2-[(5-Ethyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetate —— C7H10N3O2S-
    2-[(5-Ethyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetate
    —— 3-ethyl-5-(ethylthio)-4H-1,2,4-triazol-4-amine —— C6H12N4S
    3-ethyl-5-(ethylthio)-4H-1,2,4-triazol-4-amine
    —— 2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide —— C14H21N7O2S
    2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide
    —— 3-[chloro(difluoro)methyl]-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 832739-98-7 C11H7ClF2N4S
    3-[chloro(difluoro)methyl]-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(difluoromethyl)-6-(2,4-difluorophenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 832739-32-9 C11H6F4N4S
    3-(difluoromethyl)-6-(2,4-difluorophenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(difluoromethyl)-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 832739-49-8 C11H8F2N4S
    3-(difluoromethyl)-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(difluoromethyl)-6-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 832737-17-4 C6H6F2N4S
    3-(difluoromethyl)-6-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(Chlorodifluoromethyl)-6-(2,4-difluorophenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H5ClF4N4S
    3-(Chlorodifluoromethyl)-6-(2,4-difluorophenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-[chloro(difluoro)methyl]-6-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C6H5ClF2N4S
    3-[chloro(difluoro)methyl]-6-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine