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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H14F2N2OS2
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone —— C16H17N3O2S2
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone
    —— 1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C15H19N3O4S
    1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— Methyl 4-[2,5-dimethyl-3-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrol-1-yl]butanoate —— C20H23N3O5S
    Methyl 4-[2,5-dimethyl-3-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrol-1-yl]butanoate
    —— N,N-dibenzyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C23H21N3O3S
    N,N-dibenzyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propan-1-one —— C18H20N2O2S2
    (2S)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propan-1-one
    —— N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H23N3O3S
    N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C12H17N3OS2
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C15H15N3O3S2
    N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H23N3O3S
    N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C17H17N3O3S
    2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— N-[(4-chlorophenyl)methyl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H16ClN3O3S
    N-[(4-chlorophenyl)methyl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-cyclopropyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C10H14N2OS2
    (2S)-N-cyclopropyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H16FN3O3S
    N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-benzyl-N-ethyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H19N3O3S
    N-benzyl-N-ethyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C16H21N3OS2
    N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-(6-amino-2,4-dioxo-1-propylpyrimidin-5-yl)-N-butyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H25N5O3S2
    N-(6-amino-2,4-dioxo-1-propylpyrimidin-5-yl)-N-butyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-(1-adamantyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C17H24N2OS2
    (2S)-N-(1-adamantyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide —— C18H19N3O3S
    N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide
    —— N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H14F2N2OS2
    N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-cyclopropyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C10H14N2OS2
    (2R)-N-cyclopropyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C14H22N2OS2
    (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— 2-[(2-Bromophenyl)methylsulfanyl]-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole —— C14H11BrN2O2S
    2-[(2-Bromophenyl)methylsulfanyl]-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole
    —— N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H20N2O3S3
    N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-Cyclopentyl-2-{[5-(2-methylfuran-3-YL)-1,3,4-oxadiazol-2-YL]sulfanyl}acetamide —— C14H17N3O3S
    N-Cyclopentyl-2-{[5-(2-methylfuran-3-YL)-1,3,4-oxadiazol-2-YL]sulfanyl}acetamide
    —— (2S)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C14H22N2OS2
    (2S)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H23N3O3S
    N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide —— C15H18N2OS2
    2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C13H14N2O3S
    (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 2-(Furan-2-yl)-5-[(4-methyl-1,3-thiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C11H9N3O2S2
    2-(Furan-2-yl)-5-[(4-methyl-1,3-thiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— methyl (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C11H12N2O4S
    methyl (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H22N4O3S
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-Bromophenyl)methylsulfanyl]-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole —— C14H11BrN2O2S
    2-[(4-Bromophenyl)methylsulfanyl]-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole
    —— 1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone —— C16H20N2O3S3
    1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C16H20N2OS2
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-[(4-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H14ClN3O3S
    N-[(4-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— dimethyl-[(1S)-2-[[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]amino]-1-phenylethyl]azanium —— C19H23N4O3S+
    dimethyl-[(1S)-2-[[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]amino]-1-phenylethyl]azanium
    —— 1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone —— C16H20N2O3S3
    1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C16H20N2OS2
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— Methyl 2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C10H10N2O4S
    Methyl 2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— N-[(1R)-1-(2-bromophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H15BrN2OS2
    N-[(1R)-1-(2-bromophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 3-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C10H9N3O2S
    3-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (2S)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C21H21N3O4S
    (2S)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— N-[(2-Chlorophenyl)methyl]-2-{[5-(2-methylfuran-3-YL)-1,3,4-oxadiazol-2-YL]sulfanyl}acetamide —— C16H14ClN3O3S
    N-[(2-Chlorophenyl)methyl]-2-{[5-(2-methylfuran-3-YL)-1,3,4-oxadiazol-2-YL]sulfanyl}acetamide
    —— N-benzyl-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H17N3O3S
    N-benzyl-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H25N3O3S
    (2R)-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N'-acetyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetohydrazide —— C8H11N3O2S2
    N'-acetyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetohydrazide
    —— methyl (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C11H12N2O4S
    methyl (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H22N4O3S
    N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C16H20N2OS2
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide