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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(tert-butylcarbamoyl)propanamide —— C14H25N5O2S2
    (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(tert-butylcarbamoyl)propanamide
    —— 3-[5-[(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C15H18N6O2S2
    3-[5-[(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— (2R)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C13H22N4O3S3
    (2R)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C17H24N4OS2
    (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C16H21FN4OS2
    (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C13H22N4O3S3
    (2S)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— 3-[5-[(4-Bromophenyl)methylsulfanyl]-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C14H17BrN4OS
    3-[5-[(4-Bromophenyl)methylsulfanyl]-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[(3R)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C15H18N6O2S2
    3-[5-[(3R)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[(4-Chlorophenyl)methylamino]-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C16H20ClN5O2S
    3-[5-[2-[(4-Chlorophenyl)methylamino]-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-(Cyclopentylamino)-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C14H23N5O2S
    3-[5-[2-(Cyclopentylamino)-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[(2-Chlorophenyl)methylamino]-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C16H20ClN5O2S
    3-[5-[2-[(2-Chlorophenyl)methylamino]-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— (2R)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2-chlorophenyl)methyl]propanamide —— C16H21ClN4OS2
    (2R)-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2-chlorophenyl)methyl]propanamide
    —— [2-[4-(3,4-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 3-methyl-1,2-oxazole-5-carboxylate —— C21H20N2O4S
    [2-[4-(3,4-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 3-methyl-1,2-oxazole-5-carboxylate
    —— 2-(5-Formyl-3-phenylimidazo[2,1-b][1,3]thiazol-6-yl)sulfanylacetamide —— C14H11N3O2S2
    2-(5-Formyl-3-phenylimidazo[2,1-b][1,3]thiazol-6-yl)sulfanylacetamide
    —— (1S,9S)-3-chloro-11-methyl-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2(7),3,5-triene —— C10H12ClN3S
    (1S,9S)-3-chloro-11-methyl-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2(7),3,5-triene
    —— ethyl 2,4-dimethyl-5-[(2R)-2-(3-methylsulfanylanilino)propanoyl]-1H-pyrrole-3-carboxylate —— C19H24N2O3S
    ethyl 2,4-dimethyl-5-[(2R)-2-(3-methylsulfanylanilino)propanoyl]-1H-pyrrole-3-carboxylate
    —— 1-[4-[(2R)-2-(4-chlorophenyl)sulfanylpropanoyl]piperazin-1-yl]-2,2-dimethylpropan-1-one —— C18H25ClN2O2S
    1-[4-[(2R)-2-(4-chlorophenyl)sulfanylpropanoyl]piperazin-1-yl]-2,2-dimethylpropan-1-one
    —— 1-[4-[(2S)-2-(4-chlorophenyl)sulfanylpropanoyl]piperazin-1-yl]-2,2-dimethylpropan-1-one —— C18H25ClN2O2S
    1-[4-[(2S)-2-(4-chlorophenyl)sulfanylpropanoyl]piperazin-1-yl]-2,2-dimethylpropan-1-one
    —— N-[(2R,3S)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide —— C19H22N2O2S
    N-[(2R,3S)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(2S,3S)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide —— C19H22N2O2S
    N-[(2S,3S)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(2S,3R)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide —— C19H22N2O2S
    N-[(2S,3R)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(2R,3R)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide —— C19H22N2O2S
    N-[(2R,3R)-2-(4-methylphenyl)oxan-3-yl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-[(1R)-1-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole —— C20H19N5OS2
    2-[(1R)-1-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide —— C14H18N4OS2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide
    —— (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C14H25N5O2S
    (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylpropanamide —— C15H20N4OS2
    (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylpropanamide
    —— (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C14H25N5O2S
    (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— 2-[(1R)-1-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C19H16FN5OS2
    2-[(1R)-1-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— 2-[(1S)-1-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole —— C20H19N5OS2
    2-[(1S)-1-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C13H14ClN3O2S
    (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide —— C19H20N4OS3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide
    —— 2-(3-chlorophenyl)-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole —— C19H15ClN4O2S
    2-(3-chlorophenyl)-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-(3-chlorophenyl)-5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole —— C18H12ClFN4O2S
    2-(3-chlorophenyl)-5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-(3-chlorophenyl)-5-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole —— C18H12ClFN4O2S
    2-(3-chlorophenyl)-5-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C13H14ClN3O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— Ethyl 2-[2-(2-acetamidoethylsulfanyl)-1,3-thiazol-4-yl]acetate —— C11H16N2O3S2
    Ethyl 2-[2-(2-acetamidoethylsulfanyl)-1,3-thiazol-4-yl]acetate
    —— 2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C18H21N5O3S2
    2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— 2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C18H21N5O3S2
    2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— N-[2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]acetamide —— C14H18N4O2S
    N-[2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]acetamide
    —— 3-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C19H19N5O3S
    3-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 3-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C14H15Cl2N3OS
    3-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C17H21N5O2S2
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C20H26N2OS
    N-[[4-(dimethylamino)phenyl]methyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C16H14N4O4S
    2-(2,5-Dimethylfuran-3-yl)-5-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— 2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C18H16N4O3S2
    2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— 2-(2-Methylfuran-3-yl)-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole —— C14H10N4O3S2
    2-(2-Methylfuran-3-yl)-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-(2-Fluorophenyl)-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole —— C15H9FN4O2S2
    2-(2-Fluorophenyl)-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C17H13FN4O3S
    2-(2,5-Dimethylfuran-3-yl)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3,4-oxadiazole