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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(1,3,5-trimethylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C19H23N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(1,3,5-trimethylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— (2R)-N-(1-cyanocyclohexyl)-2-[(3-ethyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide —— C14H20N4OS2
    (2R)-N-(1-cyanocyclohexyl)-2-[(3-ethyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide
    —— (2S)-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C9H13N3OS3
    (2S)-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-(1-cyanocyclohexyl)-2-[(3-ethyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide —— C14H20N4OS2
    (2S)-N-(1-cyanocyclohexyl)-2-[(3-ethyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C17H22N4O3S2
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylacetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C14H17N3O4S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 1-[(1R)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C12H18N6OS2
    1-[(1R)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C14H17N3O4S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (3S)-3-[2-[1-[2-(dimethylamino)ethyl]tetrazol-5-yl]sulfanylethyl]oxolan-2-one —— C11H19N5O2S
    (3S)-3-[2-[1-[2-(dimethylamino)ethyl]tetrazol-5-yl]sulfanylethyl]oxolan-2-one
    —— 2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C12H12ClF3N2O3S2
    2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C17H27N3OS
    N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-[2-[(3R)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H25N3OS
    2-[2-[(3R)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— (2S)-N-(2-morpholin-4-ylsulfonylethyl)-2-pyridin-2-ylsulfanylpropanamide —— C14H21N3O4S2
    (2S)-N-(2-morpholin-4-ylsulfonylethyl)-2-pyridin-2-ylsulfanylpropanamide
    —— N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C17H27N3OS
    N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-[(1R,3R)-3-methylsulfonylcyclohexyl]sulfanyl-4-(trifluoromethyl)pyrimidine —— C12H15F3N2O2S2
    2-[(1R,3R)-3-methylsulfonylcyclohexyl]sulfanyl-4-(trifluoromethyl)pyrimidine
    —— (2R)-N-(2-morpholin-4-ylsulfonylethyl)-2-pyridin-2-ylsulfanylpropanamide —— C14H21N3O4S2
    (2R)-N-(2-morpholin-4-ylsulfonylethyl)-2-pyridin-2-ylsulfanylpropanamide
    —— 4-(2-methoxyethyl)-3-[2-[(3S)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-1,2,4-triazole —— C12H22N4OS
    4-(2-methoxyethyl)-3-[2-[(3S)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-1,2,4-triazole
    —— 2-[(1S,3S)-3-methylsulfonylcyclohexyl]sulfanyl-4-(trifluoromethyl)pyrimidine —— C12H15F3N2O2S2
    2-[(1S,3S)-3-methylsulfonylcyclohexyl]sulfanyl-4-(trifluoromethyl)pyrimidine
    —— 1-[(1S)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C12H18N6OS2
    1-[(1S)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C17H27N3OS
    N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— (3R)-3-[2-[1-[2-(dimethylamino)ethyl]tetrazol-5-yl]sulfanylethyl]oxolan-2-one —— C11H19N5O2S
    (3R)-3-[2-[1-[2-(dimethylamino)ethyl]tetrazol-5-yl]sulfanylethyl]oxolan-2-one
    —— 2-[(1S,3R)-3-methylsulfonylcyclohexyl]sulfanyl-4-(trifluoromethyl)pyrimidine —— C12H15F3N2O2S2
    2-[(1S,3R)-3-methylsulfonylcyclohexyl]sulfanyl-4-(trifluoromethyl)pyrimidine
    —— 2-[2-[(3S)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H25N3OS
    2-[2-[(3S)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[(3S)-2-oxo-3-(1,3,4-thiadiazol-2-ylsulfanyl)pyrrolidin-1-yl]thiophene-3-carbonitrile —— C11H8N4OS3
    2-[(3S)-2-oxo-3-(1,3,4-thiadiazol-2-ylsulfanyl)pyrrolidin-1-yl]thiophene-3-carbonitrile
    —— 2-[(3R)-2-oxo-3-(1,3,4-thiadiazol-2-ylsulfanyl)pyrrolidin-1-yl]thiophene-3-carbonitrile —— C11H8N4OS3
    2-[(3R)-2-oxo-3-(1,3,4-thiadiazol-2-ylsulfanyl)pyrrolidin-1-yl]thiophene-3-carbonitrile
    —— (3R)-3-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylbutan-2-one —— C9H13N3O3S
    (3R)-3-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylbutan-2-one
    —— (3S)-3-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylbutan-2-one —— C9H13N3O3S
    (3S)-3-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylbutan-2-one
    —— (2S)-3-(3-chlorophenyl)sulfanylpropane-1,2-diol —— C9H11ClO2S
    (2S)-3-(3-chlorophenyl)sulfanylpropane-1,2-diol
    —— (2R)-3-(3-chlorophenyl)sulfanylpropane-1,2-diol —— C9H11ClO2S
    (2R)-3-(3-chlorophenyl)sulfanylpropane-1,2-diol
    —— dimethyl-[(1S)-2-[[2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]amino]-1-phenylethyl]azanium —— C20H26N5O2S+
    dimethyl-[(1S)-2-[[2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]amino]-1-phenylethyl]azanium
    —— 1-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C19H19N5O2S2
    1-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C13H18N4O2S
    2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H19ClN4O2S
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C17H26N5O2S+
    (2R)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— 2-(4-Fluorophenyl)-4-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole —— C18H15FN4OS2
    2-(4-Fluorophenyl)-4-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H18F2N4O2S
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 4-Methyl-3-(2-methylfuran-3-yl)-5-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazole —— C16H17N3OS
    4-Methyl-3-(2-methylfuran-3-yl)-5-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazole
    —— N-(2-cyanoethyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C14H17N5O2S
    N-(2-cyanoethyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C15H20N4O2S
    (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— dimethyl-[(1R)-2-[[2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]amino]-1-phenylethyl]azanium —— C20H26N5O2S+
    dimethyl-[(1R)-2-[[2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]amino]-1-phenylethyl]azanium
    —— (2S)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C17H26N5O2S+
    (2S)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— N-[(4-chlorophenyl)methyl]-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H19ClN4O2S
    N-[(4-chlorophenyl)methyl]-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— methyl (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C12H15N3O3S
    methyl (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 2-(4-Chlorophenyl)-4-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole —— C18H15ClN4OS2
    2-(4-Chlorophenyl)-4-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole
    —— 3-[(2-Chlorophenyl)methylsulfanyl]-4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazole —— C15H14ClN3OS
    3-[(2-Chlorophenyl)methylsulfanyl]-4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazole
    —— (2S)-1-(4-ethylpiperazin-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C17H25N5O2S
    (2S)-1-(4-ethylpiperazin-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C15H20N4O2S
    (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— (2R)-N-cyclohexyl-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H28N4O2S
    (2R)-N-cyclohexyl-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-benzyl-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H22N4O2S
    (2S)-N-benzyl-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H25N5O2S
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide