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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C12H13N3O2S2
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[2-(thiophen-2-ylmethylsulfanyl)ethyl]acetamide —— C13H15N3O2S3
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[2-(thiophen-2-ylmethylsulfanyl)ethyl]acetamide
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H14ClN3O2S2
    N-[2-(4-chlorophenyl)sulfanylethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2S)-3-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propane-1,2-diol —— C16H23N3O2S2
    (2S)-3-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propane-1,2-diol
    —— 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C14H15N3O2S2
    2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(2-methylphenyl)sulfanylacetate —— C17H15NO4S
    [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(2-methylphenyl)sulfanylacetate
    —— (2S)-2-(2-hydroxyethylsulfanyl)-3,3-dimethylbutanal —— C8H16O2S
    (2S)-2-(2-hydroxyethylsulfanyl)-3,3-dimethylbutanal
    —— (2R)-2-(2-hydroxyethylsulfanyl)-3,3-dimethylbutanal —— C8H16O2S
    (2R)-2-(2-hydroxyethylsulfanyl)-3,3-dimethylbutanal
    —— (1S)-1-methyl-1-oxo-1lambda6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid —— C6H7NO3S
    (1S)-1-methyl-1-oxo-1lambda6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid
    —— (2R)-2-cyclohexyl-2-methylsulfanylacetaldehyde —— C9H16OS
    (2R)-2-cyclohexyl-2-methylsulfanylacetaldehyde
    —— (2S)-2-cyclohexyl-2-methylsulfanylacetaldehyde —— C9H16OS
    (2S)-2-cyclohexyl-2-methylsulfanylacetaldehyde
    —— (3R)-3-methyl-2,3-dihydro-1-benzothiophen-6-amine —— C9H11NS
    (3R)-3-methyl-2,3-dihydro-1-benzothiophen-6-amine
    —— (2S)-2-phenylsulfanylpropanal —— C9H10OS
    (2S)-2-phenylsulfanylpropanal
    —— (3S)-3-methyl-2,3-dihydro-1-benzothiophen-6-amine —— C9H11NS
    (3S)-3-methyl-2,3-dihydro-1-benzothiophen-6-amine
    —— (2S)-2-methyl-2-propan-2-ylsulfanylbutanal —— C8H16OS
    (2S)-2-methyl-2-propan-2-ylsulfanylbutanal
    —— 3-[(4-chlorophenyl)methylsulfanyl]-N-[(2,5-dimethylpyrrol-3-ylidene)methyl]-1,2,4-triazol-4-amine —— C16H16ClN5S
    3-[(4-chlorophenyl)methylsulfanyl]-N-[(2,5-dimethylpyrrol-3-ylidene)methyl]-1,2,4-triazol-4-amine
    —— (2R)-2-ethylsulfanyl-3,3-dimethylbutanal —— C8H16OS
    (2R)-2-ethylsulfanyl-3,3-dimethylbutanal
    —— N'-[(2,5-dimethylpyrrol-3-ylidene)methyl]-2-(2-fluorophenyl)sulfanylacetohydrazide —— C15H16FN3OS
    N'-[(2,5-dimethylpyrrol-3-ylidene)methyl]-2-(2-fluorophenyl)sulfanylacetohydrazide
    —— (2S)-2-ethylsulfanyl-3,3-dimethylbutanal —— C8H16OS
    (2S)-2-ethylsulfanyl-3,3-dimethylbutanal
    —— (2R)-2-methyl-2-propan-2-ylsulfanylbutanal —— C8H16OS
    (2R)-2-methyl-2-propan-2-ylsulfanylbutanal
    —— (3R)-2,3-dihydro-1-benzothiophene-3-carbonitrile —— C9H7NS
    (3R)-2,3-dihydro-1-benzothiophene-3-carbonitrile
    —— (3S)-2,3-dihydro-1-benzothiophene-3-carbonitrile —— C9H7NS
    (3S)-2,3-dihydro-1-benzothiophene-3-carbonitrile
    —— 2-(4-chlorophenyl)sulfanyl-N'-[(2,5-dimethylpyrrol-3-ylidene)methyl]acetohydrazide —— C15H16ClN3OS
    2-(4-chlorophenyl)sulfanyl-N'-[(2,5-dimethylpyrrol-3-ylidene)methyl]acetohydrazide
    —— N-(3-propan-2-yloxypropyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C15H26N4O2S
    N-(3-propan-2-yloxypropyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-(2-methylbutan-2-yl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C14H24N4OS
    N-(2-methylbutan-2-yl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[(2-fluorophenyl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C16H19FN4OS
    N-[(2-fluorophenyl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— (2S)-1-[amino(propyl)amino]propane-2-thiol —— C6H16N2S
    (2S)-1-[amino(propyl)amino]propane-2-thiol
    —— N-[(2R)-5-methylhexan-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C16H28N4OS
    N-[(2R)-5-methylhexan-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[(2S)-5-methylhexan-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C16H28N4OS
    N-[(2S)-5-methylhexan-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— (2S)-2-chloro-2-methyl-3-methylsulfanylpropanal —— C5H9ClOS
    (2S)-2-chloro-2-methyl-3-methylsulfanylpropanal
    —— N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C20H34N4OS
    N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— (2R)-2-chloro-2-methyl-3-methylsulfanylpropanal —— C5H9ClOS
    (2R)-2-chloro-2-methyl-3-methylsulfanylpropanal
    —— (2S)-3-chloro-2-methyl-2-methylsulfanylpropanal —— C5H9ClOS
    (2S)-3-chloro-2-methyl-2-methylsulfanylpropanal
    —— N-[(S)-phenyl(thiophen-2-yl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C20H22N4OS2
    N-[(S)-phenyl(thiophen-2-yl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— 5-(furan-2-yl)-3-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,2-oxazole —— C15H16N4O2S
    5-(furan-2-yl)-3-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,2-oxazole
    —— N-[(1R)-1-cyclopropylethyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C14H22N4OS
    N-[(1R)-1-cyclopropylethyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C16H26N4O4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C17H21ClN4OS
    N-[2-(3-chlorophenyl)ethyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— 2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)-N-(2,4,4-trimethylpentan-2-yl)acetamide —— C17H30N4OS
    2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)-N-(2,4,4-trimethylpentan-2-yl)acetamide
    —— N-[(2-methylphenyl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C17H22N4OS
    N-[(2-methylphenyl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[(R)-phenyl(thiophen-2-yl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C20H22N4OS2
    N-[(R)-phenyl(thiophen-2-yl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— (2R)-2-butylsulfanylpropanal —— C7H14OS
    (2R)-2-butylsulfanylpropanal
    —— (2R)-1-[amino(propyl)amino]propane-2-thiol —— C6H16N2S
    (2R)-1-[amino(propyl)amino]propane-2-thiol
    —— N-(3-phenylsulfanylpropyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C18H24N4OS2
    N-(3-phenylsulfanylpropyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C18H24N4OS
    N-[2-(2-methylphenyl)ethyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C16H26N4O4S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— (2S)-2-propan-2-ylsulfanylbutanal —— C7H14OS
    (2S)-2-propan-2-ylsulfanylbutanal
    —— (2S)-2-butylsulfanylpropanal —— C7H14OS
    (2S)-2-butylsulfanylpropanal
    —— (2R)-2-methylsulfanylhexanal —— C7H14OS
    (2R)-2-methylsulfanylhexanal
    —— N-cyclohexyl-N-[(4-fluorophenyl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C22H29FN4OS
    N-cyclohexyl-N-[(4-fluorophenyl)methyl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide