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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4R)-4-hydroxy-5-phenylsulfanylpentanenitrile —— C11H13NOS
    (4R)-4-hydroxy-5-phenylsulfanylpentanenitrile
    —— (2R)-2-(2-phenylsulfanylethyl)pyrrolidine —— C12H17NS
    (2R)-2-(2-phenylsulfanylethyl)pyrrolidine
    —— (3R,4S)-4-hydroxy-3-phenylsulfanylpentanenitrile —— C11H13NOS
    (3R,4S)-4-hydroxy-3-phenylsulfanylpentanenitrile
    —— (3R)-3-hydroxy-4-(4-methylphenyl)sulfanylbutanenitrile —— C11H13NOS
    (3R)-3-hydroxy-4-(4-methylphenyl)sulfanylbutanenitrile
    —— (3R,4R)-4-hydroxy-3-phenylsulfanylpentanenitrile —— C11H13NOS
    (3R,4R)-4-hydroxy-3-phenylsulfanylpentanenitrile
    —— 3-(4-methylphenyl)sulfanyl-N-[(4-phenyloxan-4-yl)methyl]propanamide —— C22H27NO2S
    3-(4-methylphenyl)sulfanyl-N-[(4-phenyloxan-4-yl)methyl]propanamide
    —— 2-(1-methylimidazol-2-yl)sulfanyl-N-[(S)-oxan-4-yl(phenyl)methyl]acetamide —— C18H23N3O2S
    2-(1-methylimidazol-2-yl)sulfanyl-N-[(S)-oxan-4-yl(phenyl)methyl]acetamide
    —— 2-(1-methylimidazol-2-yl)sulfanyl-N-[(R)-oxan-4-yl(phenyl)methyl]acetamide —— C18H23N3O2S
    2-(1-methylimidazol-2-yl)sulfanyl-N-[(R)-oxan-4-yl(phenyl)methyl]acetamide
    —— 1-[(2S)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1R,3S)-3-methylcyclohexyl]urea —— C14H28N2O3S
    1-[(2S)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1R,3S)-3-methylcyclohexyl]urea
    —— 1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]-3-pentylurea —— C12H26N2O3S
    1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]-3-pentylurea
    —— 1-[(3R)-1-(6-propan-2-ylsulfanylpyridazin-3-yl)piperidin-3-yl]pyrrolidin-2-one —— C16H24N4OS
    1-[(3R)-1-(6-propan-2-ylsulfanylpyridazin-3-yl)piperidin-3-yl]pyrrolidin-2-one
    —— (2S)-2-(3-nitropyridin-2-yl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide —— C14H15N3O3S2
    (2S)-2-(3-nitropyridin-2-yl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide
    —— 1-[(2R)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1S,3S)-3-methylcyclohexyl]urea —— C14H28N2O3S
    1-[(2R)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1S,3S)-3-methylcyclohexyl]urea
    —— 1-[(2S)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1S,3S)-3-methylcyclohexyl]urea —— C14H28N2O3S
    1-[(2S)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1S,3S)-3-methylcyclohexyl]urea
    —— 1-[(3S)-1-(6-propan-2-ylsulfanylpyridazin-3-yl)piperidin-3-yl]pyrrolidin-2-one —— C16H24N4OS
    1-[(3S)-1-(6-propan-2-ylsulfanylpyridazin-3-yl)piperidin-3-yl]pyrrolidin-2-one
    —— 1-[(2R)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1R,3S)-3-methylcyclohexyl]urea —— C14H28N2O3S
    1-[(2R)-1-ethylsulfonylpropan-2-yl]-1-methyl-3-[(1R,3S)-3-methylcyclohexyl]urea
    —— (3R)-4-oxo-3-phenylsulfanylpentanenitrile —— C11H11NOS
    (3R)-4-oxo-3-phenylsulfanylpentanenitrile
    —— N-[2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide —— C12H12FN3OS3
    N-[2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide
    —— N-[2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide —— C13H15N3OS3
    N-[2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]acetamide
    —— N-(1-cyanocyclohexyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C16H22N4OS
    N-(1-cyanocyclohexyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxyethyl)piperazin-1-yl]methanone —— C15H20N2O3S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxyethyl)piperazin-1-yl]methanone
    —— N-(1-cyanocyclopentyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C15H20N4OS
    N-(1-cyanocyclopentyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-(1,3,4-Thiadiazol-2-ylsulfanylmethyl)-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C13H12N4OS3
    2-(1,3,4-Thiadiazol-2-ylsulfanylmethyl)-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— (4-Oxo-6,7,8,9-tetrahydro-4H-pyrimido[2,1-B][1,3]benzothiazol-2-YL)methyl 2-(phenylsulfanyl)acetate —— C19H18N2O3S2
    (4-Oxo-6,7,8,9-tetrahydro-4H-pyrimido[2,1-B][1,3]benzothiazol-2-YL)methyl 2-(phenylsulfanyl)acetate
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxyethyl)piperazin-1-yl]methanone —— C15H20N2O3S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-(2-hydroxyethyl)piperazin-1-yl]methanone
    —— N-[2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]acetamide —— C8H11F3N4OS
    N-[2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]acetamide
    —— 2-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C15H14F3N5OS2
    2-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— 5-[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C10H8N4OS3
    5-[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 5-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C11H8F3N5OS2
    5-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 2-{[(5-Methyl-1,3,4-thiadiazol-2-YL)sulfanyl]methyl}-6,7,8,9-tetrahydro-4H-pyrimido[2,1-B][1,3]benzothiazol-4-one —— C14H14N4OS3
    2-{[(5-Methyl-1,3,4-thiadiazol-2-YL)sulfanyl]methyl}-6,7,8,9-tetrahydro-4H-pyrimido[2,1-B][1,3]benzothiazol-4-one
    —— N-[3-(3,5-dimethyl-1H-pyrazol-1-yl)propyl]-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide —— C14H20N4OS2
    N-[3-(3,5-dimethyl-1H-pyrazol-1-yl)propyl]-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide
    —— 5-(1,3,4-Thiadiazol-2-ylsulfanylmethyl)-3-thiophen-2-yl-1,2,4-oxadiazole —— C9H6N4OS3
    5-(1,3,4-Thiadiazol-2-ylsulfanylmethyl)-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 2-[(4-Methyl-1,3-thiazol-2-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C15H15N3OS3
    2-[(4-Methyl-1,3-thiazol-2-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— ethyl 4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanoate —— C11H19N3O3S
    ethyl 4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanoate
    —— 3-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C9H13Cl2N3OS
    3-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C14H17N5O3S
    3-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— N-[2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]acetamide —— C9H16N4O2S
    N-[2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]acetamide
    —— 4-propyl-3-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C12H13N5O2S2
    4-propyl-3-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— (4S)-4-phenylsulfanylcyclopentene-1-carbonitrile —— C12H11NS
    (4S)-4-phenylsulfanylcyclopentene-1-carbonitrile
    —— (4R)-4-phenylsulfanylcyclopentene-1-carbonitrile —— C12H11NS
    (4R)-4-phenylsulfanylcyclopentene-1-carbonitrile
    —— 4-[(2S)-2-hydroxypropyl]sulfanyl-2-methylpyrimidin-5-ol —— C8H12N2O2S
    4-[(2S)-2-hydroxypropyl]sulfanyl-2-methylpyrimidin-5-ol
    —— 2-[(2R)-2-hydroxypropyl]sulfanyl-6-methylpyridin-3-ol —— C9H13NO2S
    2-[(2R)-2-hydroxypropyl]sulfanyl-6-methylpyridin-3-ol
    —— 2-[(4R)-4-methyl-2-methylsulfanylcyclohexen-1-yl]acetic acid —— C10H16O2S
    2-[(4R)-4-methyl-2-methylsulfanylcyclohexen-1-yl]acetic acid
    —— 2-[(4S)-4-methyl-2-methylsulfanylcyclohexen-1-yl]acetic acid —— C10H16O2S
    2-[(4S)-4-methyl-2-methylsulfanylcyclohexen-1-yl]acetic acid
    —— 4-[(2R)-2-hydroxypropyl]sulfanyl-2-methylpyrimidin-5-ol —— C8H12N2O2S
    4-[(2R)-2-hydroxypropyl]sulfanyl-2-methylpyrimidin-5-ol
    —— [(2R,3S)-3-phenylsulfanylbutan-2-yl]hydrazine —— C10H16N2S
    [(2R,3S)-3-phenylsulfanylbutan-2-yl]hydrazine
    —— (2S)-2-chloro-3-phenylsulfanylpropanenitrile —— C9H8ClNS
    (2S)-2-chloro-3-phenylsulfanylpropanenitrile
    —— (2R)-2-chloro-3-phenylsulfanylpropanenitrile —— C9H8ClNS
    (2R)-2-chloro-3-phenylsulfanylpropanenitrile
    —— N-[2-(2-fluorophenyl)ethyl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H19FN4OS2
    N-[2-(2-fluorophenyl)ethyl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine —— C17H14N4O2S2
    5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine