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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H16FN3O4S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-[(4-fluorophenyl)methyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H15F2N3O2S
    (2R)-N-[(4-fluorophenyl)methyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H15ClFN3O2S
    (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-methyl-4-(5-methylfuran-2-yl)sulfanylbutanoic acid —— C10H14O3S
    (2R)-2-methyl-4-(5-methylfuran-2-yl)sulfanylbutanoic acid
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H17N3O3S4
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-(2-phenylsulfanylphenyl)-2-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)propanamide —— C21H18N4OS2
    (2S)-N-(2-phenylsulfanylphenyl)-2-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)propanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H17N3O3S4
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-methyl-4-(5-methylfuran-2-yl)sulfanylbutanoic acid —— C10H14O3S
    (2S)-2-methyl-4-(5-methylfuran-2-yl)sulfanylbutanoic acid
    —— (2R)-N-[(4-methylphenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C19H19N3OS3
    (2R)-N-[(4-methylphenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— methyl N-[(2R)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoyl]carbamate —— C13H13N3O3S3
    methyl N-[(2R)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoyl]carbamate
    —— (2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-prop-2-enylpropanamide —— C14H15N3OS3
    (2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-prop-2-enylpropanamide
    —— (2S)-N-[(4-fluorophenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C18H16FN3OS3
    (2S)-N-[(4-fluorophenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-cycloheptyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C18H23N3OS3
    (2S)-N-cycloheptyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-(1-cyanocyclohexyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C19H22N4OS3
    (2R)-N-(1-cyanocyclohexyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-tert-butyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H19N3OS3
    (2R)-N-tert-butyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-(2-methoxyethyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H17N3O2S3
    (2S)-N-(2-methoxyethyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C16H15N3OS4
    (2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— ethyl (4R)-4-cyano-5-methylsulfanyl-2,3-dihydropyrrole-4-carboxylate —— C9H12N2O2S
    ethyl (4R)-4-cyano-5-methylsulfanyl-2,3-dihydropyrrole-4-carboxylate
    —— (2R)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-di(propan-2-yl)propanamide —— C17H23N3OS3
    (2R)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— ethyl (4S)-4-cyano-5-methylsulfanyl-2,3-dihydropyrrole-4-carboxylate —— C9H12N2O2S
    ethyl (4S)-4-cyano-5-methylsulfanyl-2,3-dihydropyrrole-4-carboxylate
    —— (2R)-N-(2-methylpropyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H19N3OS3
    (2R)-N-(2-methylpropyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-(2-phenylsulfanylphenyl)-2-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)propanamide —— C21H18N4OS2
    (2R)-N-(2-phenylsulfanylphenyl)-2-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)propanamide
    —— (2R)-N-cycloheptyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C18H23N3OS3
    (2R)-N-cycloheptyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-(1-cyanocyclohexyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C19H22N4OS3
    (2S)-N-(1-cyanocyclohexyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-di(propan-2-yl)propanamide —— C17H23N3OS3
    (2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— [(2S)-1-(tert-butylcarbamoylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate —— C17H24N2O4S
    [(2S)-1-(tert-butylcarbamoylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate
    —— (2S)-N-(2-cyanoethyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H16N4OS3
    (2S)-N-(2-cyanoethyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H17N3O3S4
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— methyl N-[(2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoyl]carbamate —— C13H13N3O3S3
    methyl N-[(2S)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoyl]carbamate
    —— (2R)-N-(2-cyanoethyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H16N4OS3
    (2R)-N-(2-cyanoethyl)-N-methyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(4-fluorophenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C18H16FN3OS3
    (2R)-N-[(4-fluorophenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-[(4-methylphenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C19H19N3OS3
    (2S)-N-[(4-methylphenyl)methyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-methyl-4-phenylsulfanylbutanoic acid —— C11H14O2S
    (2S)-2-methyl-4-phenylsulfanylbutanoic acid
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H20N4O3S3
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 3-thiophen-3-yl-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2,4-oxadiazole —— C13H9N5OS3
    3-thiophen-3-yl-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2,4-oxadiazole
    —— 7-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C13H10N6OS3
    7-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H20N4O3S3
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (3S)-2-oxo-1H-pyrido[2,3-b][1,4]thiazine-3-carboxylic acid —— C8H6N2O3S
    (3S)-2-oxo-1H-pyrido[2,3-b][1,4]thiazine-3-carboxylic acid
    —— (4S)-5-hydroxy-4-phenylsulfanylpentanenitrile —— C11H13NOS
    (4S)-5-hydroxy-4-phenylsulfanylpentanenitrile
    —— (3R)-3-phenylsulfanylpent-4-enoic acid —— C11H12O2S
    (3R)-3-phenylsulfanylpent-4-enoic acid
    —— (2R)-2-phenylsulfanylpent-4-enoic acid —— C11H12O2S
    (2R)-2-phenylsulfanylpent-4-enoic acid
    —— (3S)-3-methyl-4-(4-methylphenyl)sulfanylbutanal —— C12H16OS
    (3S)-3-methyl-4-(4-methylphenyl)sulfanylbutanal
    —— (3S,4S)-4-hydroxy-3-phenylsulfanylpentanenitrile —— C11H13NOS
    (3S,4S)-4-hydroxy-3-phenylsulfanylpentanenitrile
    —— (4S)-4-hydroxy-5-phenylsulfanylpentanenitrile —— C11H13NOS
    (4S)-4-hydroxy-5-phenylsulfanylpentanenitrile
    —— (3S)-3-hydroxy-4-(4-methylphenyl)sulfanylbutanenitrile —— C11H13NOS
    (3S)-3-hydroxy-4-(4-methylphenyl)sulfanylbutanenitrile
    —— (3R)-3-methyl-4-(4-methylphenyl)sulfanylbutanal —— C12H16OS
    (3R)-3-methyl-4-(4-methylphenyl)sulfanylbutanal
    —— (3S,4R)-4-hydroxy-3-phenylsulfanylpentanenitrile —— C11H13NOS
    (3S,4R)-4-hydroxy-3-phenylsulfanylpentanenitrile
    —— (3S)-4-hydroxy-3-(4-methylphenyl)sulfanylbutanenitrile —— C11H13NOS
    (3S)-4-hydroxy-3-(4-methylphenyl)sulfanylbutanenitrile
    —— (2S)-2-(2-phenylsulfanylethyl)pyrrolidine —— C12H17NS
    (2S)-2-(2-phenylsulfanylethyl)pyrrolidine
    —— (4R)-5-hydroxy-4-phenylsulfanylpentanenitrile —— C11H13NOS
    (4R)-5-hydroxy-4-phenylsulfanylpentanenitrile