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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-3-ylprop-2-enoic acid —— C13H14N4O2S
    (Z)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-3-ylprop-2-enoic acid
    —— (Z)-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H19N5O3S
    (Z)-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-(5-morpholin-4-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C16H19N4O4S-
    (E)-3-(5-morpholin-4-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-4-ylprop-2-enoic acid —— C13H14N4O2S
    (E)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-4-ylprop-2-enoic acid
    —— (E)-3-(5-morpholin-4-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C16H20N4O4S
    (E)-3-(5-morpholin-4-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (Z)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate —— C15H19N4O2S-
    (Z)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate
    —— (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C18H15ClN3O3S-
    (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C18H15ClN3O3S-
    (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H16ClN3O3S
    (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H16ClN3O3S
    (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-(5-piperidin-1-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C17H22N4O3S
    (E)-3-(5-piperidin-1-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— 2-(4-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-(thiophen-2-ylmethyl)acetamide —— C17H18ClNO3S3
    2-(4-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-(thiophen-2-ylmethyl)acetamide
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(4-chlorophenyl)sulfanylpropan-1-one —— C17H18ClNO2S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(4-chlorophenyl)sulfanylpropan-1-one
    —— 2-(4-chlorophenyl)sulfanyl-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide —— C19H16ClNOS2
    2-(4-chlorophenyl)sulfanyl-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide
    —— N-[(3S,4S)-4-chloro-1,1-dioxothiolan-3-yl]-2-(4-chlorophenyl)sulfanylacetamide —— C12H13Cl2NO3S2
    N-[(3S,4S)-4-chloro-1,1-dioxothiolan-3-yl]-2-(4-chlorophenyl)sulfanylacetamide
    —— (2Z)-4-(4-chlorophenyl)sulfanyl-2-(2,5,6,7,8,9-hexahydro-[1,2,4]triazolo[4,3-a]azepin-3-ylidene)-3-oxobutanenitrile —— C17H17ClN4OS
    (2Z)-4-(4-chlorophenyl)sulfanyl-2-(2,5,6,7,8,9-hexahydro-[1,2,4]triazolo[4,3-a]azepin-3-ylidene)-3-oxobutanenitrile
    —— N-[(3R,4S)-4-chloro-1,1-dioxothiolan-3-yl]-2-(4-chlorophenyl)sulfanylacetamide —— C12H13Cl2NO3S2
    N-[(3R,4S)-4-chloro-1,1-dioxothiolan-3-yl]-2-(4-chlorophenyl)sulfanylacetamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide —— C15H16ClNOS2
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide
    —— 2-[(4-Chlorophenyl)sulfanylmethyl]-5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazole —— C15H13ClN2O2S
    2-[(4-Chlorophenyl)sulfanylmethyl]-5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazole
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide —— C15H16ClNOS2
    (2S)-2-(4-chlorophenyl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide
    —— [(3R)-3-bromobutyl]sulfanylbenzene —— C10H13BrS
    [(3R)-3-bromobutyl]sulfanylbenzene
    —— (6S)-6,7-dihydro-5H-triazolo[5,1-b][1,3]thiazine-6-carboxylic acid —— C6H7N3O2S
    (6S)-6,7-dihydro-5H-triazolo[5,1-b][1,3]thiazine-6-carboxylic acid
    —— (6R)-6,7-dihydro-5H-triazolo[5,1-b][1,3]thiazine-6-carboxylic acid —— C6H7N3O2S
    (6R)-6,7-dihydro-5H-triazolo[5,1-b][1,3]thiazine-6-carboxylic acid
    —— [(3S)-3-bromobutyl]sulfanylbenzene —— C10H13BrS
    [(3S)-3-bromobutyl]sulfanylbenzene
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[2,5-dimethyl-1-(2-thiophen-2-ylethyl)pyrrol-3-yl]ethanone —— C16H19N5OS2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[2,5-dimethyl-1-(2-thiophen-2-ylethyl)pyrrol-3-yl]ethanone
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C12H21N5OS
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— (2R)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C13H16FN5OS
    (2R)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-[[5-[2-(4-chlorophenyl)sulfanylacetyl]thiophen-2-yl]methyl]acetamide —— C15H14ClNO2S2
    N-[[5-[2-(4-chlorophenyl)sulfanylacetyl]thiophen-2-yl]methyl]acetamide
    —— 3-Benzylsulfanyl-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C19H17N5OS2
    3-Benzylsulfanyl-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 2-[[5-[2-[methyl(thiophen-3-ylmethyl)amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C15H20N4O2S4
    2-[[5-[2-[methyl(thiophen-3-ylmethyl)amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[(4-Amino-5-benzylsulfanyl-1,2,4-triazol-3-yl)sulfanyl]-1-(azocan-1-yl)ethanone —— C18H25N5OS2
    2-[(4-Amino-5-benzylsulfanyl-1,2,4-triazol-3-yl)sulfanyl]-1-(azocan-1-yl)ethanone
    —— 2-[[5-[2-[methyl-[(5-methylfuran-2-yl)methyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C16H22N4O3S3
    2-[[5-[2-[methyl-[(5-methylfuran-2-yl)methyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[[5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C17H18N4O2S3
    2-[[5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[[5-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C16H26N4O2S3
    2-[[5-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[[5-[2-[(2-fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C16H19FN4O2S3
    2-[[5-[2-[(2-fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[[5-[2-[(2-methylphenyl)methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C17H22N4O2S3
    2-[[5-[2-[(2-methylphenyl)methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— N-[2-(2-fluorophenyl)ethyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21FN4O3S
    N-[2-(2-fluorophenyl)ethyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C16H26N4O3S
    3-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— 3-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-4-(3-methoxypropyl)-1H-1,2,4-triazol-5-one —— C14H16N4O4S
    3-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-4-(3-methoxypropyl)-1H-1,2,4-triazol-5-one
    —— 2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide —— C19H22N4O3S2
    2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide
    —— N-[2-(2-fluorophenyl)ethyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21FN4O3S
    N-[2-(2-fluorophenyl)ethyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2-fluorophenyl)methyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H19FN4O3S
    N-[(2-fluorophenyl)methyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C16H26N4O3S
    3-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— N-[2-(3-chlorophenyl)ethyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21ClN4O3S
    N-[2-(3-chlorophenyl)ethyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 4-(2-phenylethyl)-3-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C20H18N4O2S
    4-(2-phenylethyl)-3-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— N-[2-(2-methylphenyl)ethyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H24N4O3S
    N-[2-(2-methylphenyl)ethyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21ClN4O3S
    N-[2-(3-chlorophenyl)ethyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2-methylphenyl)methyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4O3S
    N-[(2-methylphenyl)methyl]-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2-fluorophenyl)methyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H19FN4O3S
    N-[(2-fluorophenyl)methyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2-methylphenyl)methyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4O3S
    N-[(2-methylphenyl)methyl]-2-[[5-oxo-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide