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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(2R)-butan-2-yl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one —— C11H18N2OS
    2-[(2R)-butan-2-yl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one
    —— (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C17H13ClN2O4S
    (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— 4-propan-2-yl-2-propylsulfanyl-1H-pyrimidin-6-one —— C10H16N2OS
    4-propan-2-yl-2-propylsulfanyl-1H-pyrimidin-6-one
    —— (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C18H15ClN2O4S
    (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— 2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]ethylazanium —— C7H12N3OS+
    2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]ethylazanium
    —— 5-benzyl-4-methyl-2-[(4-methylphenyl)methylsulfanyl]-1H-pyrimidin-6-one —— C20H20N2OS
    5-benzyl-4-methyl-2-[(4-methylphenyl)methylsulfanyl]-1H-pyrimidin-6-one
    —— 4-propan-2-yl-2-propan-2-ylsulfanyl-1H-pyrimidin-6-one —— C10H16N2OS
    4-propan-2-yl-2-propan-2-ylsulfanyl-1H-pyrimidin-6-one
    —— 2-[(5-benzyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C22H23N3O2S
    2-[(5-benzyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— (Z)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C13H14N3O4S-
    (Z)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— N-cyclohexyl-2-[(4-isopropyl-6-oxo-1,6-dihydro-2-pyrimidinyl)thio]acetamide —— C15H23N3O2S
    N-cyclohexyl-2-[(4-isopropyl-6-oxo-1,6-dihydro-2-pyrimidinyl)thio]acetamide
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C17H22N4O3S
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoic acid —— C18H17N3O3S2
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoic acid
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoate —— C12H12N3O3S-
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoate
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-4-ylprop-2-enoic acid —— C12H12N4O2S
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-4-ylprop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate —— C17H16N5O3S-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate
    —— (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C17H12ClN2O4S-
    (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoic acid —— C14H18N4O2S
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoic acid
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C17H21N4O3S-
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate —— C17H16N5O3S-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate
    —— (E)-3-(5-bromothiophen-2-yl)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C11H10BrN3O2S2
    (E)-3-(5-bromothiophen-2-yl)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C15H19N4O3S-
    (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoic acid —— C12H13N3O3S
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoate —— C18H16N3O3S2-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoate
    —— (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C13H15BrN4O3S
    (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-(5-bromothiophen-2-yl)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C11H9BrN3O2S2-
    (E)-3-(5-bromothiophen-2-yl)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-4-ylprop-2-enoate —— C12H11N4O2S-
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-4-ylprop-2-enoate
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoate —— C17H14N3O3S2-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoate
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-morpholin-4-ylfuran-2-yl)prop-2-enoate —— C15H17N4O4S-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-morpholin-4-ylfuran-2-yl)prop-2-enoate
    —— (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C15H20N4O3S
    (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(furan-2-yl)prop-2-enoic acid —— C11H11N3O3S
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(furan-2-yl)prop-2-enoic acid
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(furan-2-yl)prop-2-enoate —— C11H10N3O3S-
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(furan-2-yl)prop-2-enoate
    —— (E)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C13H16N4O3S
    (E)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoic acid —— C16H20N4O3S
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoic acid
    —— (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C17H13ClN3O3S2-
    (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (Z)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H15N5O3S2
    (Z)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H16ClN3O3S
    (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoate —— C11H10N3O2S2-
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoate
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoate —— C16H19N4O3S-
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoate
    —— (Z)-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C18H18N5O3S-
    (Z)-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (Z)-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H19N5O3S
    (Z)-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C18H23N4O3S-
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoic acid —— C12H13N3O2S2
    (E)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoic acid
    —— (Z)-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C19H19N3O3S2
    (Z)-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C18H15ClN3O3S-
    (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C17H13ClN3O3S-
    (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (Z)-3-(5-phenylsulfanylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C18H16N3O3S2-
    (Z)-3-(5-phenylsulfanylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C14H17BrN4O3S
    (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (Z)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoic acid —— C15H20N4O2S
    (Z)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoic acid
    —— (Z)-3-(3-methylthiophen-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C13H14N3O2S2-
    (Z)-3-(3-methylthiophen-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-3-(5-methylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C13H14N3O3S-
    (E)-3-(5-methylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate