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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (5R)-2-[(2S)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylate —— C12H19N3O2S
    methyl (5R)-2-[(2S)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylate
    —— (5R)-2-(2-oxopropylsulfanyl)-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid —— C11H14N2O3S
    (5R)-2-(2-oxopropylsulfanyl)-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid
    —— (5S)-2-[(2S)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid —— C11H17N3O2S
    (5S)-2-[(2S)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid
    —— (5S)-2-[(2R)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid —— C11H17N3O2S
    (5S)-2-[(2R)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid
    —— methyl (5S)-2-(2-oxopropylsulfanyl)-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylate —— C12H16N2O3S
    methyl (5S)-2-(2-oxopropylsulfanyl)-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylate
    —— (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-(1-methyltetrazol-5-yl)sulfanylpropanamide —— C13H16FN5OS
    (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-(1-methyltetrazol-5-yl)sulfanylpropanamide
    —— (5S)-2-(2-oxopropylsulfanyl)-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid —— C11H14N2O3S
    (5S)-2-(2-oxopropylsulfanyl)-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylic acid
    —— methyl (5S)-2-[(2R)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylate —— C12H19N3O2S
    methyl (5S)-2-[(2R)-2-aminopropyl]sulfanyl-4,5,6,7-tetrahydro-3H-benzimidazole-5-carboxylate
    —— N-[[5-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]thiophen-2-yl]methyl]acetamide —— C11H13N5O2S2
    N-[[5-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]thiophen-2-yl]methyl]acetamide
    —— (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-(1-methyltetrazol-5-yl)sulfanylpropanamide —— C13H16FN5OS
    (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-(1-methyltetrazol-5-yl)sulfanylpropanamide
    —— N-[[5-(2-pyrimidin-2-ylsulfanylacetyl)thiophen-2-yl]methyl]acetamide —— C13H13N3O2S2
    N-[[5-(2-pyrimidin-2-ylsulfanylacetyl)thiophen-2-yl]methyl]acetamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-pyrimidin-2-ylsulfanylacetamide —— C17H21N3OS
    N-[(1S)-3-methyl-1-phenylbutyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(2-methylphenyl)methyl]-2-[[5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H21N3OS3
    N-[(2-methylphenyl)methyl]-2-[[5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-[[5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H23N3OS3
    N-[2-(2-methylphenyl)ethyl]-2-[[5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-3,3-dimethylbutan-2-yl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide —— C10H17N3OS3
    N-[(2S)-3,3-dimethylbutan-2-yl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide
    —— N-[(2R)-3,3-dimethylbutan-2-yl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide —— C10H17N3OS3
    N-[(2R)-3,3-dimethylbutan-2-yl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide
    —— (3S)-3,4,6,7,8,9-hexahydro-2H-[1,3]thiazino[3,2-a]benzimidazol-3-amine —— C10H15N3S
    (3S)-3,4,6,7,8,9-hexahydro-2H-[1,3]thiazino[3,2-a]benzimidazol-3-amine
    —— (3R)-3,4,6,7,8,9-hexahydro-2H-[1,3]thiazino[3,2-a]benzimidazol-3-amine —— C10H15N3S
    (3R)-3,4,6,7,8,9-hexahydro-2H-[1,3]thiazino[3,2-a]benzimidazol-3-amine
    —— N-[2-(2-fluorophenyl)ethyl]-2-[[5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20FN3OS3
    N-[2-(2-fluorophenyl)ethyl]-2-[[5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-1-(4,5,6,7-tetrahydro-1H-benzimidazol-2-ylsulfanyl)propan-2-amine —— C10H17N3S
    (2S)-1-(4,5,6,7-tetrahydro-1H-benzimidazol-2-ylsulfanyl)propan-2-amine
    —— 2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(2-methylphenyl)methyl]acetamide —— C16H15ClFNOS
    2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(2-methylphenyl)methyl]acetamide
    —— (2R)-3-oxo-2-(4-propan-2-yl-1,3-thiazol-2-yl)-4-pyridin-4-ylsulfanylbutanenitrile —— C15H15N3OS2
    (2R)-3-oxo-2-(4-propan-2-yl-1,3-thiazol-2-yl)-4-pyridin-4-ylsulfanylbutanenitrile
    —— 2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide —— C15H12ClF2NOS
    2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide
    —— (2S)-3-oxo-2-(4-propan-2-yl-1,3-thiazol-2-yl)-4-pyridin-4-ylsulfanylbutanenitrile —— C15H15N3OS2
    (2S)-3-oxo-2-(4-propan-2-yl-1,3-thiazol-2-yl)-4-pyridin-4-ylsulfanylbutanenitrile
    —— N-[(3R)-1-tert-butyl-5-oxopyrrolidin-3-yl]-4-phenylsulfanylbutanamide —— C18H26N2O2S
    N-[(3R)-1-tert-butyl-5-oxopyrrolidin-3-yl]-4-phenylsulfanylbutanamide
    —— N-[(3S)-1-tert-butyl-5-oxopyrrolidin-3-yl]-4-phenylsulfanylbutanamide —— C18H26N2O2S
    N-[(3S)-1-tert-butyl-5-oxopyrrolidin-3-yl]-4-phenylsulfanylbutanamide
    —— 2-Cyclohexyl-5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-1,3,4-oxadiazole —— C16H17N3O3S
    2-Cyclohexyl-5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— 2-Cyclohexyl-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole —— C18H19N3O2S
    2-Cyclohexyl-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— N-[[5-[2-(2-chlorophenyl)sulfanylacetyl]thiophen-2-yl]methyl]-2,2-dimethylpropanamide —— C18H20ClNO2S2
    N-[[5-[2-(2-chlorophenyl)sulfanylacetyl]thiophen-2-yl]methyl]-2,2-dimethylpropanamide
    —— (3R,5R)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one —— C9H10N2O2S
    (3R,5R)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one
    —— N-[[5-[2-(2-chlorophenyl)sulfanylacetyl]thiophen-2-yl]methyl]acetamide —— C15H14ClNO2S2
    N-[[5-[2-(2-chlorophenyl)sulfanylacetyl]thiophen-2-yl]methyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(cyclohexen-1-yl)-N-cyclopropylacetamide —— C13H18N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(cyclohexen-1-yl)-N-cyclopropylacetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide —— C15H20N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C15H20N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C12H20N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile —— C12H12N4S2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— (3S,5R)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one —— C9H10N2O2S
    (3S,5R)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one
    —— (3S,5S)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one —— C9H10N2O2S
    (3S,5S)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one
    —— (3R,5S)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one —— C9H10N2O2S
    (3R,5S)-5-methyl-3-pyrazin-2-ylsulfanyloxolan-2-one
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-prop-2-enyl-N-(thiophen-2-ylmethyl)acetamide —— C12H14N4OS3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-prop-2-enyl-N-(thiophen-2-ylmethyl)acetamide
    —— 2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C12H13N3OS3
    2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 1-(5-Ethylthiophen-2-yl)-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H14FN3OS3
    1-(5-Ethylthiophen-2-yl)-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 1-methyl-1-[(4-methyl-1,3-thiazol-2-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea —— C16H21N3OS2
    1-methyl-1-[(4-methyl-1,3-thiazol-2-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea
    —— 1-methyl-1-[(4-methyl-1,3-thiazol-2-yl)methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C16H21N3OS2
    1-methyl-1-[(4-methyl-1,3-thiazol-2-yl)methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— 2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C18H18N2O2S3
    2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 1-[[(3S)-oxolan-3-yl]methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea —— C15H22N2O2S
    1-[[(3S)-oxolan-3-yl]methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea
    —— 1-[[(3S)-oxolan-3-yl]methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C15H22N2O2S
    1-[[(3S)-oxolan-3-yl]methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— 1-[[(3R)-oxolan-3-yl]methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C15H22N2O2S
    1-[[(3R)-oxolan-3-yl]methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— 1-[[(3R)-oxolan-3-yl]methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea —— C15H22N2O2S
    1-[[(3R)-oxolan-3-yl]methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea
    —— 1-[(5-methyl-1,2-oxazol-3-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea —— C15H19N3O2S
    1-[(5-methyl-1,2-oxazol-3-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea